A hydrated inorganic oxide material capable of elongating from a planar shape to a fiber shape along a thickness direction of the planar shape, wherein the fiber shape is at least about 25 times greater in the thickness direction than the planar shape, and wherein during elongating a radial dimension of the hydrated inorganic oxide material changes by less than about 10% may be useful in a plurality of wellbore operations. For example, a method may include introducing a wellbore fluid comprising an aqueous base fluid and a hydrated inorganic oxide material into a wellbore penetrating a subterranean formation; and swelling the hydrated inorganic oxide material by contacting the hydrated inorganic oxide material with a polar amine compound such that the hydrated inorganic oxide material elongates from a planar shape to a fiber shape along a thickness direction of the planar shape.

A method of treating a subterranean formation penetrated by a wellbore, the method comprising pumping a wellbore fluid into the wellbore, the wellbore fluid comprising an aqueous base fluid and an environmentally friendly slurried gelling agent meeting at least two of the following three criteria: (1) Biodegradation: a) >60% in 28 days as measured by OECD 306 or any other OSPAR-accepted marine protocols, b) or in the absence of valid results for such tests: i. >60% in 28 days as measured by OECD 301B, 301C, 301D, 301F, 310, Freshwater BODIS or ii. >70% in 28 days as measured by OECD 301A, 301E); (2) Bioaccumulation: a) a bioconcentration factor of less than 100; b) log P.sub.ow≦3 and molecular weight >700, or c) if the conclusion of a weight of evidence expert judgment under Appendix 3 of OSPAR Agreement 2008-5 is positive; and (3) Aquatic Toxicity: a) LC.sub.50>10 mg/l or EC.sub.50>10 mg/l and performing a downhole operation.

Lipophilic fibers are effective media for cleaning non-aqueous fluids out of a subterranean wellbore. The fibers are preferably added to a drilling fluid, a spacer fluid, a chemical wash, a cement slurry or combinations thereof. Non-aqueous fluids, such as an oil-base mud or a water-in-oil emulsion mud, are attracted to the fibers as they circulate in the wellbore.

Lipophilic fibers are effective media for cleaning non-aqueous fluids out of a subterranean wellbore. The fibers are preferably added to a drilling fluid, a spacer fluid, a chemical wash, a cement slurry or combinations thereof. Non-aqueous fluids, such as an oil-base mud or a water-in-oil emulsion mud, are attracted to the fibers as they circulate in the wellbore.

A treatment fluid comprises: a liquid fluorinated compound; and at least one additive, wherein the additive: (A) comprises carbon and at least one fluorine functional group; and (B) is soluble or dispersible in the liquid fluorinated compound. A method of treating a portion of a well comprises: forming the treatment fluid; and introducing the treatment fluid into the well.

A treatment fluid comprises: a liquid fluorinated compound; and at least one additive, wherein the additive: (A) comprises carbon and at least one fluorine functional group; and (B) is soluble or dispersible in the liquid fluorinated compound. A method of treating a portion of a well comprises: forming the treatment fluid; and introducing the treatment fluid into the well.

A method of increasing the density of a saturated or near saturated salt (initial) brine, such as a monovalent or divalent salt solution, consists of first lowering the true crystallization temperature (TCT) of the saturated or near saturated salt brine to the eutectic point using a glycol and then adding dry salt to the brine of lower TCT to provide a brine of increased density. The TCT may be lowered by the addition of glycol to the saturated or near saturated salt brine. The dry salt is the same salt as the salt of the saturated or near saturated salt brine. The amount of dry salt added to the brine of lower TCT is an amount sufficient to render a saturated or near saturated brine. The density of the resulting brine is higher than the density of the saturated or near saturated salt (initial) brine.

A method of increasing the density of a saturated or near saturated salt (initial) brine, such as a monovalent or divalent salt solution, consists of first lowering the true crystallization temperature (TCT) of the saturated or near saturated salt brine to the eutectic point using a glycol and then adding dry salt to the brine of lower TCT to provide a brine of increased density. The TCT may be lowered by the addition of glycol to the saturated or near saturated salt brine. The dry salt is the same salt as the salt of the saturated or near saturated salt brine. The amount of dry salt added to the brine of lower TCT is an amount sufficient to render a saturated or near saturated brine. The density of the resulting brine is higher than the density of the saturated or near saturated salt (initial) brine.

Disclosed are compositions, methods, and systems of treating a well. A method may comprise providing a treatment fluid comprising a fluorous oil external phase, a salt-free non-chloride containing internal phase, and a fluorous-based surfactant; and introducing the treatment fluid into a wellbore. A treatment fluid composition may comprise a fluorous oil external phase, a salt-free non-chloride containing internal phase, and a fluorous-based surfactant.

Pressure buildup can be extremely problematic during subterranean operations when there is no effective way to vent or otherwise access one or more sealed annuli within a wellbore. This condition can compromise casing integrity and ultimately lead to failure of a well. Methods for mitigating annular pressure buildup can comprise: providing a wellbore containing an annular space having one or more annuli therein; selecting a pressure-mitigating material based upon one or more conditions present within the annular space, the pressure-mitigating material having a negative coefficient of thermal expansion; introducing the pressure-mitigating material into the annular space of the wellbore; sealing at least a portion of the annular space after introducing the pressure-mitigating material thereto; and subjecting the pressure-mitigating material to a temperature increase in the sealed portion of the annular space to decrease a volume occupied therein by the pressure-mitigating material.