Relatively low molecular weight, branched polyethyleneimine (B-PE), a specific class of polyamine, has been shown to be effective at inhibiting the formation metal naphthenate precipitate (MNP) in systems and fluids that include an organic phase and an aqueous phase where the system or fluid further contains metal ions and tetra acid, and in particular the addition of low molecular weight, B-PE molecules prevents the formation of metal naphthenate precipitates/deposits in the fluids. Inhibition of alkali earth metal naphthenates (e.g. calcium naphthenate) and alkali metal naphthenates (e.g. sodium naphthenate) are particular non-limiting embodiments.

A dry polymer powder for use in enhanced petroleum recovery without being prehydrated before being added to water or brine to be introduced into a wellhead. The dry polymer powder consisting of at least one of a polyacrylamide, a copolymer of acrylamide and acrylic acid, a functionalized derivatives thereof, a galactomannan, or cellulosic polymer or derivatives thereof, and the polymer can be crosslinked or not crosslinked, provided that if they are homo- or co-polymers of acrylic acid, they are not crosslinked. The dry polymer powder is sized between two size limits, namely at least about 85 wt % of particles of a size smaller than about 40-mesh, and at least 75 wt % of particles of a size greater than 200-mesh, which size range ensures that the dry polymer powder will efficiently hydrate in the water or brine within about one minute without forming fisheyes.

The disclosure relates to an electrocrushing drilling fluid with an electrocrushing drilling base fluid including a non-polar oil, water, and glycerin. The base fluid may further include a polar oil and an alkylene carbonate. The electrocrushing drilling fluid may further contain at least one additive. The electrocrushing drilling fluid may have a dielectric constant or dielectric strength of at least a set amount, an electric conductivity less than a set amount, or a combination of these properties. The disclosure further relates to an electrocrushing drilling system containing the electrocrushing drilling fluid and an electrocrushing drill bit.

Systems and methods for hydrofluoric (HF) acidizing compositions compatible with sensitive metallurgic grades. The systems and methods may include preparing an aqueous acidizing composition comprising one or more acid components, hydrofluoric acid, and one or more corrosion inhibitors; and injecting the aqueous composition into a subterranean formation containing sensitive metallurgic components via a wellbore.

Methods including preparing a treatment fluid comprising an aqueous base fluid, a gelling agent, and crosslinker-coated particulates, wherein the crosslinker-coated particulates are formed by at least partially coating a particulate with a stabilizing agent, and at least partially coating the particulate with a first crosslinking agent atop the stabilizing agent, wherein the stabilizing agent imparts a hydrophobic nature to the particulate when the stabilizing agent is at least partially coated onto the particulate; introducing the treatment fluid into a subterranean formation, and reacting the first crosslinking agent with the gelling agent in the treatment fluid so as to crosslink the gelling agent and suspend the crosslinker-coated particulates.

An aqueous synthetic acid composition for use in oil industry activities comprises lysine and hydrogen chloride in a molar ratio ranging from 1:3 to 1:12.5, preferably from more than 1:5 to 1:8.5. The composition can also further comprise a metal iodide or iodate; an alcohol or derivative thereof. The composition demonstrates advantageous properties over known synthetic acids at temperatures above 90° C. The composition is useful in various oil and gas industry operations. Preferred embodiments of the composition provide substantial advantages in matrix acidizing by increasing the effectiveness of wormholing as compared to conventional mineral acids such as HC1.

A treatment fluid that includes an aqueous fluid, an inorganic acid, and a hydrophobically modified quaternized polysaccharide may be useful in mitigating corrosion of metal surfaces by the inorganic acid. For example, a wellbore operation may include introducing the treatment fluid into a wellbore penetrating a subterranean formation and contacting a metal surface with a treatment fluid.

Nano-sized mixed metal oxide carriers capable of delivering a well treatment additive for a sustained or extended period of time in the environment of use, methods of making the nanoparticles, and uses thereof are described herein. The nanoparticles can have a formula of:

A/[M.sub.x.sup.1M.sub.y.sup.2M.sub.z.sup.3]O.sub.nH.sub.m

where x is 0.03 to 3, y is 0.01 to 0.4, z is 0.01 to 0.4 and n and m are determined by the oxidation states of the other elements, and M.sup.1 can be aluminum (Al), gallium (Ga), indium (In), or thallium (Tl). M.sup.2 and M.sup.3 are not the same and can be a Column 2 metal, Column 14 metal, or a transition metal. A is can be a treatment additive.

A composition for inhibiting corrosion and/or removing hydrocarbonaceous deposits in oil and gas applications is provided. The composition comprises an iron sulfide dissolver, an organic solvent, and a corrosion inhibitor.

A composition for efficient metal chelation includes (i) a primary chelant; (ii) a coordination enhancing additive; and (iii) a solvent. A wellbore servicing fluid includes (i) a primary chelant; (ii) a coordination enhancing additive; and (iii) a solvent.