A pyrolysis apparatus having a heating system adapted to heat a first gas enclosure, wherein a gas path within the heated enclosure is helical or spherical. Pyrolysis is used to destroy oils, tars and/or PAHs in a gaseous mixture.

A pyrolysis apparatus having a heating system adapted to heat a first gas enclosure, wherein a gas path within the heated enclosure is helical or spherical. Pyrolysis is used to destroy oils, tars and/or PAHs in a gaseous mixture.

A pyrolysis apparatus having a heating system adapted to heat a first gas enclosure, wherein a gas path within the heated enclosure is helical or spherical. Pyrolysis is used to destroy oils, tars and/or PAHs in a gaseous mixture.

This disclosure describes systems and methods for using pyrolysis tail gas as the source for additional hydrogen to be used in the pyrolysis reaction. Tail gas is separated from the pyrolysis products and a portion of the tail gas is converted into formic acid (HCOOH). The formic acid is then injected into the pyrolysis reactor where it becomes the donor of two monohydrogen atoms and is ultimately converted into CO.sub.2 under reaction conditions. In this fashion, a closed loop pyrolysis hydrogen donor system may be created utilizing a generally non-toxic intermediary derived from the pyrolysis reaction products. This disclosure also describes using a ruthenium catalyst supported on particles of activated carbon to improve the yield of pyrolysis reactions.

This disclosure describes systems and methods for using pyrolysis tail gas as the source for additional hydrogen to be used in the pyrolysis reaction. Tail gas is separated from the pyrolysis products and a portion of the tail gas is converted into formic acid (HCOOH). The formic acid is then injected into the pyrolysis reactor where it becomes the donor of two monohydrogen atoms and is ultimately converted into CO.sub.2 under reaction conditions. In this fashion, a closed loop pyrolysis hydrogen donor system may be created utilizing a generally non-toxic intermediary derived from the pyrolysis reaction products. This disclosure also describes using a ruthenium catalyst supported on particles of activated carbon to improve the yield of pyrolysis reactions.

A method for forming catalytically treated pyrolytic vapor product from pyrolyzable material, the method comprising burning fuel in a fluidized bed boiler, thereby heating some particulate material; transferring at least some of the heated particulate material or some other heated particulate material to a pyrolysis reactor to pyrolyze some pyrolyzable material in the pyrolysis reactor; and conveying at least some pyrolytic vapor through a catalyst bed comprising catalyst material; and conveying at least part of the formed side products upstream back to the process; thereby producing the catalytically treated pyrolytic vapor product in an resource efficient manner. In addition, a system configured to produce catalytically treated pyrolytic vapor product from pyrolyzable material. The system comprises a fluidized bed boiler; a pyrolysis reactor; a catalytic reactor; means for conveying some heated particulate material to the pyrolysis reactor; a pipeline for conveying at least some pyrolytic vapor from the pyrolysis reactor into the catalytic reactor and means for conveying at least part of the formed side products upstream back to the process for recovering heat and chemical energy bound to the side products.

A method for forming catalytically treated pyrolytic vapor product from pyrolyzable material, the method comprising burning fuel in a fluidized bed boiler, thereby heating some particulate material; transferring at least some of the heated particulate material or some other heated particulate material to a pyrolysis reactor to pyrolyze some pyrolyzable material in the pyrolysis reactor; and conveying at least some pyrolytic vapor through a catalyst bed comprising catalyst material; and conveying at least part of the formed side products upstream back to the process; thereby producing the catalytically treated pyrolytic vapor product in an resource efficient manner. In addition, a system configured to produce catalytically treated pyrolytic vapor product from pyrolyzable material. The system comprises a fluidized bed boiler; a pyrolysis reactor; a catalytic reactor; means for conveying some heated particulate material to the pyrolysis reactor; a pipeline for conveying at least some pyrolytic vapor from the pyrolysis reactor into the catalytic reactor and means for conveying at least part of the formed side products upstream back to the process for recovering heat and chemical energy bound to the side products.

A recycling method for plastic waste includes the steps of: (a) placing the plastic waste into a reactor; (b) heating the plastic waste in the reactor through a pyrolysis recovery process to generate flammable gas; (c) transferring flammable gas through a condensing unit to convert the flammable gas into liquid phase products; and (d) filtering the remaining out clean gas from the flammable gas by a filtration unit. A recycling system for plastic waste includes a reactor to decompose the plastic waste to create usable fuel products; a condensing unit operatively connected with the reactor; and a filtration unit operatively connected with said condensing unit to filter the usable fuel products.

A recycling method for plastic waste includes the steps of: (a) placing the plastic waste into a reactor; (b) heating the plastic waste in the reactor through a pyrolysis recovery process to generate flammable gas; (c) transferring flammable gas through a condensing unit to convert the flammable gas into liquid phase products; and (d) filtering the remaining out clean gas from the flammable gas by a filtration unit. A recycling system for plastic waste includes a reactor to decompose the plastic waste to create usable fuel products; a condensing unit operatively connected with the reactor; and a filtration unit operatively connected with said condensing unit to filter the usable fuel products.

A recycling method for plastic waste includes the steps of: (a) placing the plastic waste into a reactor; (b) heating the plastic waste in the reactor through a pyrolysis recovery process to generate flammable gas; (c) transferring flammable gas through a condensing unit to convert the flammable gas into liquid phase products; and (d) filtering the remaining out clean gas from the flammable gas by a filtration unit. A recycling system for plastic waste includes a reactor to decompose the plastic waste to create usable fuel products; a condensing unit operatively connected with the reactor; and a filtration unit operatively connected with said condensing unit to filter the usable fuel products.