Polybenzoxazine comprises repeat units which comprise at least one unit corresponding to the formulae (I) or (II): ##STR00001##
in which Z.sub.1 and Z.sub.2, which are identical or different, represent an at least divalent, aliphatic, cycloaliphatic or aromatic bonding group comprising at least one carbon atom and optionally at least one heteroatom selected from O, S, N and P. Such a polybenzoxazine may be used as a metal-adhesive layer, in particular for the adhesive bonding of a metal substrate, in particular made of carbon steel, to a rubber.

Polybenzoxazine comprises repeat units which comprise at least one unit corresponding to the formulae (I) or (II): ##STR00001##
in which Z.sub.1 and Z.sub.2, which are identical or different, represent an at least divalent, aliphatic, cycloaliphatic or aromatic bonding group comprising at least one carbon atom and optionally at least one heteroatom selected from O, S, N and P. Such a polybenzoxazine may be used as a metal-adhesive layer, in particular for the adhesive bonding of a metal substrate, in particular made of carbon steel, to a rubber.

Use of a benzoxazine resin (12) for the bonding of a monofilament (10) made of glass-resin composite including glass filaments (101) embedded in a thermosetting polyester resin (102), to a thermoplastic material (14), notably polyester; process for adhering such a monofilament to the thermoplastic material (14), including at least the following steps: —impregnating the monofilament (10) with a benzoxazine resin (12) in the liquid state; —after impregnation, heat-treating the monofilament (10) thus impregnated, so as to at least partly polymerize the benzoxazine resin (12); —depositing, onto the monofilament (10) thus adhesively coated, the thermoplastic material (14) in the molten state; —after cooling, optionally heat-treating the monofilament thus coated (R-1, R-2) to totally polymerize the benzoxazine resin (12) on contact with the thermoplastic material (14).

Multicomposite material (R1, R2) including at least one monofilament (10) made of glass-resin composite including glass filaments (101) embedded in a thermoset polyester resin (102), this monofilament being covered with at least two superposed layers of different materials, a first layer (12) arranged on the surface of the monofilament and a second layer (14) of polyester thermoplastic material sheathing the whole, characterized in that the first layer (12) is a layer of benzoxazine and/or polybenzoxazine; finished articles or semi-finished products made of rubber, such as vehicle tyres, reinforced with such a material.

Multicomposite material (R1, R2) including at least one monofilament (10) made of glass-resin composite including glass filaments (101) embedded in a thermoset polyester resin (102), characterized in that said monofilament is coated with at least one layer (12) of benzoxazine; use of such a material as reinforcer in finished articles or semi-finished products made of rubber; finished articles or semi-finished products made of rubber, such as vehicle tyres, reinforced with such a material.

Multicomposite material (R1, R2) including at least one monofilament (10) made of glass-resin composite including glass filaments (101) embedded in a thermoset polyester resin (102), characterized in that said monofilament is coated with at least one layer (12) of benzoxazine; use of such a material as reinforcer in finished articles or semi-finished products made of rubber; finished articles or semi-finished products made of rubber, such as vehicle tyres, reinforced with such a material.

There is provided an epoxy composition which has difficulty in precipitating a crystal during storage, is homogeneous and can be stored for a long period; and a cured product of the composition having excellent transparency, heat resistance, and light resistance can be obtained on curing. An α-type tris-(2,3-epoxypropyl)-isocyanurate crystal including β-type tris-(2,3-epoxypropyl)-isocyanurate in the crystal in a ratio of 2% by mass to 15% by mass. A method for producing the α-type tris-(2,3-epoxypropyl)-isocyanurate crystal including step (i) separating β-type tris-(2,3-epoxypropyl)-isocyanurate contained in a tris-(2,3-epoxypropyl)-isocyanurate solution from the solution as a solid to obtain a crystal with an increased content ratio of α-type tris-(2,3-epoxypropyl)-isocyanurate.

There is provided an epoxy composition which has difficulty in precipitating a crystal during storage, is homogeneous and can be stored for a long period; and a cured product of the composition having excellent transparency, heat resistance, and light resistance can be obtained on curing. An α-type tris-(2,3-epoxypropyl)-isocyanurate crystal including β-type tris-(2,3-epoxypropyl)-isocyanurate in the crystal in a ratio of 2% by mass to 15% by mass. A method for producing the α-type tris-(2,3-epoxypropyl)-isocyanurate crystal including step (i) separating β-type tris-(2,3-epoxypropyl)-isocyanurate contained in a tris-(2,3-epoxypropyl)-isocyanurate solution from the solution as a solid to obtain a crystal with an increased content ratio of α-type tris-(2,3-epoxypropyl)-isocyanurate.

The invention relates to an amine terminated prepolymer and to a curable composition containing this prepolymer. These compositions are used to make sealants, coatings or adhesives useful in the field of construction, public works and civil engineering.

The invention relates to an amine terminated prepolymer and to a curable composition containing this prepolymer. These compositions are used to make sealants, coatings or adhesives useful in the field of construction, public works and civil engineering.