A recycle content cellulose ester and method of making a recycle content cellulose ester wherein the recycle content is derived directly or indirectly from the cracking of recycle content pyrolysis oil and/or gas. The cracking of the pyrolysis oil can be conducted in a gas furnace or a split furnace.

This process comprises quenching and washing with water a gas stream derived from pyrolysis, and separating an aqueous phase from a washed gas stream; compressing, then cooling a washed gas stream; washing the compressed gas stream under pressure; passing the washed gas stream through at least one acid removal unit; drying the acid-depleted gas stream; passing the dry gas stream through at least one impurity removal unit; and feeding the purified gas stream into a cryogenic absorption unit and supplying the cryogenic absorption unit with a hydrocarbon cryogenic solvent to obtain a light gas residue, and a fraction of C.sub.2.sup.+ hydrocarbons.

The process and apparatus according to the invention allow the production of hydrocarbons and ammonia without the use of catalysts. For this purpose, waste gases containing CO.sub.2 or N.sub.2 from an upstream process are fed to compression reactors. In addition, hydrogen from an electrolyzer is fed to these reactors to enable hydrogenation of the fed substances. Methane, alcohols and ammonia, for example, can be produced by this process. In order to increase the yield of the process, it is planned to raise the reactant pressure with the aid of a compressor.

A furnace, and a method of firing it, wherein part of the fuel supplied to the furnace is produced from waste plastics by a depolymerisation process, waste heat from the furnace being used to promote the depolymerisation process. The furnace is equipped with regenerators for waste heat recovery and is fired alternately in first and second opposed directions, with the direction of firing periodically reversing between the first direction and the second direction. The supply of fuel to the furnace is temporarily interrupted while the direction of firing is reversing, means being provided to accommodate the fuel produced during the temporary interruption. The furnace may be used for producing glass.

A furnace, and a method of firing it, wherein part of the fuel supplied to the furnace is produced from waste plastics by a depolymerisation process, waste heat from the furnace being used to promote the depolymerisation process. The furnace is equipped with regenerators for waste heat recovery and is fired alternately in first and second opposed directions, with the direction of firing periodically reversing between the first direction and the second direction. The supply of fuel to the furnace is temporarily interrupted while the direction of firing is reversing, means being provided to accommodate the fuel produced during the temporary interruption. The furnace may be used for producing glass.

A method for producing a vapor stream from waste plastic comprises providing a waste plastic feedstock into a reactor containing one or more residues produced from a previously heated source of waste plastic, and heating the waste plastic feedstock in the reactor to a temperature from about 125° C. to 500° C. to generate a vapor containing one or more hydrocarbons. The waste plastic feedstock can have a calcium to sodium mass ratio from about 0.0001 to 400 as measured by inductively-coupled plasma (ICP) spectrometry. The catalytic activity in the reactor may be provided through one or more constituent elements in the waste plastic feedstock or the one or more residues produced from the previously heated source of waste plastic.

A method for producing a vapor stream from waste plastic comprises providing a waste plastic feedstock into a reactor containing one or more residues produced from a previously heated source of waste plastic, and heating the waste plastic feedstock in the reactor to a temperature from about 125° C. to 500° C. to generate a vapor containing one or more hydrocarbons. The waste plastic feedstock can have a calcium to sodium mass ratio from about 0.0001 to 400 as measured by inductively-coupled plasma (ICP) spectrometry. The catalytic activity in the reactor may be provided through one or more constituent elements in the waste plastic feedstock or the one or more residues produced from the previously heated source of waste plastic.

A pyrolysis method and system are provided that utilizes a multistage dehalogenation method to effectively remove halogen-containing compounds that are present in an initial recycled plastic feedstock. More particularly, the multistage dehalogenation system and process may involve physical sorting the plastic feedstock, melting and separating the feedstock, and subjecting the feedstock a two-stage pyrolysis with intermediate HCl removal.

A pyrolysis method and system are provided that utilizes a multistage dehalogenation method to effectively remove halogen-containing compounds that are present in an initial recycled plastic feedstock. More particularly, the multistage dehalogenation system and process may involve physical sorting the plastic feedstock, melting and separating the feedstock, and subjecting the feedstock a two-stage pyrolysis with intermediate HCl removal.

A pyrolysis method and system are provided that utilizes a hydrogen gas or steam in order to enhance the pyrolysis oils produced from recycled plastic wastes. More particularly, the disclosed pyrolysis method and system may be configured to co-feed a hydrogen gas or steam and various types of waste plastics, including post-customer and post-industrial wastes, into a pyrolysis unit and thereby produce desirable pyrolysis oils.