Patent classifications
C09K8/54
PREPARATION METHOD FOR THE PLANT-BASED NANO CORROSION INHIBITION BACTERICIDE FOR OILFIELD AND APPLICATION THEREOF
The present invention discloses a preparation method for the plant-based nano corrosion inhibition bactericide for oilfield, comprising the following steps: Step 1. Prepare the aloin liquid; Step 2. Stir the carbon nanotube, hydroxyethyl methacrylate and acrylic acid to react for 4 h at a constant temperature of 80° C. to get the carbon nanotube after fiber treatment, namely the modified carbon nanotube; Step 3. Mix the aloin liquid with imidazoline-ammonium-salt, add acetonitrile, and then add modified carbon nanotube, increase the temperature to 95° C. stir and react for 12 hours, and filter after naturally cooling down to room temperature and get the carbon nanotube loaded with bactericide; Step 4. Stir the carbon nanotube loaded with bactericide, diphenylmethane diisocyanate and polycaprolactone to react for 6 hours at a constant temperature of 95° C. and in the reaction process, continuously inject helium to get the target bactericide.
PREPARATION METHOD FOR THE PLANT-BASED NANO CORROSION INHIBITION BACTERICIDE FOR OILFIELD AND APPLICATION THEREOF
The present invention discloses a preparation method for the plant-based nano corrosion inhibition bactericide for oilfield, comprising the following steps: Step 1. Prepare the aloin liquid; Step 2. Stir the carbon nanotube, hydroxyethyl methacrylate and acrylic acid to react for 4 h at a constant temperature of 80° C. to get the carbon nanotube after fiber treatment, namely the modified carbon nanotube; Step 3. Mix the aloin liquid with imidazoline-ammonium-salt, add acetonitrile, and then add modified carbon nanotube, increase the temperature to 95° C. stir and react for 12 hours, and filter after naturally cooling down to room temperature and get the carbon nanotube loaded with bactericide; Step 4. Stir the carbon nanotube loaded with bactericide, diphenylmethane diisocyanate and polycaprolactone to react for 6 hours at a constant temperature of 95° C. and in the reaction process, continuously inject helium to get the target bactericide.
Vegetable oil invert emulsion hydrogen sulfide mitigating drilling fluid and method of drilling subterranean geological formation
A method of drilling a subterranean geological formation is described. The method includes driving a drill bit to form a wellbore into the subterranean geological formation thereby producing a formation fluid including hydrogen sulfide (H.sub.2S). The method includes injecting a drilling fluid into the subterranean geological formation through the wellbore. The drilling fluid composition includes 0.25 to 2 wt. % of a primary H.sub.2S scavenger, which is potassium permanganate, and an invert emulsion, which includes a continuous phase including a vegetable oil which is at least one selected from the group consisting of corn oil, soybean oil, rapeseed oil, canola oil, sunflower oil, safflower oil, peanut oil, and cottonseed oil and a dispersive phase including water. The potassium permanganate present in the drilling fluid composition reacts with the H.sub.2S present in the formation fluid to produce a dispersion of manganese-containing particles which are at least one selected from the group consisting of manganese sulfide and manganese sulfate.
Vegetable oil invert emulsion hydrogen sulfide mitigating drilling fluid and method of drilling subterranean geological formation
A method of drilling a subterranean geological formation is described. The method includes driving a drill bit to form a wellbore into the subterranean geological formation thereby producing a formation fluid including hydrogen sulfide (H.sub.2S). The method includes injecting a drilling fluid into the subterranean geological formation through the wellbore. The drilling fluid composition includes 0.25 to 2 wt. % of a primary H.sub.2S scavenger, which is potassium permanganate, and an invert emulsion, which includes a continuous phase including a vegetable oil which is at least one selected from the group consisting of corn oil, soybean oil, rapeseed oil, canola oil, sunflower oil, safflower oil, peanut oil, and cottonseed oil and a dispersive phase including water. The potassium permanganate present in the drilling fluid composition reacts with the H.sub.2S present in the formation fluid to produce a dispersion of manganese-containing particles which are at least one selected from the group consisting of manganese sulfide and manganese sulfate.
Using Synthetic Acid Compositions as Alternatives to Conventional Acids in The Oil And Gas Industry
An aqueous synthetic acid composition is disclosed for use in oil industry activities, the composition comprising: lysine and hydrogen chloride in a molar ratio ranging from 1 to 1:12.5, preferably from more than 1:5 to 1:8.5. The composition can also further comprise a metal iodide or iodate; an alcohol or derivative thereof. The composition demonstrates advantageous properties over known synthetic acids at temperatures above 90° C. The composition is useful in various oil and gas industry operations. Preferred embodiments of the composition provide substantial advantages in matrix acidizing by increasing the effectiveness of wormholing as compared to conventional mineral acids such as HCl.
Using Synthetic Acid Compositions as Alternatives to Conventional Acids in The Oil And Gas Industry
An aqueous synthetic acid composition is disclosed for use in oil industry activities, the composition comprising: lysine and hydrogen chloride in a molar ratio ranging from 1 to 1:12.5, preferably from more than 1:5 to 1:8.5. The composition can also further comprise a metal iodide or iodate; an alcohol or derivative thereof. The composition demonstrates advantageous properties over known synthetic acids at temperatures above 90° C. The composition is useful in various oil and gas industry operations. Preferred embodiments of the composition provide substantial advantages in matrix acidizing by increasing the effectiveness of wormholing as compared to conventional mineral acids such as HCl.
ALKYL LACTONE-DERIVED CORROSION INHIBITORS
Disclosed are alkyl lactone-derived hydroxyamide and alkyl lactone-derived hydroxyester used in compositions and methods for inhibiting corrosion. The alkyl lactone-derived hydroxyamide and alkyl lactone-derived hydroxyester are reaction products of an alkyl lactone and an amine, and an alkyl lactone and an alcohol, respectively.
ALKYL LACTONE-DERIVED CORROSION INHIBITORS
Disclosed are alkyl lactone-derived hydroxyamide and alkyl lactone-derived hydroxyester used in compositions and methods for inhibiting corrosion. The alkyl lactone-derived hydroxyamide and alkyl lactone-derived hydroxyester are reaction products of an alkyl lactone and an amine, and an alkyl lactone and an alcohol, respectively.
DOWNHOLE ACID STIMULATION METHOD WITH CORROSION INHIBITION
A method of inhibiting corrosion of metal during acid stimulation of an oil and gas well that involves treating the oil and gas well with an acidic treatment fluid that includes 10 to 28 wt. % of an acid, based on a total weight of the acidic treatment fluid, and a corrosion inhibitor composition containing gelatin, wherein the gelatin is present in the acidic treatment fluid in a concentration of 0.1 to 10% by weight per total volume of the acidic treatment fluid.
DOWNHOLE ACID STIMULATION METHOD WITH CORROSION INHIBITION
A method of inhibiting corrosion of metal during acid stimulation of an oil and gas well that involves treating the oil and gas well with an acidic treatment fluid that includes 10 to 28 wt. % of an acid, based on a total weight of the acidic treatment fluid, and a corrosion inhibitor composition containing gelatin, wherein the gelatin is present in the acidic treatment fluid in a concentration of 0.1 to 10% by weight per total volume of the acidic treatment fluid.