In one embodiment, a method for processing carbonaceous materials that includes introducing a first source of carbonaceous material as a first feedstock into a mixer. Then, a second source of carbonaceous material is introduced as a second feedstock into the mixer. The second feedstock is one of the outputs of the processing of the carbonaceous materials. These carbonaceous materials are mixed into a single feedstock of carbonaceous materials that is customized into a predetermined material composition, and this predetermined mixture is then pyrolyzed in a pyrolyzer to produce a custom carbonaceous output. Other embodiments are also disclosed.

In one embodiment, a method for processing carbonaceous materials that includes introducing a first source of carbonaceous material as a first feedstock into a mixer. Then, a second source of carbonaceous material is introduced as a second feedstock into the mixer. The second feedstock is one of the outputs of the processing of the carbonaceous materials. These carbonaceous materials are mixed into a single feedstock of carbonaceous materials that is customized into a predetermined material composition, and this predetermined mixture is then pyrolyzed in a pyrolyzer to produce a custom carbonaceous output. Other embodiments are also disclosed.

The presently disclosed subject matter relates to torrefied biomass briquettes and methods for producing the same that make use of a mixture of lightly torrefied material (LTM) and highly torrefied material (HTM) and/or make use of torrefied materials that are subjected to a hydrolysis pretreatment prior to being torrefied.

The presently disclosed subject matter relates to torrefied biomass briquettes and methods for producing the same that make use of a mixture of lightly torrefied material (LTM) and highly torrefied material (HTM) and/or make use of torrefied materials that are subjected to a hydrolysis pretreatment prior to being torrefied.

This disclosure provides a method of making a high-fixed-carbon material comprising pyrolyzing biomass to generate intermediate solids and a pyrolysis vapor; condensing the pyrolysis vapor to generate pyrolysis liquid; blending the pyrolysis liquid with the intermediate solids, to generate a mixture; and further pyrolyzing the mixture to generate a high-fixed-carbon material. A process can comprise: pyrolyzing a biomass-comprising feedstock in a first pyrolysis reactor to generate a first biogenic reagent and a first pyrolysis vapor; introducing the first pyrolysis vapor to a condensing system to generate a condenser liquid; contacting the first biogenic reagent with the condenser liquid, thereby generating an intermediate material; further pyrolyzing the intermediate material in a second pyrolysis reactor to generate a second biogenic reagent and a second pyrolysis vapor; and recovering the second biogenic reagent as a high-yield biocarbon composition. The process can further comprise pelletizing the intermediate material. Many process and system configurations are disclosed.

This disclosure provides a method of making a high-fixed-carbon material comprising pyrolyzing biomass to generate intermediate solids and a pyrolysis vapor; condensing the pyrolysis vapor to generate pyrolysis liquid; blending the pyrolysis liquid with the intermediate solids, to generate a mixture; and further pyrolyzing the mixture to generate a high-fixed-carbon material. A process can comprise: pyrolyzing a biomass-comprising feedstock in a first pyrolysis reactor to generate a first biogenic reagent and a first pyrolysis vapor; introducing the first pyrolysis vapor to a condensing system to generate a condenser liquid; contacting the first biogenic reagent with the condenser liquid, thereby generating an intermediate material; further pyrolyzing the intermediate material in a second pyrolysis reactor to generate a second biogenic reagent and a second pyrolysis vapor; and recovering the second biogenic reagent as a high-yield biocarbon composition. The process can further comprise pelletizing the intermediate material. Many process and system configurations are disclosed.

A method of processing coal includes placing coal having a heat content between about 3,000 BTU/lb and about 9,000 BTU/lb and a moisture content between about 20 wt % and about 60 wt % in a vessel. The coal is heated by conduction. A pressure in the vessel is reduced to below atmospheric pressure, thereby reducing the coal, such that an average primary particle size of the coal is less than 1 millimeter. The reduced coal is shaped to yield a fuel composition.

A method of processing coal includes placing coal having a heat content between about 3,000 BTU/lb and about 9,000 BTU/lb and a moisture content between about 20 wt % and about 60 wt % in a vessel. The coal is heated by conduction. A pressure in the vessel is reduced to below atmospheric pressure, thereby reducing the coal, such that an average primary particle size of the coal is less than 1 millimeter. The reduced coal is shaped to yield a fuel composition.

Some variations provide a process for producing biocarbon pellets, comprising: pyrolyzing a biomass-containing feedstock in a first pyrolysis reactor to generate a first biogenic reagent and a pyrolysis vapor; introducing the pyrolysis vapor to a separation unit, to generate a pyrolysis precipitate in liquid or solid form; contacting the first biogenic reagent with the pyrolysis precipitate, thereby generating an intermediate material; pelletizing the intermediate material, to generate intermediate pellets; optionally, drying the intermediate pellets; separately pyrolyzing the intermediate pellets in a second pyrolysis reactor to generate a second biogenic reagent and a pyrolysis off-gas; and recovering the second biogenic reagent as biocarbon pellets. Some variations provide a similar process that utilizes a carbon-containing condensed-matter material, which is not necessarily a pyrolysis precipitate. The disclosure provides improved processes for producing biocarbon compositions, especially with respect to carbon yield and biocarbon properties, such as reactivity.

Some variations provide a process for producing biocarbon pellets, comprising: pyrolyzing a biomass-containing feedstock in a first pyrolysis reactor to generate a first biogenic reagent and a pyrolysis vapor; introducing the pyrolysis vapor to a separation unit, to generate a pyrolysis precipitate in liquid or solid form; contacting the first biogenic reagent with the pyrolysis precipitate, thereby generating an intermediate material; pelletizing the intermediate material, to generate intermediate pellets; optionally, drying the intermediate pellets; separately pyrolyzing the intermediate pellets in a second pyrolysis reactor to generate a second biogenic reagent and a pyrolysis off-gas; and recovering the second biogenic reagent as biocarbon pellets. Some variations provide a similar process that utilizes a carbon-containing condensed-matter material, which is not necessarily a pyrolysis precipitate. The disclosure provides improved processes for producing biocarbon compositions, especially with respect to carbon yield and biocarbon properties, such as reactivity.