The invention provides a composition comprising 1,1-difluoroethene (R-1132a), difluoromethane (R-32), 2,3,3,3-tetrafluoropropene (R-1234yf), optionally carbon dioxide (CO.sub.2, R-744), and, optionally, 1,1,2-trifluoroethene (R-1123).

The present invention provides a composition, such as a refrigerant composition comprising 1,1-difluoroethene (vinylidene fluoride, R-1132a); trifluoromethane (R-23); and one or more compound selected from hexafluoroethane (R-116), ethane (R-170) and carbon dioxide (R-744, CO.sub.2).

Compositions and methods are configured to reduce flammability in a heating, ventilation, and air conditioning (HVAC) system having R32 refrigerant included in the refrigerant composition. Refrigerant compositions and methods can be used for retrofitting, servicing, controlling flammability, improving performance, lubricant solubility and miscibility, and improving the safety of an HVAC system.

A fluoropropene composition comprising E-1,3,3,3-tetrafluoropropene, 1,1,3,3,3-pentafluoropropene, and 2,3,3,3-tetrafluoropropene, wherein the total amount of 1,1,3,3,3-pentafluoropropene and 2,3,3,3-tetrafluoropropene is 1.0 wt. % or less, based on the total weight of the fluoropropene composition. A method of producing the fluoropropene, composition and methods for using the fluoropropene composition are also disclosed.

A composition including between 4 and 6 wt. % of difluoromethane, between 2.5 and 3.5 wt. % of pentafluoroethane, and between 91 and 93.5 wt. % of tetrafluoropropene. The use of the composition as replacement for R404A, R452A, R22, R134a, R245fa, R152a, R422, R502, R407A, R407F, R407C, R1234yf or R1234ze. A heat-transfer composition including the composition and at least one additive chosen from nanoparticles, stabilizing agents, surfactants, tracing agents, fluorescent agents, odorous agents, lubricants, and solubilizing agents.

Disclosed are refrigerants, and heat transfer compositions, heat transfer systems and heat transfer methods containing such refrigerants, wherein the refrigerant comprises at least about 97% by weight of the following three components (a)-(c) and the following fourth component if present: (a) trans-1-chloro-3,3,3-trifluoropropene (HFCO-1233zd(E)), (b) trans-1,3,3,3-tetrafluoropropene (HFO-1234ze(E)), (c) trifluoroiodomethane (CF3I), and. (d) 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea).

In accordance with the present invention refrigerant compositions are disclosed. The compositions comprise a refrigerant mixture consisting essentially of HFC-32, HFO-1234yf, and CO.sub.2. The compositions are useful as refrigerants in processes to produce cooling and heating, in methods for replacing refrigerant R-410A, and in refrigeration, air conditioning or heat pump systems. These inventive compositions match cooling capacity for R-410A within ±10% with GWP less than 350 or less than 300.

An object of the present invention is to provide a mixed refrigerant having three types of performance; i.e., a refrigerating capacity (also referred to as cooling capacity) and a coefficient of performance (COP) that are equivalent to those of R410A, and a sufficiently low GWP. Provided as a means for achieving the object is a composition comprising a refrigerant, the refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and 2,3,3,3-tetrafluoro-1-propene (R1234yf).

In accordance with the present invention refrigerant compositions are disclosed. The compositions comprise a refrigerant mixture consisting essentially of HFC-32, HFO-1234yf, and CO.sub.2. The compositions are useful as refrigerants in processes to produce cooling and heating, in methods for replacing refrigerant R-410A, and in refrigeration, air conditioning or heat pump systems. These inventive compositions match cooling capacity for R-410A within 20% with GWP less than 250 or less than 200.

Various uses of monochlorotrifluoropropenes, in combination with one or more other components, including other fluoroalkenes, hydrocarbons; hydrofluorocarbons (HFCs), ethers, alcohols, aldehydes, ketones, methyl formate, formic acid, water, trans-1,2-dichloroethylene, carbon dioxide and combinations of any two or more of these, in a variety of applications, including as blowing agents, are disclosed.