A shale pyrolysis system includes a retort with a first side and a second side. The second side is opposite the first side and the first side and the second side include descending angled surfaces at alternating angles to produce zig-zag motion of shale descending through the retort. Corners of the retort that change direction of the shale are rounded. The system includes steam distributors coupled to the first side and collectors coupled to the second side to produce crossflow of steam and heat across the descending shale from the first side to the second side, and a steam temperature control subsystem coupled to the steam distributors and configured to deliver higher-temperature steam to one or more upper sections of the retort and lower-temperature steam to one or more lower sections of the retort.

Systems and methods for heating material through cogeneration of thermal and electrical energy can include a heat source and an electric generator configured to produce hot exhaust gas and electricity. One or more heating conduits can carry the hot exhaust gas to one or more bodies of material. The electric generator can at least partially power one or more electric heaters configured to reheat the hot exhaust gas after a portion of heat has been transferred from the hot exhaust gas to the one or more bodies of material.

Systems and methods for heating material through cogeneration of thermal and electrical energy can include a heat source and an electric generator configured to produce hot exhaust gas and electricity. One or more heating conduits can carry the hot exhaust gas to one or more bodies of material. The electric generator can at least partially power one or more electric heaters configured to reheat the hot exhaust gas after a portion of heat has been transferred from the hot exhaust gas to the one or more bodies of material.

An open system pyrolysis of a first hydrocarbon source rock sample obtained from a natural system is performed within a pyrolysis chamber by maintaining the pyrolysis chamber at a substantially constant temperature. Hydrocarbons are recovered from the pyrolysis chamber released by the first hydrocarbon source rock sample. A thermo-vaporization is performed within the pyrolysis chamber on the pyrolyzed sample at a substantially constant temperature. A first hydrocarbon expulsion efficiency of hydrocarbon source rock is determined. A second hydrocarbon rock sample is ground to a grain size less than or equal to or less than 250 micrometers. A second pyrolysis is performed on the ground hydrocarbon source rock sample by maintaining the chamber at a substantially constant temperature. A second hydrocarbon expulsion efficiency of the hydrocarbon source rock in the natural system is determined. The first hydrocarbon expulsion efficiency is verified using the second hydrocarbon expulsion efficiency.

An open system pyrolysis of a first hydrocarbon source rock sample obtained from a natural system is performed within a pyrolysis chamber by maintaining the pyrolysis chamber at a substantially constant temperature. Hydrocarbons are recovered from the pyrolysis chamber released by the first hydrocarbon source rock sample. A thermo-vaporization is performed within the pyrolysis chamber on the pyrolyzed sample at a substantially constant temperature. A first hydrocarbon expulsion efficiency of hydrocarbon source rock is determined. A second hydrocarbon rock sample is ground to a grain size less than or equal to or less than 250 micrometers. A second pyrolysis is performed on the ground hydrocarbon source rock sample by maintaining the chamber at a substantially constant temperature. A second hydrocarbon expulsion efficiency of the hydrocarbon source rock in the natural system is determined. The first hydrocarbon expulsion efficiency is verified using the second hydrocarbon expulsion efficiency.

An open system pyrolysis of a first hydrocarbon source rock sample obtained from a natural system is performed within a pyrolysis chamber by maintaining the pyrolysis chamber at a substantially constant temperature. Hydrocarbons are recovered from the pyrolysis chamber released by the first hydrocarbon source rock sample. A thermo-vaporization is performed within the pyrolysis chamber on the pyrolyzed sample at a substantially constant temperature. A first hydrocarbon expulsion efficiency of hydrocarbon source rock is determined. A second hydrocarbon rock sample is ground to a grain size less than or equal to or less than 250 micrometers. A second pyrolysis is performed on the ground hydrocarbon source rock sample by maintaining the chamber at a substantially constant temperature. A second hydrocarbon expulsion efficiency of the hydrocarbon source rock in the natural system is determined. The first hydrocarbon expulsion efficiency is verified using the second hydrocarbon expulsion efficiency.

An open system pyrolysis of a first hydrocarbon source rock sample obtained from a natural system is performed within a pyrolysis chamber by maintaining the pyrolysis chamber at a substantially constant temperature. Hydrocarbons are recovered from the pyrolysis chamber released by the first hydrocarbon source rock sample. A thermo-vaporization is performed within the pyrolysis chamber on the pyrolyzed sample at a substantially constant temperature. A first hydrocarbon expulsion efficiency of hydrocarbon source rock is determined. A second hydrocarbon rock sample is ground to a grain size less than or equal to or less than 250 micrometers. A second pyrolysis is performed on the ground hydrocarbon source rock sample by maintaining the chamber at a substantially constant temperature. A second hydrocarbon expulsion efficiency of the hydrocarbon source rock in the natural system is determined. The first hydrocarbon expulsion efficiency is verified using the second hydrocarbon expulsion efficiency.

A processing apparatus includes a microwave processing chamber. In addition, the processing apparatus includes a rigid, rotatable feed wheel rotatable about an axis of rotation such that a part of the feed wheel is located within the processing chamber. Further, the processing apparatus includes a feed device configured to deposit materials to be processed onto the feed wheel. Still further, the processing apparatus includes an output into which processed materials from the feed wheel can be deposited.

A processing apparatus includes a microwave processing chamber. In addition, the processing apparatus includes a rigid, rotatable feed wheel rotatable about an axis of rotation such that a part of the feed wheel is located within the processing chamber. Further, the processing apparatus includes a feed device configured to deposit materials to be processed onto the feed wheel. Still further, the processing apparatus includes an output into which processed materials from the feed wheel can be deposited.

An open system pyrolysis of a first hydrocarbon source rock sample obtained from a natural system is performed within a pyrolysis chamber by maintaining the pyrolysis chamber at a substantially constant temperature. Hydrocarbons are recovered from the pyrolysis chamber released by the first hydrocarbon source rock sample. A thermo-vaporization is performed within the pyrolysis chamber on the pyrolyzed sample at a substantially constant temperature. A first hydrocarbon expulsion efficiency of hydrocarbon source rock is determined. A second hydrocarbon rock sample is ground to a grain size less than or equal to or less than 250 micrometers. A second pyrolysis is performed on the ground hydrocarbon source rock sample by maintaining the chamber at a substantially constant temperature. A second hydrocarbon expulsion efficiency of the hydrocarbon source rock in the natural system is determined. The first hydrocarbon expulsion efficiency is verified using the second hydrocarbon expulsion efficiency.