A method of stimulating petroleum production includes introducing a fracturing fluid into a petroleum formation, thereby creating at least one fracture to stimulate the petroleum production. The fracturing fluid is introduced into the petroleum formation at a pressure above the breakdown pressure of the formation. The fracturing fluid includes a plurality of proppants where from 1 to 50 wt. % of the plurality of proppants includes micro proppants having a particle size ranging from 0.5 to 150 μm, and from 50 to 99 wt. % of the plurality of proppants includes macro proppants having a particle size greater than 100 mesh.

A method and compounds for enhanced oil recovery (EOR) including flooding of a mixture of water and one or more of the compounds in a geological formation. The compounds have a fluoroalkyl group.

Methods and treatments fluids for treating a wellbore. One example method introduces the treatment fluid into the wellbore. The treatment fluid comprises an aqueous fluid, an aminopolycarboxylic acid, a nanoparticle dispersed, and an organic solvent. The treatment fluid has a pH in a range between about 5 to about 9. The method further includes contacting a rock surface in the subterranean formation; wherein at least a portion of the rock surface is coated with a hydrocarbon. The treatment fluid removes a portion of the hydrocarbon from the rock surface and alters the rock surface to be water-wet.

This disclosure relates to a fracturing fluid including an acrylamide-based copolymer, a graphene oxide additive, and a crosslinker, and methods of using the fracturing fluid to reduce fluid friction during treatment of a subterranean formation.

Producing proppants with nanoparticle proppant coatings includes reacting nanoparticles with at least one of an alkoxysilane solution or a halosilane solution to form functionalized nanoparticles and coating proppant particles with unfunctionalized organic resin, a strengthening agent, and the functionalized nanoparticles to produce the nanoparticle coated proppant. The functionalized nanoparticles include nanoparticles having at least one attached omniphobic moiety including at least a fluoroalkyl-containing group including 1H, 1H, 2H, 2H-perfluorooctylsilane. The strengthening agent comprises at least one of carbon nanotubes, silica, alumina, mica, nanoclay, graphene, boron nitride nanotubes, vanadium pentoxide, zinc oxide, calcium carbonate, or zirconium oxide. Additionally, increasing a rate of hydrocarbon production from a subsurface formation through the use of the nanoparticle coated proppant includes producing a first rate of production of hydrocarbons from the subsurface formation, introducing a hydraulic fracturing fluid into the subsurface formation, and increasing hydrocarbon production by producing a second rate of production of hydrocarbons.

The present invention discloses a preparation method for the plant-based nano corrosion inhibition bactericide for oilfield, comprising the following steps: Step 1. Prepare the aloin liquid; Step 2. Stir the carbon nanotube, hydroxyethyl methacrylate and acrylic acid to react for 4 h at a constant temperature of 80° C. to get the carbon nanotube after fiber treatment, namely the modified carbon nanotube; Step 3. Mix the aloin liquid with imidazoline-ammonium-salt, add acetonitrile, and then add modified carbon nanotube, increase the temperature to 95° C. stir and react for 12 hours, and filter after naturally cooling down to room temperature and get the carbon nanotube loaded with bactericide; Step 4. Stir the carbon nanotube loaded with bactericide, diphenylmethane diisocyanate and polycaprolactone to react for 6 hours at a constant temperature of 95° C. and in the reaction process, continuously inject helium to get the target bactericide.

A slickwater fracturing fluid that includes a brine with dissolved solids, an anionic friction reducing additive, a polysaccharide, and a nanomaterial that includes nanoparticles with an average particle size between about 1 nm and about 500 nm. The polysaccharide and the anionic friction reducing additive synergistically reduce friction of the slickwater fracturing fluid so as to increase an injection rate of the slickwater fracturing fluid. Also, the polysaccharide, the anionic friction reducing additive, and the nanomaterial synergistically provide viscosity to the slickwater fracturing fluid so as to increase proppant transport capability. Also described is a method of fracturing a subterranean formation by pumping the slickwater fracturing fluid into a borehole and fracturing the subterranean formation with the slickwater fracturing fluid.

The present specification refers to a patent of invention for a foam formulation and its use in the temporary plugging of pipes, where the foam has volumetric and time stability, is prepared from a solution containing surfactant, co-surfactant, alkaline substance and LDH nanoparticles, is able to have its viscosity increased over time and remain intact for 8 hours or more even under pressure differences of up to 0.1 bar and a temperature of 60° C. and then it is able to disperse simply by using water or even the fluid transported in the pipeline. The LDH nanoparticle reinforced foam of the present invention can be applied in pipes that need to be plugged when they are undergoing maintenance, either to prevent incandescent soldering splashes from coming into contact with an explosive atmosphere or to avoid contamination in the pipe interior, among other applications. The present invention belongs to (but is not limited to) the field of plugs for pipes with explosive atmospheres and can be applied in systems that require temporary plugs that can be easily remover by using water or another solvent.

Embodiments relate to use of graphite nanoplatelets (GnP) to enhance the mechanical and durability characteristics of cement that may be used as cement sheaths in wellbores of oil and gas wells. Generally, undesired permeability of cement is caused by diffusion of trapped oil and/or natural gas through the cementitious matrix of the cement, leading to material degradation of the cement. Methods disclosed involve using modified GnPs (having physically modified surfaces or chemically modified surfaces energies) to generate a cementitious nanocomposite with uniformly dispersed GnPs, which can effectively arrest the undesired diffusion mechanism. Modified GnPs can also increase the strength of interfacial adhesion (e.g., interfacial bonds and interfacial energies) between the GnP and the cement matrix (e.g., hydrations of the cement). Physical modification of GnP can involve non-covalent treatment techniques. Chemical modification of GnP can involve covalent treatment techniques.

A variety of fluid loss control compositions and methods are provided for controlling fluid loss in a cementing operation. As described herein, polyelectrolyte complex nanoparticles and fluid loss control compositions containing polyelectrolyte complex nanoparticles can be effective for fluid loss control in a variety of cementing operations. Methods of making and methods of using the electrolyte complex nanoparticles and fluid loss control compositions containing polyelectrolyte complex nanoparticles are also provided. The polyelectrolyte complex nanoparticles can include a polycation polymer such as a branched chain polyethylenimine, and a polyanion polymer such as polyacrylic acid or poly(vinylsulfonic) acid. The polyelectrolyte complex nanoparticles can contain additional additives such as metal ions or fluid loss additives such as a cellulose polymer.