The present invention relates to a sequential thermo-chemical treatment along with adsorption-based pre-treatment process for residual oils having a very high naphthenic acid content. First stage of the process is a thermal pre-treatment step which results into generation of hydrocarbon stream with a reduced naphthenic acid content due to high temperature. In second stage of pre-treatment, generated hydrocarbon stream from stage-1 is subjected to esterification reaction with alcohol, such as methanol, to further reduce the TAN of hydrocarbon stream. After recovery of alcohol from the reaction mixture, depending on TAN reduction required reaction mixture may be subjected to an adsorption stage, third stage pre-treatment, where an adsorbent mixture comprising of FCC spent catalyst is used to adsorb the TAN of feed hydrocarbon stream. The treated hydrocarbon stream is then co-processed with DCU feed stock for producing lighter hydrocarbons.

The present invention relates to a sequential thermo-chemical treatment along with adsorption-based pre-treatment process for residual oils having a very high naphthenic acid content. First stage of the process is a thermal pre-treatment step which results into generation of hydrocarbon stream with a reduced naphthenic acid content due to high temperature. In second stage of pre-treatment, generated hydrocarbon stream from stage-1 is subjected to esterification reaction with alcohol, such as methanol, to further reduce the TAN of hydrocarbon stream. After recovery of alcohol from the reaction mixture, depending on TAN reduction required reaction mixture may be subjected to an adsorption stage, third stage pre-treatment, where an adsorbent mixture comprising of FCC spent catalyst is used to adsorb the TAN of feed hydrocarbon stream. The treated hydrocarbon stream is then co-processed with DCU feed stock for producing lighter hydrocarbons.

The present invention reduces viscosity of highly viscous materials before entering a pump inlet by applying radio-frequency heating to the volume of material in a cage of rods that serve as electrodes surrounding a perforated inlet conduit. Applications include heavy hydrocarbonaceous materials such as tar and pitch in reservoirs, and sludge accumulating within oil storage tanks, ships, and barges. A mixer can be added to aid the process.

The present invention reduces viscosity of highly viscous materials before entering a pump inlet by applying radio-frequency heating to the volume of material in a cage of rods that serve as electrodes surrounding a perforated inlet conduit. Applications include heavy hydrocarbonaceous materials such as tar and pitch in reservoirs, and sludge accumulating within oil storage tanks, ships, and barges. A mixer can be added to aid the process.

A Filter for the removal of water from oil, the filter includes a distillation element having an inlet pipe that in one end is to be fluidly connectable to a reservoir of oil to be filtered, and in the other end being fluidly connected to a distillation head, said distillation head including a plurality of compressing tubes for injecting under pressure said oil into an evaporation chamber, whereby eventual water within the oil droplet evaporates from said decompressed oil, the filter further including a tubular core with a plurality of apertures and a hollow interior, said core having an open end for fluid communication with the hollow interior, a length of yarn wound around an outer surface of the core, wherein the filter further includes a device for blowing air or an inert gas into the evaporation chamber for removal of the water vapor during use of the filter. A method of manufacturing such a filter, as well as a method of removing water of is also disclosed. The water removal unit is part of a modular system, which makes the whole filter unit scalable within fixed steps. When water removing block with attached start block and end block, are stacked upon each other, and connected to filter unit, it becomes scalable complete cleaning equipment. Pump and motor must be adapted to each configuration.

Disclosed herein is a system comprising: a) a separator tank comprising a first inlet, a second inlet, a first outlet, and a second outlet, b) a heat exchanger, and c) a holding tank comprising a third inlet and a third outlet, wherein the separator tank is in fluid communication with the holding tank via a first connector and via a second connector, wherein the first connector is connected to the first outlet of the separator tank and to the third inlet of the holding tank, wherein the second connector is connected to the first inlet of the separator tank and to the third outlet of the holding tank, and wherein the first connector and the second connector are in communication with the heat exchanger.

Disclosed herein is a system comprising: a) a separator tank comprising a first inlet, a second inlet, a first outlet, and a second outlet, b) a heat exchanger, and c) a holding tank comprising a third inlet and a third outlet, wherein the separator tank is in fluid communication with the holding tank via a first connector and via a second connector, wherein the first connector is connected to the first outlet of the separator tank and to the third inlet of the holding tank, wherein the second connector is connected to the first inlet of the separator tank and to the third outlet of the holding tank, and wherein the first connector and the second connector are in communication with the heat exchanger.

Embodiments of the disclosure include processes using microwave heating to promote the separation of components of crude oil. In some embodiments, microwave-heated water may be used to heat the interphase between the gas phase and the oil phase of a crude oil stream to promote the separation of sulfur (for example, H.sub.2S) and light end components of the crude oil stream. In some embodiments, microwave-heated water may be used to heat the interphase between the oil phase and the water phase of a crude oil stream to promote the separation of water, salt, or both of the crude oil stream. Systems having a microwave unit to provide microwave-heated water to crude oil stream are also provided.

Process and apparatus for recovering a product stream from a waste plastic feedstock and reducing the endpoint of the product stream is provided. A polymer oil is produced as a product stream by pyrolyzing the waste plastic feedstock in a pyrolysis reactor to produce a pyrolysis reactor effluent and passing the reactor effluent stream to a contact condensing column. In the contact condensing column, the pyrolysis reactor effluent stream is separated into a vapor product stream and a liquid product stream. The vapor product stream is recovered from the condensing column and the liquid product stream is passed back to the pyrolysis reactor for further reduction.

Process and apparatus for recovering a product stream from a waste plastic feedstock and reducing the endpoint of the product stream is provided. A polymer oil is produced as a product stream by pyrolyzing the waste plastic feedstock in a pyrolysis reactor to produce a pyrolysis reactor effluent and passing the reactor effluent stream to a contact condensing column. In the contact condensing column, the pyrolysis reactor effluent stream is separated into a vapor product stream and a liquid product stream. The vapor product stream is recovered from the condensing column and the liquid product stream is passed back to the pyrolysis reactor for further reduction.