Compositions comprising multi-fluorinated olefins and HFC-32 are disclosed. Such compositions are useful particularly for in stationary refrigeration and air conditioning equipment.

This invention relates to compositions comprising 1,2-dichloro-1,2-difluoroethylene (i.e., CFO-1112) and an additional component. The compositions described herein may be useful, for example, in heat transfer applications.

Disproportionation in a refrigerant comprising HFO-1132 is suppressed. A composition comprising a refrigerant, the refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)), 2,3,3,3-tetrafluoro-1-propene (R1234yf), and propane.

The present disclosure provides a composition comprising a refrigerant that has characteristics of having a coefficient of performance (COP) and a refrigerating capacity equivalent to or higher than those of R404A, and having a sufficiently low GWP. More specifically, the present disclosure provides a composition comprising a refrigerant, the refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (HFC-32), and 2,3,3,3-tetrafluoropropene (HFO-1234yf), wherein the total concentration of the three components is 99.5% by mass or more, based on the entire refrigerant, and three components have a mass ratio that falls within a region surrounded by a figure passing through the following 4 points in a ternary composition diagram whose three vertices represent the three components: point A (HFO-1132(E)/HFC-32/HFO-1234yf=51.8/1.0/47.2 mass %), point B (HFO-1132(E)/HFC-32/HFO-1234yf=35.3/1.0/63.7 mass %), point C (HFO-1132(E)/HFC-32/HFO-1234yf=10.1/18.0/71.9 mass %), and point D (HFO-1132(E)/HFC-32/HFO-1234yf=27.8/18.0/54.2 mass %).

The invention provides a composition comprising 1,1-difluoroethene (R-1132a), difluoromethane (R-32), 2,3,3,3-tetrafluoropropene (R-1234yf), optionally carbon dioxide (CO.sub.2, R-744), and, optionally, 1,1,2-trifluoroethene (R-1123).

The present disclosure addresses the problem of providing a refrigerant composition that has a low GWP and a refrigerating capacity equivalent to that of R404A, which is currently widely used. As a solution to the problem, the present disclosure provides a composition containing carbon dioxide and a mixture of fluorinated hydrocarbons, the mixture containing difluoromethane (R32), pentafluoroethane (R125), 2,3,3,3-tetrafluoropropene (R1234yf), 1,1,1,2-tetrafluoroethane (R134a), and carbon dioxide (CO.sub.2) in specific concentrations.

A working fluid for a heat cycle containing trifluoroethylene and 2,3,3,3-tetrafluoropropene. The working fluid exhibits a pressure change of 0.00 and a temperature change of 0.5° C. or less in an evaluation of self-decomposition conducted by enclosing a sample of the working fluid and a platinum wire in a spherical pressure resistant reactor having an internal capacity of 650 cm.sup.3 at a temperature is 250° C. and a pressure of 0.98 MPaG, fusing the platinum wire to apply an energy of about 30 J to the working fluid, and measuring the temperature change and pressure change in the pressure resistant reactor after applying energy to the working fluid.

The present disclosure provides a mixed refrigerant having four types of performance, i.e., an excellent coefficient of performance and refrigerating capacity that allow it to serve as an alternative refrigerant for R410A, a sufficiently low GWP, and non-flammability. Specifically, the present disclosure provides a composition comprising a refrigerant, the refrigerant comprising trifluoroiodomethane (CF.sub.3I) and difluoromethane (R32), wherein the contents of CF.sub.3I and R32 in the refrigerant are respectively 48 mass %≥CF.sub.3I≥46 mass % and 54 mass %≥R32≥52 mass %, based on the total amount of CF.sub.3I and R32 taken as 100 mass %.

To provide a working fluid for heat cycle having a low global warming potential, which can replace R410A, a composition for a heat cycle system comprising it, and a heat cycle system employing the composition.

A working fluid for heat cycle, which comprises trifluoroethylene and 2,3,3,3-tetrafluoropropene, wherein the total proportion of trifluoroethylene and 2,3,3,3-tetrafluoropropene based on the entire amount of the working fluid is from 70 to 100 mass %, and the proportion of trifluoroethylene based on the total amount of trifluoroethylene and 2,3,3,3-tetrafluoropropene is from 35 to 95 mass %, a composition for a heat cycle system comprising the working fluid for heat cycle, and a heat cycle system employing the composition.

A refrigerant replacement method for a refrigeration apparatus is intended to replace a first refrigerant charged into a refrigerant circuit of the refrigeration apparatus with a second refrigerant. The second refrigerant is used together with a refrigerating machine oil having a higher additive content by percentage than another refrigerating machine oil to be used together with the first refrigerant. The method includes: a refrigerant recovery step of recovering the first refrigerant from the refrigerant circuit; an oil charging step of additionally charging a refrigerating machine oil having a predetermined additive content by percentage into the refrigerant circuit; and a refrigerant charging step of charging the second refrigerant into the refrigerant circuit. The predetermined additive content by percentage is higher than the additive content by percentage of the refrigerating machine oil to be used together with the second refrigerant.