A liquid crystal material, a liquid crystal display panel, and a manufacturing method thereof are provided. The liquid crystal material includes negative liquid crystal molecules and one or more thiol polymerizable monomers. The display panel uses a polymer film obtained by polymerization of a click chemistry reaction of a “thiol and double bond” system to anchor an orientation state of the liquid crystal molecules on the substrate surface, with few impurities and a low risk of image sticking displayed on the panel.

A composite photoalignment layer for aligning liquid crystal molecules includes: a monomeric material; a photoinitiator or a thermal initiator; and an azo dye material. A method for preparing a composite photoalignment layer for aligning liquid crystal molecules includes: mixing, in solution form, a monomeric material, a photoinitiator or a thermal initiator, and an azo dye material; coating the mixed solution onto a substrate to form a thin film; exposing the thin film to polarized light; and, with a thermal initiator, heating the thin film to polymerize the monomeric material and form a solid thin film.

A liquid crystal aligning agent composition for preparing a liquid crystal alignment film having enhanced stability and exhibiting excellent electrical characteristics, a method for preparing a liquid crystal alignment film using the same, and a liquid crystal alignment film and a liquid crystal display device using the liquid crystal alignment film.

A liquid crystal display device of the present invention includes a thin-film transistor substrate, a counter substrate facing the thin-film transistor substrate, a liquid crystal layer provided between the thin-film transistor substrate and the counter substrate, an alignment film provided on the thin-film transistor substrate; a sealing material which bonds together the thin-film transistor substrate and the counter substrate at the periphery of the liquid crystal layer, and a polymerized layer provided on the liquid crystal layer-side surface of the alignment film. The alignment film contains a first polymer and a second polymer of a different type from that of the first polymer and is chemically bonded to the sealing material, the first polymer and the second polymer contained in the alignment film are mixed in a surface layer in contact with the liquid crystal layer, and the first polymer and the second polymer have different photo-functional groups.

A liquid crystal alignment agent composition for producing a liquid crystal alignment film having enhanced alignment property and stability and a high voltage holding ratio, a method of producing a liquid crystal alignment film using the same, and a liquid crystal alignment film and a liquid crystal display device using the same, are provided.

A liquid crystal display device includes a TFT substrate having a first alignment film and an opposing substrate having a second alignment film with liquid crystals sandwiched therebetween. One of the first and second alignment films, comprises a first polyimide produced via polyamide acid ester containing cyclobutane as a precursor and a second polyimide produced via polyamide acid as a precursor. The polyamide acid has a higher polarity than that of the polyamide acid ester. The one of the first and second alignment films is responsive to photo-alignment. A first side of the one of the first and second alignment films is adjacent to the liquid crystals, and a second side thereof is closer to one of the TFT substrate and the counter substrate than the first side. The first side contains more of the first polyimide and less of the second polyimide than the second side.

Provided is a liquid crystal display device comprising a first substrate, a second substrate, and a liquid crystal composition disposed between said first substrate and said second substrate, wherein a surface of said first substrate in contact with said liquid crystal composition is provided with an alignment layer, while said second substrate has no alignment layer; and said liquid crystal composition comprises a liquid crystal compound, a self-aligning agent, and a polymerizable compound represented by Formula I, ##STR00001##

The present invention relates to a liquid crystal aligning agent composition capable of securing a high imidization rate under relatively mild curing conditions, minimizing side reactions and thus having excellent stability, a method for producing a liquid crystal alignment film using the same, and a liquid crystal alignment film and a liquid crystal display device using the same.

This application provides an alignment film transfer printing plate including a substrate, a first dot arranged on the substrate, and a plurality of second dots arranged around the first dot. A height of each of the second dots in a direction perpendicular to a surface of the substrate is less than or equal to a height of the first dot in the direction perpendicular to the surface of the substrate, a blocking portion is formed on an end of the first dot away from the substrate, and an area of an end surface of each of the second dots away from the substrate is less than an area of an end surface of the blocking portion away from the substrate.

A polymer having excellent liquid crystal alignment and electrical properties and thus is suitable for use as a liquid crystal alignment agent, a liquid crystal alignment agent including the same, a liquid crystal alignment film formed from the liquid crystal alignment agent, and a liquid crystal display device including the liquid crystal alignment film are provided.