The invention relates to compounds of the formula I, ##STR00001##
in which
R, A, n, L.sup.1, L.sup.2, L.sup.3 and X have the meanings given in Claim 1, to a process for their preparation, and to liquid-crystalline media comprising at least one compound of the formula I and electro-optical displays containing a liquid-crystalline medium of this type.

A method of manufacturing a modified liquid crystal polymer includes: providing a liquid crystal polymer having a first melting point; heating the liquid crystal polymer to a first temperature and maintaining at the first temperature for a first time period, in which the first temperature is lower than or equal to the first melting point; and cooling the liquid crystal polymer to a second temperature to form a first modified liquid crystal polymer, the second temperature being lower than the first temperature, the first modified liquid crystal polymer having a second melting point, in which the second melting point is higher than the first melting point.

A method of manufacturing a modified liquid crystal polymer includes: providing a liquid crystal polymer having a first melting point; heating the liquid crystal polymer to a first temperature and maintaining at the first temperature for a first time period, in which the first temperature is lower than or equal to the first melting point; and cooling the liquid crystal polymer to a second temperature to form a first modified liquid crystal polymer, the second temperature being lower than the first temperature, the first modified liquid crystal polymer having a second melting point, in which the second melting point is higher than the first melting point.

An aspect of the present invention relates to a method for producing a cholesteric liquid crystal based shell. The method comprises producing a cholesteric liquid crystal shell, solidifying the cholesteric liquid crystal shell so as to obtain a solid shell and perforating the solid shell. A second aspect of the present invention relates to a cholesteric liquid crystal based solid shell comprising a perforation. Other aspects of the present invention pertain to a coating composition comprising a plurality of cholesteric liquid crystal based solid shells, an item comprising a tag that comprises the cholesteric liquid crystal based solid shells and a method for authenticating the item.

Provided are compositions that include a nematic colloid, the nematic colloid comprising a nematic liquid crystal and a key colloid; and a lock colloid, the lock colloid optionally having at least two arms extending therefrom, the lock colloid being configured for assembly with the key colloid of the nematic colloid, the assembly optionally being mediated by a dipole interaction between the colloid and the lock colloid, by a disinclination line of the nematic colloid, or any combination thereof. Also provided are related methods. The disclosed compositions and methods can be used to, e.g., assemble chain and lattice structures from the key colloids by exploiting disinclination lines and dipole defects of the components of the compositions.

A polymer liquid crystal compound with which a light absorption anisotropic film having a high alignment degree can be formed, a liquid crystalline composition, a light absorption anisotropic film which is formed of the liquid crystalline composition, a laminate, and an image display device. The liquid crystalline composition includes a polymer liquid crystal compound which contains a repeating unit represented by Formula (1) and a dichroic substance. In Formula (1), a difference between a log P value of P1, L1, and SP1 and a log P value of M1 is 4 or greater. In Formula (1), P1 represents a main chain of the repeating unit, L1 represents a single bond or a divalent linking group, SP1 represents a spacer group, M1 represents a mesogenic group, and T1 represents a terminal group. ##STR00001##

An optically transparent actuator apparatus is provided that includes an optically transparent bi-stable member including an optically transparent liquid crystalline polymer layer. The bi-stable member is structured to move from a first state to a second state in response to a first stimulus and from the second state to the first state in response to a second stimulus. Also, a display apparatus includes a plate member and an actuator assembly coupled to the plate member. The actuator assembly includes a number of optically transparent liquid crystalline polymer layers, wherein each of the optically transparent liquid crystalline polymer layers is structured to move from a first state to a second state in response to a first stimulus.

Disclosed is an optical assembly having a first variable transmission layer comprising a first electro-optically active material between a first pair of substrates, a second variable transmission layer comprising a second electro-optically active material between a second pair of substrates, and an electronically switchable birefringent layer, that is capable of altering the phase of incident light, situated between the first and second variable transmission layers. The layers are arranged such that light passing through the optical assembly can be altered based on the voltage applied to each layer. The light transmission levels can be altered between maximally transmissive, minimally transmissive, and semi-transparent levels between the maximally and minimally transmissive levels.

An optical system in one aspect of the present disclosure includes a first light source, a second light source, a first spatial optical phase modulator, a second spatial optical phase modulator, and a projector. The first spatial optical phase modulator outputs first phase-modulated light based on an input light having a first wavelength from the first light source. The second spatial optical phase modulator outputs second phase-modulated light based on input light having a second wavelength from the second light source. The projector projects the first phase-modulated light and the second phase-modulated light on a target. The first spatial optical phase modulator is a liquid crystal device including a first liquid crystal layer. The second spatial optical phase modulator is a liquid crystal device including a second liquid crystal layer. The first liquid crystal layer includes a liquid crystal material different from that of the second liquid crystal layer.

An optical element includes an optically-anisotropic layer that is formed of a liquid crystal composition including a liquid crystal compound having a polymerizable group, in which a ratio of a bend elastic constant K33 to a splay elastic constant K11 in the liquid crystal composition satisfies 0.8≤K33/K11≤1.2 at any temperature of a nematic temperature range, and the optically-anisotropic layer has a liquid crystal alignment pattern in which a direction of an optical axis derived from the liquid crystal compound changes while continuously rotating in at least one in-plane direction.