A cyanoacrylate composition with thermoplastic polyurethane, formulated as a non-flowable soft solid or semi solid mass, for example in stick form, is reported.

An adhesive article that remains securely bonded to a substrate until a stimuli is applied. The article may be embodied as an adhesive tape, a bandage, or as other articles. The stimuli may be a change in temperature or application of a reduction that causes a structure within the article to break, creak, or otherwise disrupt to expose the adhesive to a solvent, such as via a difference in Coefficient of Thermal Expansion (CTE) or by exposing the article to a glass transition temperature.

An adhesive article that remains securely bonded to a substrate until a stimuli is applied. The article may be embodied as an adhesive tape, a bandage, or as other articles. The stimuli may be a change in temperature or application of a reduction that causes a structure within the article to break, creak, or otherwise disrupt to expose the adhesive to a solvent, such as via a difference in Coefficient of Thermal Expansion (CTE) or by exposing the article to a glass transition temperature.

Two-part cyanoacrylate/free radical curable adhesive systems, are provided.

Two-part cyanoacrylate/free radical curable adhesive systems, are provided.

An adhesive article that remains securely bonded to a substrate until a stimuli is applied. The article may be embodied as an adhesive tape, a bandage, or as other articles. The stimuli may be a change in temperature or application of a reduction that causes a structure within the article to break, creak, or otherwise disrupt to expose the adhesive to a solvent, such as via a difference in Coefficient of Thermal Expansion (CTE) or by exposing the article to a glass transition temperature.

An adhesive article that remains securely bonded to a substrate until a stimuli is applied. The article may be embodied as an adhesive tape, a bandage, or as other articles. The stimuli may be a change in temperature or application of a reduction that causes a structure within the article to break, creak, or otherwise disrupt to expose the adhesive to a solvent, such as via a difference in Coefficient of Thermal Expansion (CTE) or by exposing the article to a glass transition temperature.

A cyanoacrylate composition with thermoplastic polyurethane, formulated as a non-flowable soft solid or semi solid mass, for example in stick form, is reported.

The present invention concerns a two-part curable composition comprising: ?a first part (component A) comprising: at least 51% by weight based on the total weight of the first part, of one or more cyanoacrylate monomer(s); a transition metal complex; and an antioxidant; ?a second part (component B) comprising: a per-compound; at least one Michael acceptor M selected from the group consisting of (meth)acrylic monomers, (meth)acrylic functionalized oligomers, (meth)acrylic functionalized resins, and mixtures thereof; provided that the composition comprises (in the first part and/or in the second part) at least one compound C comprising a radical -EWG.sub.1-CH.sub.2-EWG.sub.2- wherein EWG.sub.2 and EWG.sub.1 are independently of each other an electron withdrawing group.

The present invention concerns a two-part curable composition comprising: ?a first part (component A) comprising: at least 51% by weight based on the total weight of the first part, of one or more cyanoacrylate monomer(s); a transition metal complex; and an antioxidant; ?a second part (component B) comprising: a per-compound; at least one Michael acceptor M selected from the group consisting of (meth)acrylic monomers, (meth)acrylic functionalized oligomers, (meth)acrylic functionalized resins, and mixtures thereof; provided that the composition comprises (in the first part and/or in the second part) at least one compound C comprising a radical -EWG.sub.1-CH.sub.2-EWG.sub.2- wherein EWG.sub.2 and EWG.sub.1 are independently of each other an electron withdrawing group.