Patent classifications
C09K19/04
Fluoro-boron pyrrole liquid crystal compounds containing 8-(bisphenylethynyl)-ester group flexible multiple ring, preparation method and use thereof
A series of 8-(bisphenylethynyl)-ester flexible multiple ring-containing fluoroboron pyrrole liquid crystal dyes are synthesized by introducing a diphenylethynyl rigid structure at position 8 of a boron-dipyrromethene core via a Sonogashira coupling reaction, and a flexible multiple ring such as bicyclohexane, or cholesterol is connected to the biphenylethynyl via an esterification reaction. The dye compounds all have maximum emission wavelengths in methylene chloride concentrated around 525 nm, present green fluorescence, and show good dichroic colour ratios and ordered parameters in E7 liquid crystal. The liquid crystal compounds are in a liquid crystal intermediate phase within the range of 100-280° C., and may be used for manufacturing liquid crystal display products, especially as guest dyes for guest-host mode liquid crystal displays. The response time can be improved and a rapid response effect achieved when the compounds are added to E7 liquid crystal and used for a guest-host display mode.
Fluoro-boron pyrrole liquid crystal compounds containing 8-(bisphenylethynyl)-ester group flexible multiple ring, preparation method and use thereof
A series of 8-(bisphenylethynyl)-ester flexible multiple ring-containing fluoroboron pyrrole liquid crystal dyes are synthesized by introducing a diphenylethynyl rigid structure at position 8 of a boron-dipyrromethene core via a Sonogashira coupling reaction, and a flexible multiple ring such as bicyclohexane, or cholesterol is connected to the biphenylethynyl via an esterification reaction. The dye compounds all have maximum emission wavelengths in methylene chloride concentrated around 525 nm, present green fluorescence, and show good dichroic colour ratios and ordered parameters in E7 liquid crystal. The liquid crystal compounds are in a liquid crystal intermediate phase within the range of 100-280° C., and may be used for manufacturing liquid crystal display products, especially as guest dyes for guest-host mode liquid crystal displays. The response time can be improved and a rapid response effect achieved when the compounds are added to E7 liquid crystal and used for a guest-host display mode.
Image display device and circularly polarizing plate with photosensitive adhesive
An image display device which suppresses destruction of an image display panel due to static electricity carried by a phase difference film, and has excellent adhesiveness between the phase difference film and the image display panel even in a moisture-heat environment, and a circularly polarizing plate with a photosensitive adhesive. The image display device includes a circularly polarizing plate having a linear polarizer and a phase difference film, and an image display panel in this order from a viewing side, in which the phase difference film and the image display panel are bonded by a pressure-sensitive adhesive, the phase difference film has an optically anisotropic layer obtained by polymerizing a polymerizable liquid crystal composition containing at least one kind of polymerizable liquid crystal compound having a predetermined structure, and the pressure-sensitive adhesive contains a polymer having an acid value of 1 to 30 mgKOH/g and an antistatic agent.
Image display device and circularly polarizing plate with photosensitive adhesive
An image display device which suppresses destruction of an image display panel due to static electricity carried by a phase difference film, and has excellent adhesiveness between the phase difference film and the image display panel even in a moisture-heat environment, and a circularly polarizing plate with a photosensitive adhesive. The image display device includes a circularly polarizing plate having a linear polarizer and a phase difference film, and an image display panel in this order from a viewing side, in which the phase difference film and the image display panel are bonded by a pressure-sensitive adhesive, the phase difference film has an optically anisotropic layer obtained by polymerizing a polymerizable liquid crystal composition containing at least one kind of polymerizable liquid crystal compound having a predetermined structure, and the pressure-sensitive adhesive contains a polymer having an acid value of 1 to 30 mgKOH/g and an antistatic agent.
Laminate, organic electroluminescent device, and liquid crystal display device
The present invention provides: a laminate which has a polarizer and an optically anisotropic layer and has excellent thermal durability; and an organic electroluminescent device and a liquid crystal display device, which include the laminate. The laminate according to the embodiment of the present invention is a laminate having two substrates, and a polarizing plate disposed between the two substrates, in which the polarizing plate has an optically anisotropic layer and a polarizer, the optically anisotropic layer is formed of a composition containing a polymerizable liquid crystal compound represented by Formula (I), the polarizer contains a polyvinyl alcohol-based resin, and a moisture permeability of the substrate is 10.sup.−3 g/m.sup.2.Math.day or less. ##STR00001##
Laminate, organic electroluminescent device, and liquid crystal display device
The present invention provides: a laminate which has a polarizer and an optically anisotropic layer and has excellent thermal durability; and an organic electroluminescent device and a liquid crystal display device, which include the laminate. The laminate according to the embodiment of the present invention is a laminate having two substrates, and a polarizing plate disposed between the two substrates, in which the polarizing plate has an optically anisotropic layer and a polarizer, the optically anisotropic layer is formed of a composition containing a polymerizable liquid crystal compound represented by Formula (I), the polarizer contains a polyvinyl alcohol-based resin, and a moisture permeability of the substrate is 10.sup.−3 g/m.sup.2.Math.day or less. ##STR00001##
Liquid crystal composition and liquid crystal display element including the same
An object of the present invention is to provide a liquid crystal composition suitable for producing liquid crystal display elements which reduces the risk of the formation of droplet traces during production and allows a liquid crystal material to be ejected at a constant rate during an ODF process without deteriorating the properties of the liquid crystal display element, such as dielectric anisotropy, viscosity, nematic-phase upper-limit temperature, nematic-phase stability at a low temperature, and γ.sub.1, and the image sticking resistance of the display element, and a liquid crystal display element including the liquid crystal composition. Provided are a liquid crystal composition having a negative dielectric anisotropy, the liquid crystal composition including one or more compounds represented by General Formula (I), one or more compounds represented by General Formula (II), and the compound represented by Formula (IIIb-1) and a liquid crystal display element including the liquid crystal composition.
Household appliance component
A household appliance component has a base element with at least one photoluminescent layer and at least one light guide. The light guide is configured to couple in and transmit light containing at least one excitation wavelength of the photoluminescent layer to the photoluminescent layer. An optical switch is assigned to the light guide to route light coupled in the light guide depending on the temperature of the optical switch. Further a household appliance contains the at least one household appliance component.
Household appliance component
A household appliance component has a base element with at least one photoluminescent layer and at least one light guide. The light guide is configured to couple in and transmit light containing at least one excitation wavelength of the photoluminescent layer to the photoluminescent layer. An optical switch is assigned to the light guide to route light coupled in the light guide depending on the temperature of the optical switch. Further a household appliance contains the at least one household appliance component.
Positive dielectric anisotropic liquid crystal composition and liquid crystal display device
A positive dielectric anisotropic liquid crystal composition includes one or more compounds of formula I and one or more compounds of formula II: ##STR00001##
wherein R1 represents cyclopropyl, cyclobutyl or cyclopentyl, R2, R3 and R4 are as defined in the specification, and a liquid crystal display device. The liquid crystal composition has positive dielectric properties, a high charge retention ratio, a low rotary viscosity, a fast response time, and especially a high transmittance, and is suitable for manufacturing a TFT-LCD with a high transmittance and a fast response.