A two-component polyurethane composition containing at least 55% by weight of polybutadiene polyols based on the total amount of all polyols having an average molecular weight of at least 500 g/mol, and at least one latent hardener, where the ratio of the number of reactive groups in the latent hardener to the number of OH groups present is in the range from 0.02 to 0.4. The composition has a long open time, blister-free curing, a very low glass transition temperature, high elasticity and surprisingly high strength which is very constant over a wide temperature range. Furthermore, it has very good adhesion to metallic and nonmetallic substrates, causing barely any stress cracks on glassy thermoplastics.

An exemplary embodiment of the present invention provides a multilayer marking film including: an adhesive layer; a colored base layer having a first color; and a colored coating layer having a second color, in which the first color and the second color are different from each other, the colored coating layer, the colored base layer, and the adhesive layer are sequentially provided, the colored base layer includes a cured material of a base composition including: a urethane (meth)acrylate oligomer; a (meth)acrylate monomer including one or more selected from the group consisting of a cyclo-aliphatic (meth)acrylate monomer, an epoxy-based (meth)acrylate monomer, an aliphatic (meth)acrylate monomer, and a polyol-based (meth)acrylate monomer; and a pigment, and the colored coating layer is etched by laser irradiation.

An exemplary embodiment of the present invention provides a multilayer marking film including: an adhesive layer; a colored base layer having a first color; and a colored coating layer having a second color, in which the first color and the second color are different from each other, the colored coating layer, the colored base layer, and the adhesive layer are sequentially provided, the colored base layer includes a cured material of a base composition including: a urethane (meth)acrylate oligomer; a (meth)acrylate monomer including one or more selected from the group consisting of a cyclo-aliphatic (meth)acrylate monomer, an epoxy-based (meth)acrylate monomer, an aliphatic (meth)acrylate monomer, and a polyol-based (meth)acrylate monomer; and a pigment, and the colored coating layer is etched by laser irradiation.

A brittle adhesive sheet includes a film base material, and an adhesive layer provided at a first surface side of the film base material, wherein the film base material has a film base material main body formed of a polystyrene-based resin and a print receptive layer provided at a second surface side, opposite to a side of the film base material where the adhesive layer is provided, and the print receptive layer includes a polyester-based resin or an acrylic-based resin.

An adhesive article comprising first and second tacky latent adhesive layers disposed on respective first and second opposed major surfaces of a substrate. Each of the first and second tacky latent adhesive layers independently comprises at least one polymerizable component, and a redox initiator system comprising a transition metal complex that participates in a redox cycle, an oxidizing agent, and a blocked reducing agent represented by the formula ((I). Each of R.sup.1 and R.sup.2 are independently H, an alkyl, an aryl, or RPhoto5 with the proviso that at least one of R1 and R.sup.2 is RPhoto. R.sup.Photo represents a photoremovable group. Each of R.sup.3 and R.sup.4 independently represents H, an alkyl group, or an aryl group comprising a monovalent ester, ether, urethane, or carbonate group. Methods of making and using the adhesive articles are also disclosed.

##STR00001##

Provided is a laminated sheet including an upper paper layer and a release sheet layer, the upper paper layer including synthetic paper and an adsorbing layer, the synthetic paper, the adsorbing layer and the release sheet layer, in order, being laminated, wherein the adsorbing layer is a foam sheet of a resin composition, the resin composition containing crosslinking resultant of 100 parts by mass of a (meth)acrylic acid ester copolymer resin and 1 to 20 parts by mass of a carbodiimide crosslinking agent, the (meth)acrylic acid ester copolymer resin having a N-methylol group, a glass transition temperature of the (meth)acrylic acid ester copolymer resin being no more than −10° C., the release sheet layer consists of a thermoplastic resin sheet, and a rate of tensile elastic moduli is 0.1 to 10, the rate being calculated from a tensile elastic modulus of the upper paper layer and a tensile elastic modulus of the release sheet layer, and a peel strength of the adsorbing layer and the release sheet layer is 5 to 30 N/m, the laminated sheet using a new foamed resin layer having well-balanced properties, the amount of formaldehyde emitted from which is extremely small, as the adsorbing layer, the release sheet and the adsorbing layer having a proper release force.

The invention relates to a peel detection label that is a laminate including a support, a pattern layer formed in a part of the surface of the support, and a pressure-sensitive adhesive laminate having at least a low modulus layer (X), a high modulus layer (Y) and a pressure-sensitive adhesive layer (Z) in that order, in which the low modulus layer (X) has an n-layered structure (where n is an integer of 1 to 10) having a surface in contact with the support and the pattern layer and a surface in contact with the high modulus layer (Y), and the low modulus layer (X) satisfies a specific thickness-average shear storage elastic modulus.

The invention relates to a film comprising an optionally multilayer carrier layer; wherein one surface side of the carrier layer has been modified over part of its area either by surface activation or by printing with a print medium, such that the surface side has modified regions and unmodified regions; wherein the modified regions and the unmodified regions are coated over part or all of the area by a release material; and wherein the strength of adhesion of the release material to the carrier layer in the modified regions is different compared to the adhesion of the release material to the carrier layer in the unmodified regions.

An adhesive article that remains securely bonded to a substrate until a stimuli is applied. The article may be embodied as an adhesive tape, a bandage, or as other articles. The stimuli may be a change in temperature or application of a reduction that causes a structure within the article to break, creak, or otherwise disrupt to expose the adhesive to a solvent, such as via a difference in Coefficient of Thermal Expansion (CTE) or by exposing the article to a glass transition temperature.

The present disclosure generally relates to conformable stretch release adhesive and/or stretch-releasable, adhesive articles that are capable of attaching or adhering to a substrate and that can be removed from the substrate without causing damage to the substrate. The present disclosure also generally relates to methods of making and using such adhesive articles