This disclosure relates to a processing that includes a first shell and a second shell disposed within the first shell. The second shell includes a first end, a second end, and a wall extending between the first end and the second end. The second shell also defines a cavity and a longitudinal axis extending between the first end and the second end. A cross section of the second shell transverse to the longitudinal axis includes a first arcuate inner wall portion having a first radius of curvature and a second arcuate inner wall portion having a second radius of curvature. The first radius of curvature is larger than the second radius of curvature.

A hermetically sealed flow-through reactor for non-oxidative thermal degradation of a rubber containing waste into a char product, the reactor having an internal cylindrical surface, and the reactor including: one or more thermal reaction zones arranged between the inlet and the outlet, wherein each zone is provided with: one or more heating elements controllable to heat the zone to an operating temperature, and one or more gas outlets for withdrawing gas or gases evolved during the degradation of the rubber; and a screw auger located within the reactor, the screw augur configured to rotate in both the forward and reverse directions to agitate and transport the rubber containing waste to the outlet, wherein fighting on the screw auger tracks the internal cylindrical surface of the reactor in close relationship to minimise or prevent the transport of material through a clearance space between outer edges of the fighting and the internal cylindrical surface of the reactor.

A hermetically sealed flow-through reactor for non-oxidative thermal degradation of a rubber containing waste into a char product, the reactor having an internal cylindrical surface, and the reactor including: one or more thermal reaction zones arranged between the inlet and the outlet, wherein each zone is provided with: one or more heating elements controllable to heat the zone to an operating temperature, and one or more gas outlets for withdrawing gas or gases evolved during the degradation of the rubber; and a screw auger located within the reactor, the screw augur configured to rotate in both the forward and reverse directions to agitate and transport the rubber containing waste to the outlet, wherein fighting on the screw auger tracks the internal cylindrical surface of the reactor in close relationship to minimise or prevent the transport of material through a clearance space between outer edges of the fighting and the internal cylindrical surface of the reactor.

In a method for physical and thermochemical treatment of biomass, the biomass moisture content is reduced in a dryer and ammonia (NH.sub.3) is also released from the biomass during drying. The dried biomass is then either pyrolyzed in a pyrolysis reactor and the pyrolysis gas is forwarded to and combusted in a combustion device to form flue gas, or is combusted in a combustion facility unit to form flue gas. In either case the flue gas is fed to a mixer. Oxygen (O.sub.2) is metered to the flue gas in the mixer and is fed directly to the dryer as drying gas. As the drying gas passes through the dryer, the sulfur dioxide (SO.sub.2) contained in the drying gas and/or the sulfur trioxide (SO.sub.3) chemically reacts with the ammonia (NH.sub.3) to form ammonium sulfite ((NH.sub.4).sub.2SO.sub.3) and/or ammonium sulfate ((NH.sub.4).sub.2SO.sub.4). Also a treatment facility physically and thermochemically treats the biomass.

A heat treatment apparatus has a first screw conveyor, a second screw conveyor, a first nozzle pipe, and a second nozzle pipe. If the first screw conveyor rotates right, the first nozzle pipe is disposed on the left lateral side of the first screw conveyor. If the first screw conveyor rotates left, the first nozzle pipe is disposed on the right lateral side of the first screw conveyor. If the second screw conveyor rotates right, the second nozzle pipe is disposed on the left lateral side of the second screw conveyor. If the second screw conveyor rotates left, the second nozzle pipe is disposed on the right lateral side of the second screw conveyor.

A heat treatment apparatus has a first screw conveyor, a second screw conveyor, a first nozzle pipe, and a second nozzle pipe. If the first screw conveyor rotates right, the first nozzle pipe is disposed on the left lateral side of the first screw conveyor. If the first screw conveyor rotates left, the first nozzle pipe is disposed on the right lateral side of the first screw conveyor. If the second screw conveyor rotates right, the second nozzle pipe is disposed on the left lateral side of the second screw conveyor. If the second screw conveyor rotates left, the second nozzle pipe is disposed on the right lateral side of the second screw conveyor.

The invention relates to an improved process for providing purified styrenic monomers, such as styrene, from styrene-containing polymer waste. Styrene-containing waste is depolymerized in a suitable reactor, and the depolymerization products are condensed and separated in a three-step distillation process.

A heat treatment apparatus has a first screw conveyor, a second screw conveyor, a first nozzle pipe, and a second nozzle pipe. If the first screw conveyor rotates right, the first nozzle pipe is disposed on the left lateral side of the first screw conveyor. If the first screw conveyor rotates left, the first nozzle pipe is disposed on the right lateral side of the first screw conveyor. If the second screw conveyor rotates right, the second nozzle pipe is disposed on the left lateral side of the second screw conveyor. If the second screw conveyor rotates left, the second nozzle pipe is disposed on the right lateral side of the second screw conveyor.

A heat treatment apparatus has a first screw conveyor, a second screw conveyor, a first nozzle pipe, and a second nozzle pipe. If the first screw conveyor rotates right, the first nozzle pipe is disposed on the left lateral side of the first screw conveyor. If the first screw conveyor rotates left, the first nozzle pipe is disposed on the right lateral side of the first screw conveyor. If the second screw conveyor rotates right, the second nozzle pipe is disposed on the left lateral side of the second screw conveyor. If the second screw conveyor rotates left, the second nozzle pipe is disposed on the right lateral side of the second screw conveyor.

A plastic pyrolytic conversion vessel comprises a conveying mechanism for moving a liquid, or a semi-molten, or a molten waste material, or a solid inert residue, or any combination thereof through the vessel. During pyrolyzation of the waste material, the same is heated and vaporized and undergoes in situ chemical reactions comprising cracking, recombination, reforming, recracking, and the like, and is subsequently removed from the vessel. A plurality of scraper blades serve to mix the liquid, or the semi-molten, or the molten waste material, or a solid inert residue, or any combination thereof and convey the waste material forward toward a vessel egress. In another embodiment, one or more sweeping devices serve to move forward the waste material that is located between adjacent rotating conveyor devices.