The invention provides a process to purify a gas stream by using an adsorbent bed and a secondary device to remove heavy hydrocarbons with a recycle stream then sent first to a vessel containing an amine solvent to remove acid gases including carbon dioxide and hydrogen sulfide and then in most embodiments of the invention sending the treated gas stream to a dehydration unit such as an adsorbent bed or to a triethylene glycol absorbent to remove water. The invention further provides improved integration of the process streams to allow for smaller amine solvent and dehydration units as compared to the prior art.

A process and device for reducing the environmental contaminants in a ISO 8217 compliant Feedstock Heavy Marine Fuel Oil, the process involving: mixing a quantity of the Feedstock Heavy Marine Fuel Oil with a quantity of Activating Gas mixture to give a feedstock mixture; contacting the feedstock mixture with one or more catalysts to form a Process Mixture from the feedstock mixture; separating the Product Heavy Marine Fuel Oil liquid components of the Process Mixture from the gaseous components and by-product hydrocarbon components of the Process Mixture and, discharging the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil is compliant with ISO 821 7 for residual marine fuel oils and has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05% wt. to 0.5% wt. The Product Heavy Marine Fuel Oil can be used as or as a blending stock for an ISO 8217 compliant, IMO MARPOL Annex VI (revised) compliant low sulfur or ultralow sulfur heavy marine fuel oil.

A photovoltaic module comprising: (a) a photovoltaic laminate including: two or more electrically conducting dements extending through the photovoltaic laminate so that power is moved from one photovoltaic module towards another photovoltaic module or towards an inverter; and (b) one or more connectors connected to each of the two or more electrically conducting elements by a connection joint, each of the one or more connectors include: two or more opposing terminals that each are connected to and extend from one of the two or more electrically conducing elements; wherein a dielectric space is located between the two or more opposing terminals and the dielectric space blocks material used to form a connection joint from passing from a first terminal to a second terminal, the material from the connection joint cools before the material passes from one terminal to a second terminal, the material fails to travel from the first terminal to the second terminal, or a combination thereof.

The present invention provides a method which can efficiently adsorb and remove ionic mercury and/or organic mercury contained in a hydrocarbon oil for a long period of time. The method involves bringing the hydrocarbon oil into contact with an adsorbent containing a layered silicate mineral having an interlayer charge of 0 or an interlayer charge of greater than 0 to 0.6 or less.

Methods of forming a nanocomposite of a base material and a plurality of nanoparticles are provided. In embodiments, the method comprises combining a first input stream of flowing fluid comprising a base material having nucleation sites, a second input stream of flowing fluid comprising a nanoparticle precursor material, and a third input stream of flowing fluid comprising a nanoparticle nucleation agent, to form an output stream of flowing fluid; heating or sonicating or both heating and sonicating the output stream for a period of time; and collecting a nanocomposite formed within the fluid of the output stream, the nanocomposite comprising the base material and a plurality of nanoparticles directly anchored onto a surface of the base material via the nucleation sites. The nanocomposites are also provided.

A catalyst system comprising a combination of: 1) one or more catalyst compounds comprising at least one oxygen linkage, such as a phenoxide transition metal compound; 2) a support comprising an organosilica material, which may be a mesoporous organosilica material; and 3) an optional activator. Useful catalysts include biphenyl phenol catalysts (BPP). The organosilica material may be a polymer of at least one monomer of Formula [Z.sup.1OZ.sup.2SiCH.sub.2].sub.3 (I), where Z.sup.1 represents a hydrogen atom, a C.sub.1-C.sub.4 alkyl group, or a bond to a silicon atom of another monomer and Z.sup.2 represents a hydroxyl group, a C.sub.1-C.sub.4 alkoxy group, a C.sub.1-C.sub.6 alkyl group, or an oxygen atom bonded to a silicon atom of another monomer. This invention further relates to processes to polymerize olefins comprising contacting one or more olefins with the above catalyst system.

The present invention relates to the use of adsorbents comprising zinc oxide nanowires decorated with catalytically active metal particles for the removal of sulfur from hydrocarbon feedstocks, including the desulfurization of diesel fuels and the deep desulfurization of natural gas, and to the use of decorated zinc oxide nanowire adsorbents for the hydrogenation of naphthalene selectively to tetralin in the presence of sulfur compounds. The adsorbent comprises nickel metal particles or nickel-zinc alloy particles deposited on zinc oxide nanowires.

Materials and methods for mitigating the effects of halide species contained in process streams are provided. A halide-containing process stream can be contacted with mitigation materials comprising active metal oxides and a non-acidic high surface area carrier combined with a solid, porous substrate. The halide species in the process stream can be reacted with the mitigation material to produce neutralized halide salts and a process stream that is essentially halide-free. The neutralized salts can be attracted and retained on the solid, porous substrate.

Systems and methods for separating hydrocarbons on an internal combustion powered vehicle via one or more metal organic frameworks are disclosed. Systems and methods can further include utilizing separated hydrocarbons and exhaust to generate hydrogen gas for use as fuel. In one aspect, a method for separating hydrocarbons can include contacting a first component containing a first metal organic framework with a flow of hydrocarbons and separating hydrocarbons by size. In certain embodiments, the hydrocarbons can include alkanes.

The disclosure provides a process to hydrodearylate the non-condensed alkyl-bridged multi-aromatics at the outlet of the clay tower where such multi-aromatics form rather than performing hydrodearylation on the reject stream of the aromatics complex. Hydrodearylation may feature combining a C.sub.8+ hydrocarbon stream from a clay treater with a hydrogen stream over a catalyst bed comprising a support and an acidic component optionally containing Group 8 and/or Group 6 metals.