Patent classifications
C09J153/02
PRESSURE-SENSITIVE ADHESIVE COMPOUNDS, AND SELF-ADHESIVE PRODUCTS AND COMPOSITES COMPRISING THE LATTER
The present invention relates to a foamed pressure-sensitive adhesive compound on the basis of aromatic polyvinyl-polydiene block copolymers, in particular for double-sided self-adhesive strips, containing a) 39.8 wt. % to 51.8 wt. % of an elastomer component, b) 35.0 wt. % to 58.0 wt % of an adhesive resin component, c) 2.0 wt. % to 15.0 wt. % of a plasticizer component, d) 0.0 wt. % to 18.0 wt. % of further additives and e) microballoons, the microballoons being at least partly expanded.
PRESSURE-SENSITIVE ADHESIVE COMPOUNDS, AND SELF-ADHESIVE PRODUCTS AND COMPOSITES COMPRISING THE LATTER
The present invention relates to a foamed pressure-sensitive adhesive compound on the basis of aromatic polyvinyl-polydiene block copolymers, in particular for double-sided self-adhesive strips, containing a) 39.8 wt. % to 51.8 wt. % of an elastomer component, b) 35.0 wt. % to 58.0 wt % of an adhesive resin component, c) 2.0 wt. % to 15.0 wt. % of a plasticizer component, d) 0.0 wt. % to 18.0 wt. % of further additives and e) microballoons, the microballoons being at least partly expanded.
HOT MELT PRESSURE SENSITIVE ADHESIVE COMPOSITIONS AND ARTICLES INCLUDING THE SAME
The HMPSA compositions of this invention include from 10% by weight to 35% by weight of a styrenic block copolymer, from 10% by weight to 60% by weight of a near white rosin ester tackifying agent having a neat Molten Garner Color of no greater than 2, and from 28% by weight to 45% by weight of a plasticizer. The HMPSA compositions are especially useful as positioning adhesives adhering well to both cotton and microfiber.
HOT MELT PRESSURE SENSITIVE ADHESIVE COMPOSITIONS AND ARTICLES INCLUDING THE SAME
The HMPSA compositions of this invention include from 10% by weight to 35% by weight of a styrenic block copolymer, from 10% by weight to 60% by weight of a near white rosin ester tackifying agent having a neat Molten Garner Color of no greater than 2, and from 28% by weight to 45% by weight of a plasticizer. The HMPSA compositions are especially useful as positioning adhesives adhering well to both cotton and microfiber.
HOT MELT PRESSURE SENSITIVE ADHESIVE COMPOSITIONS AND ARTICLES INCLUDING THE SAME
The HMPSA compositions of this invention include from 10% by weight to 35% by weight of a styrenic block copolymer, from 10% by weight to 60% by weight of a near white rosin ester tackifying agent having a neat Molten Garner Color of no greater than 2, and from 28% by weight to 45% by weight of a plasticizer. The HMPSA compositions are especially useful as positioning adhesives adhering well to both cotton and microfiber.
FOAMED ADHESIVE MASS LAYER AND ADHESIVE TAPE COMPRISING THE FOAMED ADHESIVE MASS LAYER
The invention relates to a foamed adhesive mass layer comprising a) 41.7 to 62.0 wt. % of an elastomer component, b) 37.7 to 58.0 wt. % of an adhesive resin component, c) 0 to 15 wt. % of a soft resin component, d) 0 to 18 wt. % further additives, and e) microballoons with a proportion of preferably 0.3 to 2.5 wt. %, preferably 0.5 to 2.0 wt. % and particularly preferably 0.7 to 1.7 wt. %, wherein the microballoons are at least partially expanded, wherein the elastomer component (a) consists of up to at least 90 wt. % polyvinyl aromatic compound polydine block copolymer, wherein the adhesive resin component (b) contains up to 4 to 100 wt. % of at least one type K1 if a rosin oligomer with a softening temperature (Ring & Ball, Test VI) of at least 90° C., and wherein the density (Text IX) of the foamed adhesive mass layer is at least 600 kg/m.sup.3 and max. 920 kg/m.sup.3.
FOAMED ADHESIVE MASS LAYER AND ADHESIVE TAPE COMPRISING THE FOAMED ADHESIVE MASS LAYER
The invention relates to a foamed adhesive mass layer comprising a) 41.7 to 62.0 wt. % of an elastomer component, b) 37.7 to 58.0 wt. % of an adhesive resin component, c) 0 to 15 wt. % of a soft resin component, d) 0 to 18 wt. % further additives, and e) microballoons with a proportion of preferably 0.3 to 2.5 wt. %, preferably 0.5 to 2.0 wt. % and particularly preferably 0.7 to 1.7 wt. %, wherein the microballoons are at least partially expanded, wherein the elastomer component (a) consists of up to at least 90 wt. % polyvinyl aromatic compound polydine block copolymer, wherein the adhesive resin component (b) contains up to 4 to 100 wt. % of at least one type K1 if a rosin oligomer with a softening temperature (Ring & Ball, Test VI) of at least 90° C., and wherein the density (Text IX) of the foamed adhesive mass layer is at least 600 kg/m.sup.3 and max. 920 kg/m.sup.3.
PRESSURE-SENSITIVE ADHESIVE TAPE
An adhesive tape with high repeelability from the state that a portion of the adhesive tape has already been peeled from an adherend is provided. The adhesive tape includes a substrate layer and an adhesive layer. The substrate layer has a breaking stress in a range of 1 to 90 MPa and an elongation at break in a range of 400% to 3000%. The adhesive tape satisfies the following relational expression (i): [Math. 1] P.sub.400/P.sub.0≤0.9 (i). P.sub.0 denotes an initial cleavage strength N/cm.sup.2 of the adhesive tape, and P.sub.400 denotes a cleavage strength N/cm.sup.2 when the adhesive tape is stretched by 400%.
PRESSURE-SENSITIVE ADHESIVE TAPE
An adhesive tape with high repeelability from the state that a portion of the adhesive tape has already been peeled from an adherend is provided. The adhesive tape includes a substrate layer and an adhesive layer. The substrate layer has a breaking stress in a range of 1 to 90 MPa and an elongation at break in a range of 400% to 3000%. The adhesive tape satisfies the following relational expression (i): [Math. 1] P.sub.400/P.sub.0≤0.9 (i). P.sub.0 denotes an initial cleavage strength N/cm.sup.2 of the adhesive tape, and P.sub.400 denotes a cleavage strength N/cm.sup.2 when the adhesive tape is stretched by 400%.
Protective film
A protective film 10 of the present invention includes a base material layer and a pressure sensitive adhesive layer, and is used by being attached to a resin substrate 21 at the time of performing heat bending on the resin substrate 21. The pressure sensitive adhesive layer contains a polyolefin having a melting point of lower than 125° C. The base material layer has a first layer which contains a polyolefin having a melting point of 150° C. or higher, and a second layer which contains an adhesive resin. In a case of heating the protective film 100 having such a configuration, in a state of being interposed between two attaching substrates which are formed of polycarbonate, at 145° C. for 30 minutes, peeling off one attaching substrate on the side of the pressure sensitive adhesive layer at 25° C., and then viewing a surface of the one attaching substrate in a plan view, a residual ratio of an area where the pressure sensitive adhesive layer remains is 5% or less.