A liquid crystal display device includes a TFT substrate having a first alignment film and an opposing substrate having a second alignment film with liquid crystals sandwiched therebetween. One of the first and second alignment films, comprises a first polyimide produced via polyamide acid ester containing cyclobutane as a precursor and a second polyimide produced via polyamide acid as a precursor. The polyamide acid has a higher polarity than that of the polyamide acid ester. The one of the first and second alignment films is responsive to photo-alignment. A first side of the one of the first and second alignment films is adjacent to the liquid crystals, and a second side thereof is closer to one of the TFT substrate and the counter substrate than the first side. The first side contains more of the first polyimide and less of the second polyimide than the second side.

The present invention is a liquid crystal display device including a liquid crystal layer containing a liquid crystal material, a sealing member surrounding the liquid crystal layer in a plan view, a pair of substrates sandwiching the liquid crystal layer, and an alignment control layer being in contact with the liquid crystal layer in a region surrounded by the sealing member in a plan view. The alignment control layer aligns a liquid crystal compound in the liquid crystal material in a direction horizontal to faces of the substrates, and contains a polymer formed by polymerization of at least one monomer, and the at least one monomer contains a monomer represented by the following Chemical formula (1): ##STR00001##
wherein at least one hydrogen atom of the phenylene group may be the same or different and may be substituted with a halogen atom, a methyl group, an ethyl group, or a propyl group.

A photo-alignment film of the present invention includes a polymer layer containing a photoreactive polymer and metal nanoparticles dispersed in the polymer layer at a concentration of 10.sup.9 particles/(cm.sup.2×100 nm) or more and 10.sup.19 particles/(cm.sup.2×100 nm) or less. The metal nanoparticles have an absorption peak in a wavelength region of 420 nm or less. An absorbance A1 at the absorption peak of the metal nanoparticles and an absorbance A2 at an absorption peak of the polymer layer satisfy a relationship represented by the following formula 1:
0.2≤A1/A2≤25  (Formula 1).

The present invention relates to siloxane polymer, copolymer or oligomer for the photoalignment of liquid crystals, especially for the planar orientation of liquid crystals, and which derives from at least one monomer of formula (I), to compositions thereof, to a process for the preparation of the linear, branched or crosslinked siloxane polymer, and to its use for optical and electro optical devices, such as liquid crystal devices (LCDs):

##STR00001##

The present disclosure provides a liquid crystal material, a method of manufacturing a liquid crystal display panel, and a display panel. The display panel includes a thin film transistor substrate, a color film substrate, a polymer layer structure, and a liquid crystal layer. During the preparation, after three different irradiations, the liquid crystal material is directly polymerized into the first polymer layer structure and the second polymer layer structure under the irradiations, eliminating the black matrix structure and the polyimide alignment film structure, improving the display effect of the panel, and reducing preparation costs.

This application provides an alignment film transfer printing plate including a substrate, a first dot arranged on the substrate, and a plurality of second dots arranged around the first dot. A height of each of the second dots in a direction perpendicular to a surface of the substrate is less than or equal to a height of the first dot in the direction perpendicular to the surface of the substrate, a blocking portion is formed on an end of the first dot away from the substrate, and an area of an end surface of each of the second dots away from the substrate is less than an area of an end surface of the blocking portion away from the substrate.

A photo-alignment polymer has a repeating unit represented by Formula (1), in Formula (1), R.sup.1 represents a hydrogen atom or a substituent, X represents —O—, —S—, or —NR.sup.2—, in which R.sup.2 represents a hydrogen atom or a substituent, L.sup.1 represents a single bond or a divalent linking group, P represents a photo-aligned group, and A represents an acid-cleavage group which is decomposed by an action of acid to produce a polar group ##STR00001##

A liquid crystal display includes: a first substrate; a second substrate overlapping the first substrate and spaced apart therefrom; a liquid crystal layer between the first substrate and the second substrate and including liquid crystal molecules; a first alignment layer between the first substrate and the liquid crystal layer; and a plurality of protrusions between the first alignment layer and the liquid crystal layer, wherein the first alignment layer includes a photoinitiator, wherein the plurality of protrusions include a polymerization product of the photoinitiator, a reactive mesogen, and a vertical alignment additive, and the vertical alignment additive may be less reactive than the photoinitiator.

The present invention relates to a liquid crystal display device. The liquid crystal display device of the present invention comprises a first substrate, a second substrate, and a liquid crystal composition disposed between said first substrate and said second substrate, wherein said first substrate and said second substrate are disposed in parallel and opposite to each other; alignment layers are disposed on the sides of said first and second substrates that are close to said liquid crystal composition; and said alignment layers are provided with vertical alignment films that allow liquid crystal molecules in said liquid crystal composition to be arranged roughly perpendicular to said first and second substrates, with said liquid crystal molecules having a pretilt angle of 88.5° to 89.5°.

Manufacturing equipment of low-temperature formed liquid crystal alignment film and panel manufacturing process thereof are provided. The manufacturing equipment includes an engraving member, a light curing agent coating member, and a light curing device. In the panel manufacturing process, the engraving member is applied for engraving an alignment pattern on a surface of a prepared substrate. Next, the light curing agent coating member coats the light curing agent on the surface of the substrate having the alignment pattern thereon. Then, the light curing device is applied for light curing the light curing agent, so as to form a crystal alignment film having a texture of the alignment pattern. Finally, liquid crystal is injected between two substrates having the liquid crystal alignment film and encapsulating the structure to form a panel.