A method for the stimulation of a hydrocarbon-bearing formation, said method comprising the steps of providing a wellbore in need of stimulation; inserting a plug in the wellbore at a location slightly beyond a predetermined location; inserting a perforating tool having an outside surface and a spearhead or breakdown acid composition into the wellbore, wherein said outside surface of said tool is pre-treated prior to downhole insertion with a grease containing a first corrosion inhibitor adapted to eliminate/minimize/reduce the corrosion inflicted upon it by the exposure of the acid for the duration of the fracking or stimulation and wherein said acidic composition comprises a second corrosion inhibitor which reacts with said first corrosion inhibitor to generate a corrosion protective layer onto said surface; positioning the tool at said predetermined location; perforating the wellbore with the tool thereby creating a perforated area; allowing the spearhead acid to come into contact with the perforated area for a predetermined period of time sufficient to prepare the formation for stimulation; removing the tool from the wellbore; and initiating the fracking of the perforated area using a stimulation fluid. Also disclosed is a corrosion inhibiting compound or composition for use with the acid composition.

Corrosion inhibition compositions and methods useful for inhibiting corrosion are provided. The corrosion inhibition compositions comprise at least one coupling agent and at least one corrosion inhibitor, wherein the at least one coupling agent is at least one of one or more ether amines, one or more ether amine oxides, and at least one combination thereof, and the at least one corrosion inhibitor is at least one selected from one or more thiophosphates, one or more polyphosphate esters, one or more imidazolines, one or more quinolines, one or more alkynols, one or more alkynol derivatives, and at least one combination thereof. The methods for inhibiting corrosion on metal surfaces utilize the disclosed corrosion inhibiting compositions.

Corrosion inhibition compositions and methods useful for inhibiting corrosion are provided. The corrosion inhibition compositions comprise at least one coupling agent and at least one corrosion inhibitor, wherein the at least one coupling agent is at least one of one or more ether amines, one or more ether amine oxides, and at least one combination thereof, and the at least one corrosion inhibitor is at least one selected from one or more thiophosphates, one or more polyphosphate esters, one or more imidazolines, one or more quinolines, one or more alkynols, one or more alkynol derivatives, and at least one combination thereof. The methods for inhibiting corrosion on metal surfaces utilize the disclosed corrosion inhibiting compositions.

Compounds, compositions and methods are provided for reducing, inhibiting, or preventing corrosion of a surface, using a polyester polyamine compound. The polyester polyamine compound having a structure corresponding to Formula 1 or 2, or a salt thereof:

##STR00001##

wherein R.sub.1 is independently alkylene; R.sub.2 is independently hydrogen or —COR.sub.4; R.sub.3 is independently alkyl, alkenyl, aryl, or alkaryl; R.sub.4 is independently alkyl or alkenyl; R.sub.10 and R.sub.11 are each independently hydrogen, alkyl, or alkaryl; m is an integer from 1 to 10; n is an integer from 3 to 10; and wherein at least one R.sub.2 is —COR.sub.4.

Compositions and methods for inhibiting corrosion of metal surfaces are disclosed herein. Also disclosed are methods of manufacturing the corrosion inhibitors compositions. The corrosion inhibitor compositions include the reaction product of a dicarbonyl compound with thioglycolic acid. The compositions may include other components, such as a solvent, a hydrogen sulfide scavenger, or a biocide.

A modified drilling mud includes a drilling mud selected from a group consisting of water-based mud (WBM), oil-based mud (OBM) and synthetic-based mud (SBM), and a liquid treatment composition including water and collectively 35-55 weight percent of one or more hydroxide compounds, wherein a ratio of the liquid treatment composition to the drilling mud in the modified drilling mud is in a range of 10 gallons of the liquid treatment composition per 42,000 gallons of drilling mud to 100 gallons of the liquid treatment composition per 42,000 gallons of drilling mud.

A modified drilling mud includes a drilling mud selected from a group consisting of water-based mud (WBM), oil-based mud (OBM) and synthetic-based mud (SBM), and a liquid treatment composition including water and collectively 35-55 weight percent of one or more hydroxide compounds, wherein a ratio of the liquid treatment composition to the drilling mud in the modified drilling mud is in a range of 10 gallons of the liquid treatment composition per 42,000 gallons of drilling mud to 100 gallons of the liquid treatment composition per 42,000 gallons of drilling mud.

Methods for the fracking or stimulation of a hydrocarbon-bearing formation are provided in multiple embodiments. According to one method, it comprises the steps of: providing a wellbore having a casing; inserting a plug in the wellbore at a predetermined location; inserting a perforating tool and an acidic composition into the wellbore; wherein the acidic composition includes a corrosion inhibiting composition comprising at least two compounds selected from: Group A-I, and wherein at least two compounds are selected from different groups of the Groups A-I.

Methods for the fracking or stimulation of a hydrocarbon-bearing formation are provided in multiple embodiments. According to one method, it comprises the steps of: providing a wellbore having a casing; inserting a plug in the wellbore at a predetermined location; inserting a perforating tool and an acidic composition into the wellbore; wherein the acidic composition includes a corrosion inhibiting composition comprising at least two compounds selected from: Group A-I, and wherein at least two compounds are selected from different groups of the Groups A-I.

A composition for inhibiting corrosion and/or removing hydrocarbonaceous deposits in oil and gas applications is provided. The composition comprises an iron sulfide dissolver, an organic solvent, and a corrosion inhibitor.