Patent classifications
C09K8/52
Dual cation hydrate inhibitors
Dual cation hydrate inhibitor compositions and methods of using such compositions to, for example, inhibit the formation of gas hydrate agglomerates are provided. In some embodiments, such methods include introducing a hydrate inhibitor composition into a fluid, wherein the hydrate inhibitor composition includes at least one compound having the structural formula: ##STR00001##
wherein each of R.sup.1, R.sup.2, and R.sup.3 is independently a C.sub.1 to C.sub.6 hydrocarbon chain, wherein R.sup.4 is selected from the group consisting of hydrogen and any C.sub.1 to C.sub.50 hydrocarbon chain, wherein each of R.sup.5 and R.sup.6 is independently selected from the group consisting of hydrogen and a C.sub.1 to C.sub.50 hydrocarbon chain, wherein X.sup.− and Y.sup.− are counter anions, and wherein each of a and b is independently an integer from 1 to 10.
AN OIL FIELD CHEMICAL RELEASE SYSTEM
An oil field chemical release system for controlled release of an oil field chemical within a hydrocarbon reservoir, well, or wellbore, the oil field chemical release system comprising: a plurality of microcapsules, each microcapsule comprising an oil field chemical and a microencapsulant, wherein the oil field chemical is contained within the microencapsulant; and a continuous bulk polymer matrix, wherein the plurality of microcapsules are disposed within the continuous bulk polymer matrix, wherein the oil field chemical release system is configured to allow the oil field chemical to move through the microencapsulant into the continuous bulk polymer matrix and through the continuous bulk polymer matrix to be released through a surface of the bulk polymer matrix into the hydrocarbon reservoir, well, or wellbore at a controlled rate, and wherein the oil field chemical release system is configured to provide a release profile.
N,N,N′,N′-tetradodecyl-substituted diphenyl ether sulfonate anionic Gemini surfactant and synthesis method thereof
The present invention discloses a N,N,N′,N′-tetradodecyl-substituted diphenyl ether sulfonate anionic Gemini surfactant and the synthesis method thereof. It has a structural formula of: ##STR00001## and is prepared in a two-step reaction comprising: S1. subjecting 4,4′-diaminodiphenyl ether and bromododecane to an amine alkylation reaction to obtain N,N,N′,N′-tetradodecyl-substituted diphenyl ether; and S2. sulfonating the N,N,N′,N′-tetradodecyl-substituted diphenyl ether with concentrated sulfuric acid to produce the target product, N,N,N′,N′-tetradodecyl-substituted diphenyl ether sulfonate. The surfactant of the present invention has a high surface activity and can be synthesized with a simple procedure under mild reaction conditions, and can be easily separated and purified. The surfactant of the present invention is promising in applications for alkaline/surfactant in tertiary oil recovery, for polymer/surfactant binary compound flooding, alkaline/surfactant/polymer tertiary compound flooding, microemulsion emulsifier, and the like, and may also be compounded with common surfactants to lower the cost, thereby enabling its application in a large scale.
HYDRATE-INHIBITING CHEMICAL INJECTOR AND RELATED METHODS
Systems and methods of injecting hydrate inhibiting chemicals into a gaseous fuel line of a burner are described. One system includes: an oilfield burner; a gaseous fuel line connected to the oilfield burner; a storage tank containing hydrate-inhibiting chemicals; a hydrate-inhibiting chemical supply line connected between the storage tank and the gaseous fuel line; and a control valve connected to control flow in the hydrate-inhibiting chemical supply line in response to the operation of the oilfield burner. A kit may be provided with at least the hydrate-inhibiting chemical supply line and control valve.
HYDRATE-INHIBITING CHEMICAL INJECTOR AND RELATED METHODS
Systems and methods of injecting hydrate inhibiting chemicals into a gaseous fuel line of a burner are described. One system includes: an oilfield burner; a gaseous fuel line connected to the oilfield burner; a storage tank containing hydrate-inhibiting chemicals; a hydrate-inhibiting chemical supply line connected between the storage tank and the gaseous fuel line; and a control valve connected to control flow in the hydrate-inhibiting chemical supply line in response to the operation of the oilfield burner. A kit may be provided with at least the hydrate-inhibiting chemical supply line and control valve.
Use of controlled release acid system in treatment of wells
Release of hydrochloric acid, hydrofluoric acid and fluoroboric acid into a well may be controlled by introducing into the well an aqueous fluid containing ammonium chloride, ammonium bifluoride, ammonium fluoroborate, ammonium tetrafluoroborate or a mixture thereof and a breaker. After being introduced into the well, the ammonium salt reacts with the breaker and the acid is released into the well.
Use of controlled release acid system in treatment of wells
Release of hydrochloric acid, hydrofluoric acid and fluoroboric acid into a well may be controlled by introducing into the well an aqueous fluid containing ammonium chloride, ammonium bifluoride, ammonium fluoroborate, ammonium tetrafluoroborate or a mixture thereof and a breaker. After being introduced into the well, the ammonium salt reacts with the breaker and the acid is released into the well.
Filter cake removal compositions and methods of making and using same
A breaker composition comprising (i) a first acid precursor, (ii) a second acid precursor and (iii) an aqueous fluid wherein the first acid precursor has an effective operating temperature of from about 15° C. to about 120° C. and the second acid precursor has an effective operating temperature of from about 30° C. to about 180° C.
ENHANCED SCALE INHIBITOR SQUEEZE TREATMENT USING A CHEMICAL ADDITIVE
Compositions and methods for the use in scale inhibitor squeeze treatments are provided. In some embodiments the present disclosure provides a method including introducing a pre-flush fluid into at least a portion of a subterranean formation, the pre-flush fluid including a choline chloride chemical additive; and introducing a treatment fluid including a scale inhibitor into the portion of the subterranean formation after at least a portion of the pre-flush fluid has been introduced into the portion of the subterranean formation.
ENHANCED SCALE INHIBITOR SQUEEZE TREATMENT USING A CHEMICAL ADDITIVE
Compositions and methods for the use in scale inhibitor squeeze treatments are provided. In some embodiments the present disclosure provides a method including introducing a pre-flush fluid into at least a portion of a subterranean formation, the pre-flush fluid including a choline chloride chemical additive; and introducing a treatment fluid including a scale inhibitor into the portion of the subterranean formation after at least a portion of the pre-flush fluid has been introduced into the portion of the subterranean formation.