The invention presents a covered cavity kiln pyrolyzer with modulated means of rotation, to promote mixing and exposure of the biomass to heat, thereby allowing complete and efficient pyrolysis of biomass therein. The invention has a portal arrangement for simultaneous entry of fuel and air alongside the exit of emissions and flames to a separate hood structure. In addition to rotational modulation for mixing, the rotational capabilities of the kiln also permit the removal of processed charcoal when the portal is turned downward. The invention also has a system of internal prongs for mixing and sifting removal of char, as well as automated fuel delivery mechanisms and a system of openings to allow insertion of pipes and sensors into the kiln for monitoring and for additional delivery of reagents for better modulation and efficiency by a user during the pyrolyzation process.

A reactor (16) for the remediation of polyfluoroalkyl- and/or microplastic-contaminated feedstocks includes an elongated, horizontally oriented, axially rotatable drum (34) having a shell (72) within a housing (32), with a feedstock input assembly (38) adjacent one end of the drum (34) and a feedstock output assembly (40) adjacent the opposite end thereof. A burner (94) within the housing (32) generates hot combustion gases which surround the drum (34) in order to conductively heat feedstock passing through the drum (34). The invention substantially completely remediates the feedstocks through volatilization of the contaminants.

A reactor (16) for the remediation of polyfluoroalkyl- and/or microplastic-contaminated feedstocks includes an elongated, horizontally oriented, axially rotatable drum (34) having a shell (72) within a housing (32), with a feedstock input assembly (38) adjacent one end of the drum (34) and a feedstock output assembly (40) adjacent the opposite end thereof. A burner (94) within the housing (32) generates hot combustion gases which surround the drum (34) in order to conductively heat feedstock passing through the drum (34). The invention substantially completely remediates the feedstocks through volatilization of the contaminants.

In various embodiments, a method may comprise disposing biomass into a processing chamber; regulating at least one of a temperature and a pressure in the processing chamber; and/or processing the biomass to create biochar. The biomass may comprise cellulose acetate.

In various embodiments, a method may comprise disposing biomass into a processing chamber; regulating at least one of a temperature and a pressure in the processing chamber; and/or processing the biomass to create biochar. The biomass may comprise cellulose acetate.

Methods and apparatus for compact and easily maintainable waste reformation. Some embodiments include a rotary oven reformer adapted and configured to provide synthesis gas from organic waste. Some embodiments include a rotary oven with simplified operation both as to reformation of the waste, usage of the synthesized gas and other products, and easy removal of the finished waste products, preferably in a unit of compact size for use in austere settings. Yet other embodiments include Fischer-Tropsch reactors of synthesized gas. Some of these reactors include heat exchanging assemblies that provide self-cleaning effects, efficient utilization of waste heat, and ease of cleaning.

Methods and apparatus for compact and easily maintainable waste reformation. Some embodiments include a rotary oven reformer adapted and configured to provide synthesis gas from organic waste. Some embodiments include a rotary oven with simplified operation both as to reformation of the waste, usage of the synthesized gas and other products, and easy removal of the finished waste products, preferably in a unit of compact size for use in austere settings. Yet other embodiments include Fischer-Tropsch reactors of synthesized gas. Some of these reactors include heat exchanging assemblies that provide self-cleaning effects, efficient utilization of waste heat, and ease of cleaning.

A carbide producing method for carbonizing a woody biomass to produce a carbide includes a pyrolysis process in which the woody biomass is pyrolyzed and carbonized, an LHV calculating process in which an LHV of the carbide which is a carbonized woody biomass is calculated, and a supplied heat amount control process in which an amount of heat supplied per unit time to the woody biomass in the pyrolysis process on the basis of the calculated LHV is controlled.

A carbide producing method for carbonizing a woody biomass to produce a carbide includes a pyrolysis process in which the woody biomass is pyrolyzed and carbonized, an LHV calculating process in which an LHV of the carbide which is a carbonized woody biomass is calculated, and a supplied heat amount control process in which an amount of heat supplied per unit time to the woody biomass in the pyrolysis process on the basis of the calculated LHV is controlled.

Methods and apparatus for compact and easily maintainable waste reformation. Some embodiments include a rotary oven reformer adapted and configured to provide synthesis gas from organic waste. Some embodiments include a rotary oven with simplified operation both as to reformation of the waste, usage of the synthesized gas and other products, and easy removal of the finished waste products, preferably in a unit of compact size for use in austere settings. Yet other embodiments include Fischer-Tropsch reactors of synthesized gas. Some of these reactors include heat exchanging assemblies that provide self-cleaning effects, efficient utilization of waste heat, and ease of cleaning.