C10B55/02

Reverse flow reactors having low maldistribution parameter while containing asymmetric feeds, methods of using same, and pyrolysis products made from same

Reverse flow reactor (RFR) apparatuses exhibiting asymmetric feed profiles and improved flow distribution during heating mode and/or pyrolysis mode operation, and methods of using same to transform a hydrocarbon feed into a pyrolysed hydrocarbon product are disclosed. The RFR apparatus includes an RFR body with a reaction zone having at least one bed. The RFR body has a central vertical axis and is flanked by first and second void spaces. The method utilizes at least two oxygen-containing feeds, a combustion fuel feed, a purge feed, and a hydrocarbon pyrolysis feed. The RFR apparatus can cycle between an exothermic heating mode (heated to ≥700° C. while maintaining a pressure drop across the reaction zone of ≤100 kPag), a purge mode (purging oxygen using <6 bed volumes of purge gas while maintaining a pressure drop of ≤35 kPag), and an endothermic pyrolysis mode (feeding pyrolysis hydrocarbons through the reaction zone to form pyrolysis products, while maintaining a pressure drop across the reaction zone of ≤70 kPag).

PROCESSES AND SYSTEMS FOR PETROCHEMICAL PRODUCTION INTEGRATING COKING AND DEEP HYDROGENATION OF COKING PRODUCTS
20210246388 · 2021-08-12 ·

A feedstock is processed in a coking zone unit to produce at least light gases, coker naphtha, light coker gas oil and petroleum coke. Light coker gas oil, and in certain embodiments hydrotreated light coker gas oil, is subjected to deep hydrogenation to produce a deeply hydrogenated middle distillate fraction. All or a portion of the deeply hydrogenated middle distillate fraction is used as feed to a petrochemicals production complex to produce light olefins.

PROCESSES AND SYSTEMS FOR PETROCHEMICAL PRODUCTION INTEGRATING COKING AND DEEP HYDROGENATION OF COKING PRODUCTS
20210246388 · 2021-08-12 ·

A feedstock is processed in a coking zone unit to produce at least light gases, coker naphtha, light coker gas oil and petroleum coke. Light coker gas oil, and in certain embodiments hydrotreated light coker gas oil, is subjected to deep hydrogenation to produce a deeply hydrogenated middle distillate fraction. All or a portion of the deeply hydrogenated middle distillate fraction is used as feed to a petrochemicals production complex to produce light olefins.

NEEDLE COKE PRODUCTION FROM HPNA RECOVERED FROM HYDROCRACKING UNIT
20210179945 · 2021-06-17 · ·

A process for the treatment of a hydrocracking unit bottoms stream containing heavy poly-nuclear aromatic (HPNA) compounds and/or a fresh hydrocracking feedstock stream containing HPNA precursors to produce coke. The HPNA and/or HPNA precursors are removed from the hydrocracking unit bottoms stream and/or a fresh hydrocracking feedstock stream by solvent washing, and the HPNA and/or HPNA precursors are subjected to delayed coking for the production of coke.

Processes and systems for petrochemical production integrating coking and deep hydrogenation of coking products
11118123 · 2021-09-14 · ·

A feedstock is processed in a coking zone unit to produce at least light gases, coker naphtha, light coker gas oil and petroleum coke. Light coker gas oil, and in certain embodiments hydrotreated light coker gas oil, is subjected to deep hydrogenation to produce a deeply hydrogenated middle distillate fraction. All or a portion of the deeply hydrogenated middle distillate fraction is used as feed to a petrochemicals production complex to produce light olefins.

Processes and systems for petrochemical production integrating coking and deep hydrogenation of coking products
11118123 · 2021-09-14 · ·

A feedstock is processed in a coking zone unit to produce at least light gases, coker naphtha, light coker gas oil and petroleum coke. Light coker gas oil, and in certain embodiments hydrotreated light coker gas oil, is subjected to deep hydrogenation to produce a deeply hydrogenated middle distillate fraction. All or a portion of the deeply hydrogenated middle distillate fraction is used as feed to a petrochemicals production complex to produce light olefins.

Reverse Flow Reactors Having Low Maldistribution Parameter While Containing Asymmetric Feeds, Methods of Using Same, and Pyrolysis Products Made from Same
20210139788 · 2021-05-13 ·

Reverse flow reactor (RFR) apparatuses exhibiting asymmetric feed profiles and improved flow distribution during heating mode and/or pyrolysis mode operation, and methods of using same to transform a hydrocarbon feed into a pyrolysed hydrocarbon product are disclosed. The RFR apparatus includes an RFR body with a reaction zone having at least one bed. The RFR body has a central vertical axis and is flanked by first and second void spaces. The method utilizes at least two oxygen-containing feeds, a combustion fuel feed, a purge feed, and a hydrocarbon pyrolysis feed. The RFR apparatus can cycle between an exothermic heating mode (heated to ≥700° C. while maintaining a pressure drop across the reaction zone of ≤100 kPag), a purge mode (purging oxygen using <6 bed volumes of purge gas while maintaining a pressure drop of ≤35 kPag), and an endothermic pyrolysis mode (feeding pyrolysis hydrocarbons through the reaction zone to form pyrolysis products, while maintaining a pressure drop across the reaction zone of ≤70 kPag).

Reverse Flow Reactors Having Low Maldistribution Parameter While Containing Asymmetric Feeds, Methods of Using Same, and Pyrolysis Products Made from Same
20210139788 · 2021-05-13 ·

Reverse flow reactor (RFR) apparatuses exhibiting asymmetric feed profiles and improved flow distribution during heating mode and/or pyrolysis mode operation, and methods of using same to transform a hydrocarbon feed into a pyrolysed hydrocarbon product are disclosed. The RFR apparatus includes an RFR body with a reaction zone having at least one bed. The RFR body has a central vertical axis and is flanked by first and second void spaces. The method utilizes at least two oxygen-containing feeds, a combustion fuel feed, a purge feed, and a hydrocarbon pyrolysis feed. The RFR apparatus can cycle between an exothermic heating mode (heated to ≥700° C. while maintaining a pressure drop across the reaction zone of ≤100 kPag), a purge mode (purging oxygen using <6 bed volumes of purge gas while maintaining a pressure drop of ≤35 kPag), and an endothermic pyrolysis mode (feeding pyrolysis hydrocarbons through the reaction zone to form pyrolysis products, while maintaining a pressure drop across the reaction zone of ≤70 kPag).

Reverse Flow Reactors Having High Purge Efficiencies While Containing Asymmetric Feeds, Methods of Using Same, and Pyrolysis Products Made from Same
20210139789 · 2021-05-13 ·

Reverse flow reactor (RFR) apparatuses exhibiting asymmetric feed profiles and improved purge mode efficiency, and methods of using same to transform a hydrocarbon feed into a pyrolysed hydrocarbon product are disclosed. The RFR apparatus includes an RFR body with a reaction zone having at least one bed. The RFR body has a central vertical axis and flanked by first and second void spaces. The method utilizes at least two oxygen-containing feeds, a combustion fuel feed, a purge feed, and a hydrocarbon pyrolysis feed. The RFR apparatus can cycle between an exothermic heating mode (heated to ≥700° C. while maintaining a pressure drop across the reaction zone of ≤100 kPag), a purge mode (purging oxygen using <6 bed volumes of purge gas to achieve a residual oxygen level of ≤20 ppm while maintaining a pressure drop of ≤35 kPag), and an endothermic pyrolysis mode (feeding pyrolysis hydrocarbons through the reaction zone to form pyrolysis products, while maintaining a pressure drop across the reaction zone of ≤70 kPag).

Reverse Flow Reactors Having High Purge Efficiencies While Containing Asymmetric Feeds, Methods of Using Same, and Pyrolysis Products Made from Same
20210139789 · 2021-05-13 ·

Reverse flow reactor (RFR) apparatuses exhibiting asymmetric feed profiles and improved purge mode efficiency, and methods of using same to transform a hydrocarbon feed into a pyrolysed hydrocarbon product are disclosed. The RFR apparatus includes an RFR body with a reaction zone having at least one bed. The RFR body has a central vertical axis and flanked by first and second void spaces. The method utilizes at least two oxygen-containing feeds, a combustion fuel feed, a purge feed, and a hydrocarbon pyrolysis feed. The RFR apparatus can cycle between an exothermic heating mode (heated to ≥700° C. while maintaining a pressure drop across the reaction zone of ≤100 kPag), a purge mode (purging oxygen using <6 bed volumes of purge gas to achieve a residual oxygen level of ≤20 ppm while maintaining a pressure drop of ≤35 kPag), and an endothermic pyrolysis mode (feeding pyrolysis hydrocarbons through the reaction zone to form pyrolysis products, while maintaining a pressure drop across the reaction zone of ≤70 kPag).