Process for isomerization of paraffinic feedstocks operating at a temperature of between 200 C. and 500 C., at a total pressure of between 0.45 MPa and 7 MPa, at a partial pressure of hydrogen of between 0.3 and 5.5 MPa, at an hourly space velocity of between 0.1 and 10 kg of feedstock introduced per kg of catalyst and per hour, using a catalyst having at least one group VIII metal, at least one matrix and at least one IZM-2 zeolite, the total weight content of alkali metal and/or alkaline-earth metal elements is less than 200 ppm by weight relative to the total mass of said catalyst.

The present disclosure describes systems and methods for producing eFuels or chemicals such as sustainable aviation fuel, renewable diesel, methanol, and ammonia, as well as the synthesis of oxygenated and non-oxygenated chemical feedstocks. Electrolyzers, CO2 capture devices, Reverse Water Gas Shift (RWGS) reactors, syngas conversion reactors, and electrical steam methane reformers (eSMR) are used to produce eFuel.

Disclosed is an electrochemical process to simultaneously produce a syngas suitable for the Fischer-Tropsch (F-T) process and oxygen. In an example embodiment, the process includes feeding steam and CO.sub.2 to an intermediate temperature (e.g., <700 C.) electrochemical reactor to produce separate CO-rich and O.sub.2-rich streams. An additional electrochemical reactor can be used to produce H.sub.2. The H.sub.2 is combined with CO from the first reactor to produce a syngas mixture ideal for a downstream F-T process. Alternatively, the electrochemical reactor can produce methane directly or a methanol stream for conversion to a hydrocarbon fuel.

Methods of preparing syngas are provided. An exemplary method can include hydrogenation of carbon dioxide (CO.sub.2) via a reverse water gas shift (RWGS) reaction. Catalysts that include Cu and/or Mn can be used, and the RWGS reaction can be conducted at a temperature greater than 600 C. The syngas produced from hydrogenation of CO.sub.2 can be used to generate light olefins via a Fischer-Tropsch synthesis (FT) reaction.

A method of synthesizing fuel from an aqueous solution includes pumping the aqueous solution, containing dissolved inorganic carbon, from a body of water into a carbon extraction unit. The method further includes extracting the dissolved inorganic carbon from the aqueous solution to create CO.sub.2 by changing a pH of the aqueous solution in the carbon extraction unit. The CO.sub.2 derived in the carbon extraction unit is received by a fuel synthesis unit, and the CO.sub.2 is converted into fuel including at least one of a hydrocarbon, an ether, or an alcohol using the fuel synthesis unit.

A feedstock delivery system transfers a carbonaceous material, such as municipal solid waste, into a product gas generation system. The feedstock delivery system includes a splitter for splitting bulk carbonaceous material into a plurality of carbonaceous material streams. Each stream is processed using a weighing system for gauging the quantity of carbonaceous material, a densification system for forming plugs of carbonaceous material, a de-densification system for breaking up the plugs of carbonaceous material, and a gas and carbonaceous material mixing system for forming a carbonaceous material and gas mixture. A pressure of the mixing gas is reduced prior to mixing with the carbonaceous material, and the carbonaceous material to gas weight ratio is monitored. A transport assembly conveys the carbonaceous material and gas mixture to a first reactor where at least the carbonaceous material within the mixture is subject to thermochemical reactions to form the product gas.

Ultra-clean char is used to generate hydrocarbons and/or electricity in a clean environmentally friendly process. The ultra-clean char is produced by pyrolizing organic matter, such as coal or various organic waste. The pyrolized organic matter may be combusted in the presence of oxygen to produce heat, which can be used to generate electricity in a conventional boiler/generator system. Further, pyrolized organic matter can be combusted in the presence of carbon dioxide and further processed to produce various hydrocarbons. In other embodiments, the ultra-clean char may be subjected to an extraction process for capturing valuable rare earth elements.

The disclosure relates to the conversion of a paraffinic feedstock that comprises at least 50 wt % of compounds boiling above 370 c. and which has a paraffin content of at least 60 wt %, an aromatics content of below 1 wt %, a naphthenic content below 2 wt %, a nitrogen content of below 0.1 wt % The process includes: a) subjecting the paraffinic feedstock to a hydroprocessing step to obtain an at least partially isomerized feedstock; and b) separating the at least partially isomerized feedstock into one or more middle distillate fractions and a first residual fraction. Step (a) is carried out by contacting the paraffinic feedstock with a first catalyst having hydrocracking and hydroisomerizing activity and then with a second catalyst having hydrocracking and hydroisomerizing activity. The second catalyst is more active in hydroisomerization and less active in hydrocracking than the first catalyst.

Disclosed herein is a method comprising the steps of: a) producing a hydrocarbon stream from syngas via a Fischer-Tropsch reaction, wherein the hydrocarbon stream comprises a first C2 hydrocarbon stream comprising ethane and a first ethylene product; b) separating at least a portion of the first C2 hydrocarbon stream from the hydrocarbon stream; c) separating at least a portion of the first ethylene product from the first C2 hydrocarbon stream, thereby producing a second C2 hydrocarbon stream; d) converting at least a portion of the ethane in the second C2 hydrocarbon stream to a second ethylene product; and e) producing polyethylene from at least a portion of the second ethylene product.

Process for the production of a synthesis gas for use in the production of chemical compounds from a hydrocarbon feed stock containing higher hydrocarbons comprising the steps of: (a) in a pre-reforming stage pre-reforming the feed stock with steam to a pre-reformed gas containing methane, hydrogen, carbon monoxide and carbon dioxide; and (b) cooling the pre-reformed gas to below its dewpoint and removing condensed water; and (c) reducing the amount of carbon dioxide the in the pre-reformed gas from step (b) to obtain a module of (H.sub.2CO.sub.2)/(CO+CO.sub.2) of between 1.0 and 3.8 in the pre-reformed gas.