The present invention discloses a rapid evaluation method for quality of lignin-pyrolyzed bio-oil and an application thereof, and particularly relates to a rapid evaluation method for quality of lignin-pyrolyzed bio-oil based on radical detection and an application thereof. The method can be used to evaluate the quality of lignin-pyrolyzed bio-oil by detecting the spin concentration of radicals in lignin char obtained by lignin pyrolysis, thus avoiding the complex processes involved in the evaluation for the quality of conventional pyrolyzed bio-oils such as, extraction, separation and detection and reducing the detection costs substantially. The detection method of the present invention is simple and easy to operate, thus achieving the rapid evaluation for the quality of lignin-pyrolyzed bio-oil. Moreover, the detection method of the present invention is non-contact detection without destructive samples, which is applicable to the rapid detection on the quality of lignin-pyrolyzed bio-oil in the field of industry and scientific research. The present invention further broadens the application fields of radical detection and contributes to the development of radical detection technology in the field of pyrolysis, and provides a reliable method for the detection of lignin-pyrolyzed bio-oil, which has good application prospect.

This disclosure relates to the production of chemicals and plastics using pyrolysis oil from the pyrolysis of plastic waste as a co-feedstock along with a petroleum-based, fossil fuel-based, or bio-based feedstock. In an aspect, the polymers and chemicals produced according to this disclosure can be certified under International Sustainability and Carbon Certification (ISCC) provisions as circular polymers and chemicals at any point along complex chemical reaction pathways. The use of a mass balance approach which attributes the pounds of pyrolyzed plastic products derived from pyrolysis oil to any output stream of a given unit has been developed, which permits ISCC certification agency approval.

A process for producing diluent for use in a hydrocarbon recovery process includes heating a dilbit feed stream comprising hydrocarbons produced from a hydrocarbon reservoir and an added diluent, to a temperature of 350° C. or less, fractionating the dilbit feed stream after heating to produce a light fraction and a heavy fraction, the light fraction comprising the diluent, additional light hydrocarbons, and sour water, separating the sour water from a remainder of the light fraction, and stabilizing the remainder of the light fraction to provide recovered diluent and cooling the recovered diluent. A volume of the recovered diluent is greater than a volume of the added diluent.

Where thermochemical liquefaction of lignocellulosic biomass is conducted using recirculated product oil as solvent, yields can be substantially increased by addition of a short chain alcohol reactant such as ethanol or methanol. A synergistic effect is thereby obtained where liquefaction is improved over using either recycled product oil or alcohol alone. The combination of re-circulated product oil and alcohol reactant permits high conversion at operating pressures considerably lower than typically applied in alcohol solvolysis, typically within the range 30-60 bar. The liquefaction reaction occurs at subcritical pressure where the alcohol acts as a gaseous reactant and not as a solvent.

A system for processing a hydrocarbon feed has a final stage reactor and internal separator with cyclone that forms a substantially gas stream and a substantially non-gas stream. The substantially gas stream is sent directly from the final stage reactor and separator to further downstream processing.

A chemical recycling process and facility for turning one or more waste plastics into syngas are provided. Generally, the chemical recycling process involves: (a) liquefying at least one solid waste plastic to form a liquefied waste plastic; (b) introducing at least a portion of the liquefied waste plastic into a partial oxidation (POX) gasifier; and (c) converting at least a portion of the liquefied waste plastic in the POX gasifier into a syngas composition.

The invention provides a thermal cracking system which comprises a reactor, and a feed module or a solid product discharge module. The feed module transports a feed material from the outside environment to the reactor. While being transported, the feed material is heated by the feed module to become molten and fills up the interior of the feed module, thereby preventing air from entering the reactor. The solid product discharge module transports a solid product from the reactor to the outside environment. One end of the solid product discharge module is connected with the reactor. The other end of the solid product discharge module comprises a first opening interfacing with the outside environment. When the solid product is transported to the outside environment, the opening size of the first opening is selected such that the speed at which the solid product is entering the solid product discharge module form the reactor is equal to or greater than that at which the solid product is leaving the solid product discharge module, through the first opening, and into the outside environment. Benefit of the invention includes a higher production efficiency and enhanced safety for a thermal cracking system at industrial scale.

Device and process for the conversion of a feedstock of aromatic compounds, in which the feedstock is treated notably by means of a fractionation train (4-7), a xylene separation unit (10) and an isomerization unit (11), and in which a pyrolysis unit (13) treats a second hydrocarbon feedstock, produces a pyrolysis effluent feeding the feedstock, and produces a pyrolysis gas comprising CO, CO.sub.2 and H.sub.2; a reverse water gas shift RWGS reaction section (50) treats the pyrolysis gas and produces an RWGS gas enriched in CO and in water; a fermentation reaction section (52) treats the RWGS gas enriched in CO and in water, to produce ethanol and recycle the ethanol to the inlet of the pyrolysis unit.

Method of producing pyrolysis products from mixed plastics along with an associated system for processing mixed plastics. The method includes conducting pyrolysis of a plastic feedstock to produce plastic pyrolysis oil; feeding the plastic pyrolysis oil to a first fractionator to separate the plastic pyrolysis oil into a distillate fraction and a vacuum gas oil fraction; and feeding the distillate fraction to a two step oligomerization operation. The two step oligomerization operation includes feeding the distillate fraction to a first hydrotreating unit to remove di-olefins to produce a first product stream and feeding the first product stream to an olefin oligomerization reactor to react and combine mono-olefins into longer chain olefins. Such system may be integrated with a conventional refinery.

Electric-powered, closed-loop, continuous-feed, endothermic energy-conversion systems and methods are disclosed. In one embodiment, the presently disclosed energy-conversion system includes a shaftless auger. In another embodiment, the presently disclosed energy-conversion system includes a drag conveyor. In yet another embodiment, the presently disclosed energy-conversion system includes a distillation and/or fractionating stage. The endothermic energy-conversion systems and methods feature mechanisms for natural resource recovery, refining, and recycling, such as secondary recovery of metals, minerals, nutrients, and/or carbon char.