Patent classifications
C09K3/18
Surface Treatment Agent and Method for Manufacturing Surface Treatment Body
Please substitute the new Abstract submitted herewith for the original Abstract: The present disclosure provides a surface treatment agent capable of not only being prepared by dissolving raw materials in a short time but also exerting a good water repellency imparting effect, and a method for manufacturing a surface treated body with the use of the surface treatment agent. The surface treatment agent according to the present disclosure includes the following components: (I) at least one kind selected from the group consisting of silicon compounds represented by the following formulas (1) and (2); (II) at least one kind selected from the group consisting of a nitrogen-containing heterocyclic compound represented by the following general formula (3), a nitrogen-containing heterocyclic compound represented by the following general formula (4) and imidazole; (III) an organic solvent; and (IV) at least one kind selected from the group consisting of silicon compounds represented by the following formulas (5) and (6).
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FLUOROPOLYETHER-GROUP-CONTAINING POLYMER, SURFACE TREATMENT AGENT, AND ARTICLE
A surface treatment agent that comprises a fluoropolyether-group-containing polymer represented by general formula (1), which has a hydroxylated silyl group or a hydrolyzable silyl group, and/or a product of partial (hydrolytic) condensation of the polymer. The surface treatment agent is capable of forming cured coating films which are excellent in terms of water and oil repellency and resistance to wear by steel wool and have a small water-sliding angle.
Rf—[CH(V).sub.2].sub.α Formula (1):
(In the formula, Rf is a mono- or divalent residue of a polymer including a fluorooxyalkylene group, the V moieties each independently are a monovalent group having a hydroxylated silyl group or hydrolyzable silyl group at the end and having no polar group besides the hydroxylated silyl group or hydrolyzable silyl group, and α is 1 or 2.)
FLUOROPOLYETHER-GROUP-CONTAINING POLYMER, SURFACE TREATMENT AGENT, AND ARTICLE
A surface treatment agent that comprises a fluoropolyether-group-containing polymer represented by general formula (1), which has a hydroxylated silyl group or a hydrolyzable silyl group, and/or a product of partial (hydrolytic) condensation of the polymer. The surface treatment agent is capable of forming cured coating films which are excellent in terms of water and oil repellency and resistance to wear by steel wool and have a small water-sliding angle.
Rf—[CH(V).sub.2].sub.α Formula (1):
(In the formula, Rf is a mono- or divalent residue of a polymer including a fluorooxyalkylene group, the V moieties each independently are a monovalent group having a hydroxylated silyl group or hydrolyzable silyl group at the end and having no polar group besides the hydroxylated silyl group or hydrolyzable silyl group, and α is 1 or 2.)
FILM AND METHOD FOR PRODUCING SAME
The present invention relates to a film including a base layer and an oil-containing layer formed on the base layer, wherein the oil-containing layer contains an oil ingredient which bleeds out from a surface of the oil-containing layer at a given temperature or lower, the base layer is an elemental metal or a multilayer structure including a metal layer, and the elemental metal or the metal layer is in contact with the oil-containing layer.
FILM AND METHOD FOR PRODUCING SAME
The present invention relates to a film including a base layer and an oil-containing layer formed on the base layer, wherein the oil-containing layer contains an oil ingredient which bleeds out from a surface of the oil-containing layer at a given temperature or lower, the base layer is an elemental metal or a multilayer structure including a metal layer, and the elemental metal or the metal layer is in contact with the oil-containing layer.
CURABLE COMPOSITION, ANTIFOGGING COATING AGENT, AND CURED FILM
Provided are a curable composition that provides a cured film excellent in antifogging properties, an antifogging coating agent containing the composition, and a cured film formed from a cured product of the composition. A curable composition according to an embodiment of the invention contains a (meth)acrylate compound (A), and a surfactant (B), wherein the component (A) contains a (meth)acrylate compound (A1) having an HLB value of 15.2 or more, and the content of the component (B) with respect to 100 parts by mass of the component (A) is 0.1 parts by mass or more and 20 parts by mass or less.
CURABLE COMPOSITION, ANTIFOGGING COATING AGENT, AND CURED FILM
Provided are a curable composition that provides a cured film excellent in antifogging properties, an antifogging coating agent containing the composition, and a cured film formed from a cured product of the composition. A curable composition according to an embodiment of the invention contains a (meth)acrylate compound (A), and a surfactant (B), wherein the component (A) contains a (meth)acrylate compound (A1) having an HLB value of 15.2 or more, and the content of the component (B) with respect to 100 parts by mass of the component (A) is 0.1 parts by mass or more and 20 parts by mass or less.
Liquid composition, coating film, and method for producing liquid composition
A liquid composition that can provide a film having excellent antifogging performance and weather resistance. The liquid composition contains nanocomposite particles. The nanocomposite particles contain metal particles and a perfluorocarbon sulfonic acid resin or a sulfonic acid salt resin thereof. The perfluorocarbon sulfonic acid resin has an equivalent weight of 550 to 800. The nanocomposite particles have an average particle size of 15 to 100 nm.
Method for producing water/oil repellent composition and method for producing water/oil repellent article
A method for producing a water/oil repellent composition can produce an article which is excellent in the oil repellency while maintaining the water repellency and the heavy-rain durability. The method includes mixing an emulsion of a polymer having from 10 to 50 mass % of units based on a monomer having a perfluoroalkyl group per all units and an emulsion of a monomer component containing at least 80 mass % of a monomer having a perfluoroalkyl group so that the proportion of the mass of the polymer will be from 50 to 99 mass % per the sum of the mass of the polymer and the total mass of the monomer component and then polymerizing the monomer component. The monomer component includes emulsified particles in the emulsion of the monomer component. The emulsified particles have an average particle size of from 50 to 600 nm.
Method for producing water/oil repellent composition and method for producing water/oil repellent article
A method for producing a water/oil repellent composition can produce an article which is excellent in the oil repellency while maintaining the water repellency and the heavy-rain durability. The method includes mixing an emulsion of a polymer having from 10 to 50 mass % of units based on a monomer having a perfluoroalkyl group per all units and an emulsion of a monomer component containing at least 80 mass % of a monomer having a perfluoroalkyl group so that the proportion of the mass of the polymer will be from 50 to 99 mass % per the sum of the mass of the polymer and the total mass of the monomer component and then polymerizing the monomer component. The monomer component includes emulsified particles in the emulsion of the monomer component. The emulsified particles have an average particle size of from 50 to 600 nm.