The present invention relates to a photoinduced thermochromic or thermoluminescent composition, comprising: a) nanoparticles capable of absorbing near-infrared (NIR) radiation and converting the NIR radiation into heat, in particular metal gold nanoparticles; b) one or more phase change materials (PCM) selected from the group consisting of: b1) a PCM capable of acting as chromic or fluorochromic promoter; and b2) a PCM uncapable of acting as chromic or fluorochromic promoter; c) one or more dyes selected from the group consisting of: c1) a dye capable of modifying its colour- or emission-properties when the PCM changes between the solid state and the liquid state; and c2) a dye uncapable of modifying its colour- or emission-properties when the PCM between the solid state and the liquid state; and articles containing it. It also relates to processes for their preparation and their uses in therapy, cosmetics, diagnostics, optics and anti-fake technology.

The present invention relates to a photoinduced thermochromic or thermoluminescent composition, comprising: a) nanoparticles capable of absorbing near-infrared (NIR) radiation and converting the NIR radiation into heat, in particular metal gold nanoparticles; b) one or more phase change materials (PCM) selected from the group consisting of: b1) a PCM capable of acting as chromic or fluorochromic promoter; and b2) a PCM uncapable of acting as chromic or fluorochromic promoter; c) one or more dyes selected from the group consisting of: c1) a dye capable of modifying its colour- or emission-properties when the PCM changes between the solid state and the liquid state; and c2) a dye uncapable of modifying its colour- or emission-properties when the PCM between the solid state and the liquid state; and articles containing it. It also relates to processes for their preparation and their uses in therapy, cosmetics, diagnostics, optics and anti-fake technology.

Provided is a moisture curable polyurethane composition that is a moisture curable polyurethane having an isocyanate group on one end of a molecule thereof. The moisture curable polyurethane composition contains a moisture curable polyurethane (A) and an organic solvent (B). The moisture curable polyurethane (A) is obtainable by reacting a polyisocyanate compound having at least two isocyanate groups in a molecule thereof (A1) with a low-molecular weight polyol compound having at least two hydroxyl groups in a molecule thereof and having a number average molecular weight of 50-300 (A2). Also provided is a laminate including an optical substrate and a polyurethane resin layer comprising the moisture curable polyurethane composition.

An electrochemical aptamer-based (E-AB) sensor is disclosed. The sensor is a closed bipolar electrode having a first end and a second end. The first end comprises an electrochromic material. The second end comprises an electrocatalyst and an oligonucleotide aptamer tethered to the second end. Further, the oligonucleotide aptamer is labelled with a redox indicator.

Novel reaction media for electron donating and electron accepting components in colour-change compositions are described. The compound is of formula (VI); R.sub.1, and R.sub.2 are independently selected from an optionally substituted linear or branched alkyl group, alkenyl group, alkoxy group, aryl group and an alkylene aryl group having from 5 to 22 carbon atoms; X.sub.1 and X.sub.2 are independently selected from —OC(O)—, —CO.sub.2— and O; Y.sub.1, and Y.sub.2 are independently selected from hydrogen, halogen, R.sub.1, —OR.sub.1; y is independently 0 or 1; and suitably the groups R.sub.1X.sub.1— and —X.sub.2R.sub.2 are independently in the ortho or meta position. The compounds are useful in ink compositions, writing implements containing the compound and medical and industrial applications in which temperature sensitive colour change may be required. ##STR00001##

Novel reaction media for electron donating and electron accepting components in colour-change compositions are described. The compound is of formula (VI); R.sub.1, and R.sub.2 are independently selected from an optionally substituted linear or branched alkyl group, alkenyl group, alkoxy group, aryl group and an alkylene aryl group having from 5 to 22 carbon atoms; X.sub.1 and X.sub.2 are independently selected from —OC(O)—, —CO.sub.2— and O; Y.sub.1, and Y.sub.2 are independently selected from hydrogen, halogen, R.sub.1, —OR.sub.1; y is independently 0 or 1; and suitably the groups R.sub.1X.sub.1— and —X.sub.2R.sub.2 are independently in the ortho or meta position. The compounds are useful in ink compositions, writing implements containing the compound and medical and industrial applications in which temperature sensitive colour change may be required. ##STR00001##

A light-modulating material of which the light transmittance can be controlled over a wide region from visible light to infrared light by voltage application is provided. The light-modulating material comprises a graphene-like carbon material having an aspect ratio of 3 or more and 330 or less.

A light-modulating material of which the light transmittance can be controlled over a wide region from visible light to infrared light by voltage application is provided. The light-modulating material comprises a graphene-like carbon material having an aspect ratio of 3 or more and 330 or less.

The present invention relates to a photochromic compound having a core fused ring structure represented by at least one of the following Formula (Ia) or Formula (IIa), (Ia) (IIa) Independently for each of Formula (Ia) and Formula (IIa): R.sup.1 is in each case independently selected from substituted or unsubstituted aryl, substituted or unsubstituted heteroaryl, —SO.sub.2R.sup.5, or —C(O)—XR.sup.5, where, X is selected from a single bond, —N(R.sup.5)—, or —O—, and R.sup.5 in each case is independently selected from hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, or substituted or unsubstituted heteroaryl; and B and B′ are each independently selected from substituted or unsubstituted alkenyl, substituted or unsubstituted alkynyl, substituted or unsubstituted aryl, or substituted or unsubstituted heteroaryl. The present invention also relates to photochromic compositions and articles including such photochromic compounds.

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The present invention relates to a photochromic compound having a core fused ring structure represented by at least one of the following Formula (Ia) or Formula (IIa), (Ia) (IIa) Independently for each of Formula (Ia) and Formula (IIa): R.sup.1 is in each case independently selected from substituted or unsubstituted aryl, substituted or unsubstituted heteroaryl, —SO.sub.2R.sup.5, or —C(O)—XR.sup.5, where, X is selected from a single bond, —N(R.sup.5)—, or —O—, and R.sup.5 in each case is independently selected from hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, or substituted or unsubstituted heteroaryl; and B and B′ are each independently selected from substituted or unsubstituted alkenyl, substituted or unsubstituted alkynyl, substituted or unsubstituted aryl, or substituted or unsubstituted heteroaryl. The present invention also relates to photochromic compositions and articles including such photochromic compounds.

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