A composite photoalignment layer for aligning liquid crystal molecules includes: a monomeric material; a photoinitiator or a thermal initiator; and an azo dye material. A method for preparing a composite photoalignment layer for aligning liquid crystal molecules includes: mixing, in solution form, a monomeric material, a photoinitiator or a thermal initiator, and an azo dye material; coating the mixed solution onto a substrate to form a thin film; exposing the thin film to polarized light; and, with a thermal initiator, heating the thin film to polymerize the monomeric material and form a solid thin film.

The present disclosure relates to a photo-alignment material, a liquid crystal display panel, and a manufacturing method thereof. The chemical structural formulas of photo-alignment material includes an orientation anchor group, a linking group, a photosensitive group with one or more photosensitive cyclohexanone, and an alignment group with a linear or branched alkyl having 3-15 carbon atoms; wherein the orientation anchor group, the linking group, the photosensitive group and the alignment group are connected successively. Through the above-mentioned manner, the present disclosure can simplify the manufacturing process of the liquid crystal display panel, and improve the product quality.

The present specification provides a multi-layer liquid crystal film including: a substrate; a first alignment film provided on the substrate; a first liquid crystal film provided on the first alignment film; a second alignment film provided on the first liquid crystal film and comprising a multifunctional acrylate; and a second liquid crystal film provided on the second alignment film, and a method for manufacturing a polarizing plate, including: laminating the multi-layer liquid crystal film to a polarizer, and peeling off the substrate.

An example of the present invention provides a quantum rod layer including: a photo-induced polymer including a base polymer aligned along a first direction and a photo-reactive group combined to the base polymer; and a quantum rod aligned along the first direction.

A liquid crystal panel includes substrates, a liquid crystal layer between the substrates, a spacer provided on an opposite surface of one of the substrates, and an alignment film provided on an opposite surface of another substrate. The display surface is curved around a curved axis or formed to be bendable around the curved axis, and the spacer directly or indirectly abuts on the alignment film provided on the opposite surface of the other substrate. The alignment film is a horizontal alignment film that contains a polymer having an alkylene chain structure having two or more carbon atoms in a main chain and allows liquid crystal molecules in the liquid crystal layer to be aligned horizontally to the alignment film, and in the alignment film provided on the opposite surface of the other substrate, the polymer is aligned such that the alkylene chain structure extends parallel to the curved axis.

A liquid crystal display device of the present invention includes a thin-film transistor substrate, a counter substrate facing the thin-film transistor substrate, a liquid crystal layer provided between the thin-film transistor substrate and the counter substrate, an alignment film provided on the thin-film transistor substrate; a sealing material which bonds together the thin-film transistor substrate and the counter substrate at the periphery of the liquid crystal layer, and a polymerized layer provided on the liquid crystal layer-side surface of the alignment film. The alignment film contains a first polymer and a second polymer of a different type from that of the first polymer and is chemically bonded to the sealing material, the first polymer and the second polymer contained in the alignment film are mixed in a surface layer in contact with the liquid crystal layer, and the first polymer and the second polymer have different photo-functional groups.

A photo-alignment film of the present invention includes a polymer layer containing a photoreactive polymer and metal nanoparticles dispersed in the polymer layer at a concentration of 10.sup.9 particles/(cm.sup.2100 nm) or more and 10.sup.19 particles/(cm.sup.2100 nm) or less. The metal nanoparticles have an absorption peak in a wavelength region of 420 nm or less. An absorbance A1 at the absorption peak of the metal nanoparticles and an absorbance A2 at an absorption peak of the polymer layer satisfy a relationship represented by the following formula 1:

0.2A1/A225(Formula 1).

A photo-alignment material in which an alignment film can be formed parallel to a vibration direction of light and a tilt angle of the alignment film is easily controlled and a photo-alignment method using the photo-alignment material are provided. A photo-alignment material of the present invention contains a photo-responsive substance having a threshold value of responding light intensity.

Ink-jet printable compositions including nanoparticles capped with a protective layer of hydrocarbon chains and a single solvent exhibiting a single evaporation rate and having a specifically defined viscosity and surface tension that result in uniform and printable alignment layers for liquid crystal materials. Patterned liquid crystal-containing cells are also disclosed including one or more layers including the same or different nanoparticles capped with a protective layer of hydrocarbon chains printed on a surface of a substrate or even another nanoparticle-containing layer. Methods for producing the cells are also disclosed, including the step of printing a pattern on one or more portions of a cell surface utilizing a composition comprising the capped nanoparticles. Devices including the cells are also disclosed.

Disclosed is a liquid crystal display (LCD) device. The LCD device includes a first substrate and a second substrate facing each other, a liquid crystal layer between the first substrate and the second substrate, an alignment layer on at least one of the first and second substrates for alignment of liquid crystals in the liquid crystal layer, and a sealant in an edge area of each of the first and second substrates to bond the first substrate to the second substrate, the sealant including a diene compound.