Systems and processes for pyrolyzing waste plastics, including, in one or more heating stages, heating a waste plastic from an initial temperature to a peak pyrolysis temperature, and, in a final pyrolysis stage, providing heat input sufficient to maintain a temperature of the waste plastic at a pyrolysis reaction temperature less than the peak pyrolysis temperature and maintaining the waste plastic at the pyrolysis reaction temperature for a time period to convert a portion of the waste plastic to a pyrolyzed product and a pitch. The process further includes recovering the pyrolyzed product and recovering the pitch.

Systems and processes for pyrolyzing waste plastics, including, in one or more heating stages, heating a waste plastic from an initial temperature to a peak pyrolysis temperature, and, in a final pyrolysis stage, providing heat input sufficient to maintain a temperature of the waste plastic at a pyrolysis reaction temperature less than the peak pyrolysis temperature and maintaining the waste plastic at the pyrolysis reaction temperature for a time period to convert a portion of the waste plastic to a pyrolyzed product and a pitch. The process further includes recovering the pyrolyzed product and recovering the pitch.

Some variations provide a process for producing biocarbon pellets, comprising: pyrolyzing a biomass-containing feedstock in a first pyrolysis reactor to generate a first biogenic reagent and a pyrolysis vapor; introducing the pyrolysis vapor to a separation unit, to generate a pyrolysis precipitate in liquid or solid form; contacting the first biogenic reagent with the pyrolysis precipitate, thereby generating an intermediate material; pelletizing the intermediate material, to generate intermediate pellets; optionally, drying the intermediate pellets; separately pyrolyzing the intermediate pellets in a second pyrolysis reactor to generate a second biogenic reagent and a pyrolysis off-gas; and recovering the second biogenic reagent as biocarbon pellets. Some variations provide a similar process that utilizes a carbon-containing condensed-matter material, which is not necessarily a pyrolysis precipitate. The disclosure provides improved processes for producing biocarbon compositions, especially with respect to carbon yield and biocarbon properties, such as reactivity.

Some variations provide a process for producing biocarbon pellets, comprising: pyrolyzing a biomass-containing feedstock in a first pyrolysis reactor to generate a first biogenic reagent and a pyrolysis vapor; introducing the pyrolysis vapor to a separation unit, to generate a pyrolysis precipitate in liquid or solid form; contacting the first biogenic reagent with the pyrolysis precipitate, thereby generating an intermediate material; pelletizing the intermediate material, to generate intermediate pellets; optionally, drying the intermediate pellets; separately pyrolyzing the intermediate pellets in a second pyrolysis reactor to generate a second biogenic reagent and a pyrolysis off-gas; and recovering the second biogenic reagent as biocarbon pellets. Some variations provide a similar process that utilizes a carbon-containing condensed-matter material, which is not necessarily a pyrolysis precipitate. The disclosure provides improved processes for producing biocarbon compositions, especially with respect to carbon yield and biocarbon properties, such as reactivity.

A method for making a soft carbon includes providing a coke, and subjecting the coke to a carbonization process. The carbonization process includes a preliminary calcination treatment conducted by calcining the coke at a first temperature ranging from 800° C. to 1000° C. to obtain a pre-calcinated coke, followed by a main calcination treatment conducted by calcining the pre-calcinated coke at a second temperature ranging from 1000° C. to 1200° C., and/or a surface-modifying calcination treatment conducted by calcining the pre-calcinated coke in the presence of a carbonaceous material for modifying surfaces thereof at a third temperature ranging from 1000° C. to 1200° C. A soft carbon made by the method is also disclosed.

A method for making a soft carbon includes providing a coke, and subjecting the coke to a carbonization process. The carbonization process includes a preliminary calcination treatment conducted by calcining the coke at a first temperature ranging from 800° C. to 1000° C. to obtain a pre-calcinated coke, followed by a main calcination treatment conducted by calcining the pre-calcinated coke at a second temperature ranging from 1000° C. to 1200° C., and/or a surface-modifying calcination treatment conducted by calcining the pre-calcinated coke in the presence of a carbonaceous material for modifying surfaces thereof at a third temperature ranging from 1000° C. to 1200° C. A soft carbon made by the method is also disclosed.

The present invention provides a system for producing mesophase coke from an isotropic pitch. The system includes a reactor having a first heating zone to carry out pretreating of the isotropic pitch by operating at a temperature of 250° C.-350° C. under atmospheric pressure. The reactor further includes a second heating zone to carry out heating of the pretreated isotropic pitch by maintaining the temperature of 350° C.-500° C. under the atmospheric pressure to obtain mesophase pitch. The reactor includes a third heating zone to carry out heating of the said mesophase pitch by maintaining the temperature of 500° C.-800° C. under the atmospheric pressure to obtain mesophase coke. The system further includes a pusher unit adapted to physically move the container from the entry zone to the exit zone to obtain the mesophase coke.

The present invention provides a system for producing mesophase coke from an isotropic pitch. The system includes a reactor having a first heating zone to carry out pretreating of the isotropic pitch by operating at a temperature of 250° C.-350° C. under atmospheric pressure. The reactor further includes a second heating zone to carry out heating of the pretreated isotropic pitch by maintaining the temperature of 350° C.-500° C. under the atmospheric pressure to obtain mesophase pitch. The reactor includes a third heating zone to carry out heating of the said mesophase pitch by maintaining the temperature of 500° C.-800° C. under the atmospheric pressure to obtain mesophase coke. The system further includes a pusher unit adapted to physically move the container from the entry zone to the exit zone to obtain the mesophase coke.

A pyrolysis method and system are provided that may utilize a recycled plastic feedstock that comprises various types of waste plastics or a feedstock that comprises various types of waste plastics and at least one crude post-industrial liquid waste. The disclosed pyrolysis method and system may be configured to convert various types of waste plastics, including post-customer and post-industrial wastes, and/or crude post-industrial liquid wastes into useful pyrolysis oils.

Described is a system for producing primarily diesel with some heavy fuel oil from plastic feedstock. The feedstock is received into a pyrolizer. There are two zones in the pyrolizer—one where the temperature is elevated during conveyance, and a second where the temperature is maintained. A distillation vessel receives fuel oils from the pyrolizer and agitates the oils at high temperature. A hydrogenation vessel then mixes the fuel liquid with H2 at a high pressure while recirculating to and from an expansion vessel to create converted fuel oil. A diesel distillation tank receives the converted fuel oil and creates diesel gas, which is then condensed to form a usable diesel product. Any remaining fuel oil is sent the heavy fuel oil tank.