An apparatus for on-line temperature measurement and gas sampling used in the chute area of CDQ coke oven. The oven external unit includes a temperature indicator, a gas tube, a vacuum tank, and the oven internal unit includes a temperature measuring element, a temperature indicator. The temperature measuring element pass through the oven shell and oven along the oven radical, is located in the upper channel of the high-temperature ceramic tube with double-channel, one end of the high-temperature ceramic tube with double-channel is connected with the gas tube of the vacuum tank. The apparatus solves the problem that hard to measure the temperature and sample the gas of the part where the environment is the most complicated in CDQ coke oven, and has the advantages that the structure is simple, operation is easy to handle and can achieve real-time monitoring for the inner environment of the CDQ coke oven.

This invention provides processes and systems for converting biomass into high carbon biogenic reagents that are suitable for a variety of commercial applications. Some embodiments employ pyrolysis in the presence of an inert gas to generate hot pyrolyzed solids, condensable vapors, and non-condensable gases, followed by separation of vapors and gases, and cooling of the hot pyrolyzed solids in the presence of the inert gas. Additives may be introduced during processing or combined with the reagent, or both. The biogenic reagent may include at least 70 wt %, 80 wt %, 90 wt %, 95 wt %, or more total carbon on a dry basis. The biogenic reagent may have an energy content of at least 12,000 Btu/lb, 13,000 Btu/lb, 14,000 Btu/lb, or 14,500 Btu/lb on a dry basis. The biogenic reagent may be formed into fine powders, or structural objects. The structural objects may have a structure and/or strength that derive from the feedstock, heat rate, and additives.

This invention provides processes and systems for converting biomass into high carbon biogenic reagents that are suitable for a variety of commercial applications. Some embodiments employ pyrolysis in the presence of an inert gas to generate hot pyrolyzed solids, condensable vapors, and non-condensable gases, followed by separation of vapors and gases, and cooling of the hot pyrolyzed solids in the presence of the inert gas. Additives may be introduced during processing or combined with the reagent, or both. The biogenic reagent may include at least 70 wt %, 80 wt %, 90 wt %, 95 wt %, or more total carbon on a dry basis. The biogenic reagent may have an energy content of at least 12,000 Btu/lb, 13,000 Btu/lb, 14,000 Btu/lb, or 14,500 Btu/lb on a dry basis. The biogenic reagent may be formed into fine powders, or structural objects. The structural objects may have a structure and/or strength that derive from the feedstock, heat rate, and additives.

A method is described for quenching coke coming from the distillation of coal and having a temperature higher than or equal to 900 C., comprising the steps of a) lowering the temperature of said coke to about 700-300 C. by heat exchange with a fluid through walls of a thermally conductive material interposed between coke and fluid, b) feeding a continuous flow of said coke at about 700-300 C. into a turbo-cooler (T), comprising a cylindrical tubular body (18), closed at opposite ends by respective end plates (19,20), provided with an optional cooling jacket (21) for the inner wall thereof, at least one inlet opening (9) for the coke, at least one inlet opening (10, 15, 16) for water, at least one discharge opening (11, 12) and a rotor, rotatably supported in the cylindrical tubular body (5) and comprising a shaft (13) provided with elements (14) projecting radially from said shaft, adapted for the handling and advancement of the coke; c) feeding a continuous flow of water at a temperature less than or equal to 100 C. into the turbo-cooler (T), through said at least one inlet opening (10, 15, 16) and subjecting said flow of coke and water to the action of the rotor, which advances the coke towards said at least one discharge opening (11); d) continuously discharging from said at least one discharge opening (11, 12) a flow of coke at a temperature lower than or equal to 200 C., and a flow of water vapor.

A method is described for quenching coke coming from the distillation of coal and having a temperature higher than or equal to 900 C., comprising the steps of a) lowering the temperature of said coke to about 700-300 C. by heat exchange with a fluid through walls of a thermally conductive material interposed between coke and fluid, b) feeding a continuous flow of said coke at about 700-300 C. into a turbo-cooler (T), comprising a cylindrical tubular body (18), closed at opposite ends by respective end plates (19,20), provided with an optional cooling jacket (21) for the inner wall thereof, at least one inlet opening (9) for the coke, at least one inlet opening (10, 15, 16) for water, at least one discharge opening (11, 12) and a rotor, rotatably supported in the cylindrical tubular body (5) and comprising a shaft (13) provided with elements (14) projecting radially from said shaft, adapted for the handling and advancement of the coke; c) feeding a continuous flow of water at a temperature less than or equal to 100 C. into the turbo-cooler (T), through said at least one inlet opening (10, 15, 16) and subjecting said flow of coke and water to the action of the rotor, which advances the coke towards said at least one discharge opening (11); d) continuously discharging from said at least one discharge opening (11, 12) a flow of coke at a temperature lower than or equal to 200 C., and a flow of water vapor.

This invention provides processes and systems for converting biomass into high carbon biogenic reagents that are suitable for a variety of commercial applications. Some embodiments employ pyrolysis in the presence of an inert gas to generate hot pyrolyzed solids, condensable vapors, and non-condensable gases, followed by separation of vapors and gases, and cooling of the hot pyrolyzed solids in the presence of the inert gas. Additives may be introduced during processing or combined with the reagent, or both. The biogenic reagent may include at least 70 wt %, 80 wt %, 90 wt %, 95 wt %, or more total carbon on a dry basis. The biogenic reagent may have an energy content of at least 12,000 Btu/lb, 13,000 Btu/lb, 14,000 Btu/lb, or 14,500 Btu/lb on a dry basis. The biogenic reagent may be formed into fine powders, or structural objects. The structural objects may have a structure and/or strength that derive from the feedstock, heat rate, and additives.

This invention provides processes and systems for converting biomass into high carbon biogenic reagents that are suitable for a variety of commercial applications. Some embodiments employ pyrolysis in the presence of an inert gas to generate hot pyrolyzed solids, condensable vapors, and non-condensable gases, followed by separation of vapors and gases, and cooling of the hot pyrolyzed solids in the presence of the inert gas. Additives may be introduced during processing or combined with the reagent, or both. The biogenic reagent may include at least 70 wt %, 80 wt %, 90 wt %, 95 wt %, or more total carbon on a dry basis. The biogenic reagent may have an energy content of at least 12,000 Btu/lb, 13,000 Btu/lb, 14,000 Btu/lb, or 14,500 Btu/lb on a dry basis. The biogenic reagent may be formed into fine powders, or structural objects. The structural objects may have a structure and/or strength that derive from the feedstock, heat rate, and additives.

This invention provides processes and systems for converting biomass into highcarbon biogenic reagents that are suitable for a variety of commercial applications. Some embodiments employ pyrolysis in the presence of an inert gas to generate hot pyrolyzed solids, condensable vapors, and non-condensable gases, followed by separation of vapors and gases, and cooling of the hot pyrolyzed solids in the presence of the inert gas. Additives may be introduced during processing or combined with the reagent, or both. The biogenic reagent may include at least 70 wt %, 80 wt %, 90 wt %, 95 wt %, or more total carbon on a dry basis. The biogenic reagent may have an energy content of at least 12,000 Btu/lb, 13,000 Btu/lb, 14,000 Btu/lb, or 14,500 Btu/lb on a dry basis. The biogenic reagent may be formed into fine powders, or structural objects.

This invention provides processes and systems for converting biomass into highcarbon biogenic reagents that are suitable for a variety of commercial applications. Some embodiments employ pyrolysis in the presence of an inert gas to generate hot pyrolyzed solids, condensable vapors, and non-condensable gases, followed by separation of vapors and gases, and cooling of the hot pyrolyzed solids in the presence of the inert gas. Additives may be introduced during processing or combined with the reagent, or both. The biogenic reagent may include at least 70 wt %, 80 wt %, 90 wt %, 95 wt %, or more total carbon on a dry basis. The biogenic reagent may have an energy content of at least 12,000 Btu/lb, 13,000 Btu/lb, 14,000 Btu/lb, or 14,500 Btu/lb on a dry basis. The biogenic reagent may be formed into fine powders, or structural objects.

This invention provides processes and systems for converting biomass into high carbon biogenic reagents that are suitable for a variety of commercial applications. Some embodiments employ pyrolysis in the presence of an inert gas to generate hot pyrolyzed solids, condensable vapors, and non-condensable gases, followed by separation of vapors and gases, and cooling of the hot pyrolyzed solids in the presence of the inert gas. Additives may be introduced during processing or combined with the reagent, or both. The biogenic reagent may include at least 70 wt %, 80 wt %, 90 wt %, 95 wt %, or more total carbon on a dry basis. The biogenic reagent may have an energy content of at least 12,000 Btu/lb, 13,000 Btu/lb, 14,000 Btu/lb, or 14,500 Btu/lb on a dry basis. The biogenic reagent may be formed into fine powders, or structural objects. The structural objects may have a structure and/or strength that derive from the feedstock, heat rate, and additives.