The present invention concerns a method for manufacturing an insulating product based on organic or mineral fibers, which comprises—applying an aqueous binder composition to organic or mineral fibers, preferably mineral wool fibers; —heating the fibers bonded with the aqueous binder composition so as to evaporate the volatile phase of the aqueous binder composition and to bring about the thermal curing of the non-volatile residue, or packaging the organic or mineral fibers bonded with the aqueous binder composition for the purpose of storage and/or transport, the aqueous binder composition having a pH of between 1.0 and 6.5, preferably between 1.5 and 5.0, and comprising: a) at least one carbohydrate selected from hydrogenated sugars, reducing sugars, non-reducing sugars and mixtures thereof, (b) at least one polycarboxylic acid or an anhydride of such an acid, (c) from 1 to 35% by weight, relative to the total weight of components (a), (b) and (c), of a water-soluble, amine-containing phenolic resin consisting essentially of phenol-formaldehyde condensates and phenol-formaldehyde-amine condensates.

The present invention concerns a method for manufacturing an insulating product based on organic or mineral fibers, which comprises—applying an aqueous binder composition to organic or mineral fibers, preferably mineral wool fibers; —heating the fibers bonded with the aqueous binder composition so as to evaporate the volatile phase of the aqueous binder composition and to bring about the thermal curing of the non-volatile residue, or packaging the organic or mineral fibers bonded with the aqueous binder composition for the purpose of storage and/or transport, the aqueous binder composition having a pH of between 1.0 and 6.5, preferably between 1.5 and 5.0, and comprising: a) at least one carbohydrate selected from hydrogenated sugars, reducing sugars, non-reducing sugars and mixtures thereof, (b) at least one polycarboxylic acid or an anhydride of such an acid, (c) from 1 to 35% by weight, relative to the total weight of components (a), (b) and (c), of a water-soluble, amine-containing phenolic resin consisting essentially of phenol-formaldehyde condensates and phenol-formaldehyde-amine condensates.

The present invention relates to a sizing composition for mineral fibers, especially glass fibers or rock fibers, containing a liquid phenolic resin having a free formaldehyde content, expressed with respect to the total weight of liquid, of 0.1% or less and an extender.

Preferably, the liquid phenolic resin is mainly composed of phenol-formaldehyde and phenol-formaldehyde-amine condensates and has a water dilutability, at 20° C., at least equal to 1000%.

Another subject of the present invention is the insulating products based on mineral fibers treated by said sizing composition.

The present invention relates to a sizing composition for mineral fibers, especially glass fibers or rock fibers, containing a liquid phenolic resin having a free formaldehyde content, expressed with respect to the total weight of liquid, of 0.1% or less and an extender.

Preferably, the liquid phenolic resin is mainly composed of phenol-formaldehyde and phenol-formaldehyde-amine condensates and has a water dilutability, at 20° C., at least equal to 1000%.

Another subject of the present invention is the insulating products based on mineral fibers treated by said sizing composition.

The present invention relates to a sizing composition for mineral fibers, especially glass fibers or rock fibers, containing a liquid phenolic resin having a free formaldehyde content, expressed with respect to the total weight of liquid, of 0.1% or less and an extender.

Preferably, the liquid phenolic resin is mainly composed of phenol-formaldehyde and phenol-formaldehyde-amine condensates and has a water dilutability, at 20° C., at least equal to 1000%.

Another subject of the present invention is the insulating products based on mineral fibers treated by said sizing composition.

A metallic or metallized reinforcer has at least a surface of which is at least partially metallic, the at least partially metallic surface being coated with a polybenzoxazine sulfide whose repeating units include at least one unit corresponding to formula (I) or (II):

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in which the two oxazine rings are connected together via a central aromatic group, the benzene ring of which bears one, two, three or four groups of formula —S.sub.x—R in which “x” is an integer from 1 to 8 and R represents hydrogen or a hydrocarbon-based group including 1 to 10 carbon atoms and optionally a heteroatom chosen from O, S, N and P. Such a reinforcement can be used for the reinforcement of a rubber article, in particular a motor vehicle tire.

A method of manufacturing a composite product, comprising: applying a binder composition, notably in the form of an aqueous solution, to non or loosely assembled matter to provide resinated matter, wherein the binder composition consists of a binder composition prepared by combining reactants comprising at least 50% by dry weight reducing sugar reactant(s) and at least 5% by dry weight nitrogen-containing reactant(s); and arranging the resinated matter to provide loosely arranged resinated matter; and subjecting the loosely arranged resinated matter to heat and/or pressure to cure the binder composition and to form the composite product; wherein the nitrogen-containing reactant(s) comprise TPTA triprimary triamine(s), notably wherein the nitrogen-containing reactant(s) comprise at least 5% by dry weight of TPTA triprimary triamine(s).

A method of manufacturing a composite product, comprising: applying a binder composition, notably in the form of an aqueous solution, to non or loosely assembled matter to provide resinated matter, wherein the binder composition consists of a binder composition prepared by combining reactants comprising at least 50% by dry weight reducing sugar reactant(s) and at least 5% by dry weight nitrogen-containing reactant(s); and arranging the resinated matter to provide loosely arranged resinated matter; and subjecting the loosely arranged resinated matter to heat and/or pressure to cure the binder composition and to form the composite product; wherein the nitrogen-containing reactant(s) comprise TPTA triprimary triamine(s), notably wherein the nitrogen-containing reactant(s) comprise at least 5% by dry weight of TPTA triprimary triamine(s).

The present invention relates to a sizing composition for mineral fibers, especially glass fibers or rock fibers, containing a liquid phenolic resin having a free formaldehyde content, expressed with respect to the total weight of liquid, of 0.1% or less and an extender. Preferably, the liquid phenolic resin is mainly composed of phenol-formaldehyde and phenol-formaldehyde-amine condensates and has a water dilutability, at 20 C., at least equal to 1000%. Another subject of the present invention is the insulating products based on mineral fibers treated by said sizing composition.

The present invention relates to a sizing composition for mineral fibers, especially glass fibers or rock fibers, containing a liquid phenolic resin having a free formaldehyde content, expressed with respect to the total weight of liquid, of 0.1% or less and an extender. Preferably, the liquid phenolic resin is mainly composed of phenol-formaldehyde and phenol-formaldehyde-amine condensates and has a water dilutability, at 20 C., at least equal to 1000%. Another subject of the present invention is the insulating products based on mineral fibers treated by said sizing composition.