Terpene-based spotting fluid compositions and processes for freeing differentially stuck pipe are provided. A spotting fluid composition includes a terpene and an acid, such that the acid initiates an exothermic polymerization reaction of the terpene. Another spotting fluid composition includes an invert emulsion having a terpene external phase and a non-miscible organic hygroscopic fluid internal phase. The terpene emulsion spotting fluid composition may be introduced downhole in the vicinity of a portion of a differentially stuck pipe such that the spotting fluid composition contacts a filter cake surrounding the portion of the differentially stuck pipe. An acid may be introduced downhole in the vicinity of a portion of a differentially stuck pipe such that the acid initiates an exothermic polymerization reaction of the terpene of the terpene emulsion spotting fluid composition.

Various embodiments disclosed relate to clay stabilizers. In various embodiments, the present invention provides a method of treating a subterranean formation, including obtaining or providing a composition including a clay stabilizer having the structure Y—R.sup.1—(O—R.sup.2).sub.x—Y. The variable R.sup.1 can be a substituted or unsubstituted (C.sub.1-C.sub.20)hydrocarbylene. At each occurrence, R.sup.2 can independently be a substituted or unsubstituted (C.sub.1-C.sub.20)hydrocarbylene. At each occurrence, Y can be independently selected from a substituted or unsubstituted amino group, a substituted or unsubstituted ammonium group, a nitro group, a substituted or unsubstituted amine oxide group, and a substituted or unsubstituted (C.sub.1-C.sub.20)hydrocarbyloxy group, wherein at least one terminal group Y is a substituted amino group, a substituted or unsubstituted ammonium group, a substituted or unsubstituted amine oxide group, or a nitro group. The variable x can be an integer between 1 and 200,000. The method also includes placing the composition in a subterranean formation.

The present disclosure provides a drilling fluid lubricant and a preparation method and use thereof. The preparation method includes steps of: 1) mixing styrene and water, then adding a nano-inorganic intermediate, a crosslinking agent and an emulsifier and stirring to obtain a first mixture; 2) under an inert atmosphere, stirring the first mixture to obtain an intermediate emulsion; then heating the intermediate emulsion to 70-85 C., then adding an initiator, keeping temperature and stirring for 7-10 hours to obtain an emulsion of polystyrene nanocomposite with a particle size of 40-90 nm; the emulsion of polystyrene nanocomposite being sequentially subjected to a granulating treatment to obtain polystyrene nanocomposite particles; 3) mixing industrial base oil, polystyrene nanocomposite particles and industrial oleic acid, and stirring evenly at room temperature to obtain the drilling fluid lubricant.

Alkyl ester spotting fluid compositions and processes for freeing differentially stuck pipe are provided. An alkyl ester spotting fluid composition includes an invert emulsion having an alkyl ester as the external phase and water as the internal phase. In some embodiments, the alkyl ester spotting fluid composition may include the alkyl ester invert emulsion and an emulsifier. The alkyl ester spotting fluid composition may be introduced downhole in the vicinity of a portion of a differentially stuck pipe such that the spotting fluid composition contacts the mudcake and frees the differentially stuck pipe.

Alkyl ester spotting fluid compositions and processes for freeing differentially stuck pipe are provided. An alkyl ester spotting fluid composition includes an invert emulsion having an alkyl ester as the external phase and water as the internal phase. In some embodiments, the alkyl ester spotting fluid composition may include the alkyl ester invert emulsion and an emulsifier. The alkyl ester spotting fluid composition may be introduced downhole in the vicinity of a portion of a differentially stuck pipe such that the spotting fluid composition contacts the mudcake and frees the differentially stuck pipe.

Methods and systems for the treatment of wells are disclosed. A method for treating a well comprises providing a treatment fluid comprising calcium-aluminate cement, water, and a cement set retarder; and introducing the treatment fluid into a wellbore. A system for treating a well comprises a treatment fluid comprising calcium-aluminate cement, water, and a cement set retarder; a vessel to contain the treatment fluid; a pumping system coupled to the vessel to pump the treatment fluid; and a conduit coupled to the pumping system.

Alkyl ester spotting fluid compositions and processes for freeing differentially stuck pipe are provided. An alkyl ester spotting fluid composition includes an invert emulsion having an alkyl ester as the external phase and water as the internal phase. In some embodiments, the alkyl ester spotting fluid composition may include the alkyl ester invert emulsion and an emulsifier. The alkyl ester spotting fluid composition may be introduced downhole in the vicinity of a portion of a differentially stuck pipe such that the spotting fluid composition contacts the mudcake and frees the differentially stuck pipe.

Alkyl ester spotting fluid compositions and processes for freeing differentially stuck pipe are provided. An alkyl ester spotting fluid composition includes an invert emulsion having an alkyl ester as the external phase and water as the internal phase. In some embodiments, the alkyl ester spotting fluid composition may include the alkyl ester invert emulsion and an emulsifier. The alkyl ester spotting fluid composition may be introduced downhole in the vicinity of a portion of a differentially stuck pipe such that the spotting fluid composition contacts the mudcake and frees the differentially stuck pipe.

Alkyl ester spotting fluid compositions and processes for freeing differentially stuck pipe are provided. An alkyl ester spotting fluid composition includes an invert emulsion having an alkyl ester as the external phase and water as the internal phase. In some embodiments, the alkyl ester spotting fluid composition may include the alkyl ester invert emulsion and an emulsifier. The alkyl ester spotting fluid composition may be introduced downhole in the vicinity of a portion of a differentially stuck pipe such that the spotting fluid composition contacts the mudcake and frees the differentially stuck pipe.

Various embodiments disclosed relate to guanidine- or guanidinium-containing clay or shale stabilizers for treatment of subterranean formations. In various embodiments, the present invention provides a method of treating a subterranean formation that can include placing a composition including a clay or shale stabilizer including at least one of a substituted guanidine group and a substituted guanidinium group in a subterranean formation.