Patent classifications
C10G1/002
PROCESS FOR THE PREPARATION OF AROMATICS FROM WASTE PLASTIC FEEDSTOCKS
The present invention relates to a process for the production of aromatics from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to one or more separation units; (f) performing a separation operation to obtain different streams comprising benzene, toluene, styrene, ethylbenzene and xylenes; wherein in step (d): ⋅ the coil outlet temperature is ≥800 and ≤80° C., preferably ≥830 and ≤870° C.; 7 and ⋅ the weight ratio of steam to feed C is >0.3 and <0.8, preferably >0.3 and <0.5. Such process allows for optimisation of the quantity of waste plastic material that finds its way back into products that are produced as outcome of the process. The higher that quantity is, i.e. the higher the quantity of chemical building blocks that are present in the waste plastic material that are converted to the produced products, the better the sustainability footprint of the process is. The process allows for circular utilisation of plastics.
METHOD FOR THE TREATMENT OF PLASTIC PYROLYSIS OILS INCLUDING SINGLE-STAGE HYDROCRACKING
The present invention relates to a process for treating a plastics pyrolysis oil, comprising: a) selective hydrogenation of said feedstock in the presence of at least hydrogen and of at least one selective hydrogenation catalyst; b) hydrotreatment of said hydrogenated effluent in the presence of at least hydrogen and of at least one hydrotreatment catalyst, to obtain a hydrotreated effluent; c) hydrocracking of said hydrotreated effluent in the presence of at least hydrogen and of at least one hydrocracking catalyst, to obtain a hydrocracked effluent; d) separation of the hydrocracked effluent in the presence of an aqueous stream, at a temperature of between 50 and 370° C., to obtain at least one gaseous effluent, an aqueous liquid effluent and a hydrocarbon-based liquid effluent.
METHOD FOR PROCESSING PYROLYSIS OILS FROM PLASTICS AND/OR SOLID RECOVERED FUELS LOADED WITH IMPURITIES
The present invention relates to a process for treating an SRF and/or plastics pyrolysis oil, comprising: a) optionally, selective hydrogenation of the feedstock; b) hydroconversion in an ebullated bed, in an entrained bed and/or in a moving bed, to obtain a hydroconverted effluent; c) separation of the hydroconverted effluent in the presence of an aqueous stream, to obtain a gaseous effluent, an aqueous liquid effluent and a liquid hydrocarbon effluent; d) fractionation of the liquid hydrocarbon effluent to obtain at least one gas stream and a cut with a boiling point of less than or equal to 385° C. and a cut with a boiling point above 385° C.; e) hydrotreatment of said cut comprising compounds with a boiling point of less than or equal to 385° C. to obtain a hydrotreated effluent; f) separation to obtain at least a gaseous effluent and a hydrotreated liquid hydrocarbon effluent.
CO-PROCESSING ROUTE FOR HYDROTREATING POLYMER WASTE-BASED MATERIAL
Provided is a method for upgrading polymer waste-based material. The method includes providing a polymer waste-based feedstock, providing a crude oil-derived feedstock, mixing the polymer waste-based feedstock, the crude oil-derived feedstock, and optionally a further feed material, to provide a feed mixture, hydrotreating the feed mixture in a FCC feed hydrotreater to provide a hydrocarbonaceous material, and recovering at least a distillate product and a distillation bottoms product from the hydrocarbonaceous material (step E).
Method and apparatus for producing biofuel
The present invention relates to the field of renewable energy. More specifically, the present invention relates to the production of biofuel from biomass including, for example, polymeric materials.
Terpolymers for oil sands tailings treatment
Terpolymers and use thereof are provided comprising one or more nonionic monomers, one or more anionic monomers and one or more cationic monomers, These terpolymers and compositions containing may be used as flocculants, for example, for treating tailings, such as oil sands tailings, to facilitate solid-liquid separation, for example, in order to efficiently recycle water and/or to reduce the volume of tailings which may be transferred to a tailings pond and/or to a dedicated disposal area.
Circular economy for plastic waste to polyethylene and lubricating oil via crude and isomerization dewaxing units
Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. In one embodiment, the process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit distillation column in a refinery where a straight run naphtha (C.sub.5-C.sub.8) fraction or a propane/butane (C.sub.3-C.sub.4) fraction is recovered. The straight run naphtha fraction (C.sub.5-C.sub.8) or the propane/butane (C.sub.3-C.sub.4) fraction is passed to a steam cracker for ethylene production. The heavy fraction from the pyrolysis unit can also be passed to an isomerization dewaxing unit to produce a base oil.
COMPOSITION OF MATTER OF PYOIL SUITABLE FOR CRACKING
A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. More particularly cracker feedstock comprises a recycle content pyrolysis oil composition (r-pyoil), wherein the cracker feedstock has a boiling point curve defined the following characteristics (i) through (iii): (i) a 90% boiling point at least 350° C.; (ii) a 10% boiling point of at least 60° C.; and (iii) a 50% boiling point in the range of from 95° C. to 200° C.
Thermal Pyoil to a Gas Fed Cracker Furnace
A predominantly C.sub.2 to C.sub.4 hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to a first coil while a second cracker feed with none of the r-pyoil or less of the r-pyoil is fed to a second coil, and both are cracked in a cracker furnace to form an olefin-containing effluent stream. Alternatively, the r-pyoil can be fed and distributed across multiple coils along with the non-recycle cracker feed. The furnace can be a gas fed furnace, or split cracker furnace. Further, a first cracker stream with r-pyoil in a first coil can have a lower total molar flow rate than a second cracker stream in a second coil in the same furnace.
PROCESS FOR THE PREPARATION OF POLYMERS FROM WASTE PLASTIC FEEDSTOCKS
A process for the production of polymers from waste plastics feedstocks includes: providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; optionally providing a hydrocarbon stream B; supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; supplying the cracked hydrocarbon stream D to a separation unit; performing a separation operation in the separation unit to obtain a product stream E comprising a monomer; supplying the product stream E to a polymerisation reactor; and performing a polymerisation reaction to obtain an polymer. The process allows for optimisation of the quantity of waste plastic material that finds its way back into a polymer that is produced as outcome of the process.