Patent classifications
C10G9/14
PROCESS FOR THE PREPARATION OF AROMATICS FROM WASTE PLASTIC FEEDSTOCKS
The present invention relates to a process for the production of aromatics from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by hydrotreatment of pyrolysis oil produced from a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and optionally a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to one or more separation units; (f) performing a separation operation to obtain different streams comprising benzene, toluene, styrene, ethylbenzene and xylenes; wherein in step (d): ⋅ the coil outlet temperature is ≥800 and ≤850° C., preferably ≥805 and ≤835° C.; and ⋅ the weight ratio of steam to feed C is >0.3 and <0.8, preferably >0.3 and <0.5. Such process allows for optimisation of the quantity of waste plastic material that finds its way back into products that are produced as outcome of the process. The higher that quantity is, i.e. the higher the quantity of chemical building blocks that are present in the waste plastic material that are converted to the produced products, the better the sustainability footprint of the process is. The process allows for circular utilisation of plastics.
PROCESS FOR THE PREPARATION OF AROMATICS FROM WASTE PLASTIC FEEDSTOCKS
The present invention relates to a process for the production of aromatics from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to one or more separation units; (f) performing a separation operation to obtain different streams comprising benzene, toluene, styrene, ethylbenzene and xylenes; wherein in step (d): ⋅ the coil outlet temperature is ≥800 and ≤80° C., preferably ≥830 and ≤870° C.; 7 and ⋅ the weight ratio of steam to feed C is >0.3 and <0.8, preferably >0.3 and <0.5. Such process allows for optimisation of the quantity of waste plastic material that finds its way back into products that are produced as outcome of the process. The higher that quantity is, i.e. the higher the quantity of chemical building blocks that are present in the waste plastic material that are converted to the produced products, the better the sustainability footprint of the process is. The process allows for circular utilisation of plastics.
PROCESS FOR THE PREPARATION OF POLYMERS FROM WASTE PLASTIC FEEDSTOCKS
A process for the production of polymers from waste plastics feedstocks includes: providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; optionally providing a hydrocarbon stream B; supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; supplying the cracked hydrocarbon stream D to a separation unit; performing a separation operation in the separation unit to obtain a product stream E comprising a monomer; supplying the product stream E to a polymerisation reactor; and performing a polymerisation reaction to obtain an polymer. The process allows for optimisation of the quantity of waste plastic material that finds its way back into a polymer that is produced as outcome of the process.
PROCESS FOR THE PREPARATION OF POLYMERS FROM WASTE PLASTIC FEEDSTOCKS
A process for the production of polymers from waste plastics feedstocks includes: providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; optionally providing a hydrocarbon stream B; supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; supplying the cracked hydrocarbon stream D to a separation unit; performing a separation operation in the separation unit to obtain a product stream E comprising a monomer; supplying the product stream E to a polymerisation reactor; and performing a polymerisation reaction to obtain an polymer. The process allows for optimisation of the quantity of waste plastic material that finds its way back into a polymer that is produced as outcome of the process.
PROCESS FOR THE PREPARATION OF BUTENES AND BUTADIENES FROM WASTE PLASTIC FEEDSTOCKS
Process for the production of butenes and butadienes from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to one or more separation units; and (f) performing a separation operation to obtain different streams comprising isobutene, 1-butene, 2-butene, 1,2-butediene and 1,3-butadiene; wherein in step (d): • the coil outlet temperature is ≥ 800 and ≤ 850° C. and • the weight ratio of steam to feed C is > 0.3 and < 0.8.
PROCESS FOR THE PREPARATION OF POLYETHYLENES FROM WASTE PLASTIC FEEDSTOCKS
The present invention relates to a process for the production of ethylene-based polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by hydrotreatment of a pyrolysis oil produced from a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and optionally a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising ethylene; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an ethylene-based polymer; wherein in step (d): • ⋅ the coil outlet temperature is 2: 800 and; 870° C., preferably 2: 820 and; 870° C.; and • ⋅ the weight ratio of steam to feed C is >0.3 and <0.8.
PROCESS FOR THE PREPARATION OF BUTENES AND BUTADIENES FROM WASTE PLASTIC FEEDSTOCKS
Process for the production of butenes and butadienes from waste plastics feedstocks comprising the steps: (a) providing a hydrocarbon stream A obtained by hydrotreatment of pyrolysis oil produced from a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and optionally a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to one or more separation units; and (f) performing a separation operation to obtain different streams comprising isobutene, 1-butene, 2-butene, 1,2-butediene and 1,3-butadiene; wherein in step (d): • the coil outlet temperature is ≥ 800 and ≤ 850° C.; and • the weight ratio of steam to feed C is > 0.3 and < 0.8-
PROCESS FOR THE PREPARATION OF CHEMICAL PRODUCTS FROM WASTE PLASTIC FEEDSTOCKS
The present invention relates to a process for the production of butenes and butadienes from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to one or more separation units; (f) performing a separation operation to obtain different streams of chemical products comprising ethylene, propylene, isobutene, 1-butene, 2-butene, 1,2-butadiene, 1,3-butadiene, benzene, styrene, toluene, ethylbenzene and xylenes; wherein in step (d): ⋅ the coil outlet temperature is ≥800 and ≤870° C., preferably ≥805 and ≤835° C.; and ⋅ the weight ratio of steam to feed C is >0.3 and <0.8, preferably >0.3 and <0.5. Such process allows for optimisation of the quantity of waste plastic material that finds its way back into products that are produced as outcome of the process. The higher that quantity is, i.e. the higher the quantity of chemical building blocks that are present in the waste plastic material that are converted to the produced products, the better the sustainability footprint of the process is. The process allows for circular utilisation of plastics.
Separation of viscous oils into components
The invention provides methods for treating a source oil phase consisting of heavy oil, bitumen, a mixture of heavy oil and bitumen, a mixture of solvent and heavy oil or bitumen or both. The method comprises: introducing the source oil phase to a lower reservoir section of a device, flowing the source oil phase through an array of vertically extending heated pipes with an inert gas so as to thermally separate a vaporized light oil phase component from a heated liquid source oil phase, and segregating fluid flows by density in an upper fluid separating manifold to provide a light product fluid and a heavy product fluid.
Separation of viscous oils into components
The invention provides methods for treating a source oil phase consisting of heavy oil, bitumen, a mixture of heavy oil and bitumen, a mixture of solvent and heavy oil or bitumen or both. The method comprises: introducing the source oil phase to a lower reservoir section of a device, flowing the source oil phase through an array of vertically extending heated pipes with an inert gas so as to thermally separate a vaporized light oil phase component from a heated liquid source oil phase, and segregating fluid flows by density in an upper fluid separating manifold to provide a light product fluid and a heavy product fluid.