A process for preparing hydrocarbons from an oxygenated hydrocarbon feedstock, such as animal fat, having a high nitrogen impurity is described. Hydrotreatment of the oxygenated feedstock occurs in a first hydrotreating bed arranged downstream of a polishing bed. A gaseous phase is removed and the liquid hydrotreated phase is fed to the polishing bed arranged upstream of the first hydrotreating bed together with fresh hydrogen. The process effectively removes nitrogen impurities from the resultant hydrocarbon product causing an improved cloud point after isomerisation, and the arrangement makes efficient use of fresh hydrogen for polishing, providing a polished hydrocarbon product rich in dissolved hydrogen. Part of the product can be used as hydrocarbon diluent in the downstream hydrotreating bed, and/or withdrawn between the polishing and hydrotreating bed and isomerised in an isomerisation reactor.

High-quality graphite/needle grade coke is produced with reduced impurity levels and improved coefficient of thermal expansion using an integrated hydrotreatment, catalytic cracking and coking reaction sections, employing a combination of highly paraffinic hydrotreated VGO stream and aromatic CLO stream, which is thereafter processed in a delayed coking section.

High-quality graphite/needle grade coke is produced with reduced impurity levels and improved coefficient of thermal expansion using an integrated hydrotreatment, catalytic cracking and coking reaction sections, employing a combination of highly paraffinic hydrotreated VGO stream and aromatic CLO stream, which is thereafter processed in a delayed coking section.

A method of converting a liquid hydrocarbon stream to lower boiling point hydrocarbons includes converting the liquid hydrocarbon stream to an aerosolized hydrocarbon particle stream, introducing a charge to the aerosolized hydrocarbon particle stream to produce a charged aerosolized hydrocarbon particle stream including positively charged aerosolized hydrocarbon particles or negatively charged aerosolized hydrocarbon particles, contacting the aerosolized hydrocarbon particle stream with an aerosolized reaction catalyst, subjecting the aerosolized hydrocarbon particle stream to reaction conditions, thereby forming the lower boiling point hydrocarbons, and separating the lower boiling point hydrocarbons from the charged aerosolized hydrocarbon particle stream. The reaction conditions include a temperature of from 25° C. to 1,000° C. and a pressure of from 0 bar to 15 bar. The lower boiling point hydrocarbons includes at least C.sub.2-C.sub.4 olefins.

A method of converting a liquid hydrocarbon stream to lower boiling point hydrocarbons includes converting the liquid hydrocarbon stream to an aerosolized hydrocarbon particle stream, introducing a charge to the aerosolized hydrocarbon particle stream to produce a charged aerosolized hydrocarbon particle stream including positively charged aerosolized hydrocarbon particles or negatively charged aerosolized hydrocarbon particles, contacting the aerosolized hydrocarbon particle stream with an aerosolized reaction catalyst, subjecting the aerosolized hydrocarbon particle stream to reaction conditions, thereby forming the lower boiling point hydrocarbons, and separating the lower boiling point hydrocarbons from the charged aerosolized hydrocarbon particle stream. The reaction conditions include a temperature of from 25° C. to 1,000° C. and a pressure of from 0 bar to 15 bar. The lower boiling point hydrocarbons includes at least C.sub.2-C.sub.4 olefins.

The present disclosure provides a method of treating waste plastic pyrolysis oil. The method includes a first step of washing waste plastic pyrolysis oil with water and then removing moisture; a second step of mixing the waste plastic pyrolysis oil from which the moisture is removed and a sulfur source to prepare a mixed oil; a third step of hydrotreating the mixed oil with hydrogen gas in the presence of a hydrotreating catalyst; a fourth step of separating the hydrotreated mixed oil into a liquid stream and a gas stream to obtain liquid pyrolysis oil; and a fifth step of recovering hydrogen gas from the separated gas stream and recycling the recovered hydrogen gas to the third step.

The present disclosure provides a method of treating waste plastic pyrolysis oil. The method includes a first step of washing waste plastic pyrolysis oil with water and then removing moisture; a second step of mixing the waste plastic pyrolysis oil from which the moisture is removed and a sulfur source to prepare a mixed oil; a third step of hydrotreating the mixed oil with hydrogen gas in the presence of a hydrotreating catalyst; a fourth step of separating the hydrotreated mixed oil into a liquid stream and a gas stream to obtain liquid pyrolysis oil; and a fifth step of recovering hydrogen gas from the separated gas stream and recycling the recovered hydrogen gas to the third step.

A process for separating and upgrading a hydrocarbon feed includes passing the hydrocarbon feed to a distillation unit to separate it into at least a naphtha stream and a residue, passing the naphtha stream to a NHT that hydrotreats the naphtha stream to produce a hydrotreated naphtha, passing the hydrotreated naphtha to a NREF that reforms the hydrotreated naphtha to produce a reformate, passing the reformate to an ARC that processes the reformate to produce at least one aromatic product effluent and an aromatic bottoms stream, passing at least a portion of the residue to a residue hydroprocessing unit that hydroprocesses the portion of the residue to produce a hydroprocessed effluent, and passing a portion of the aromatic bottoms stream to the residue hydroprocessing unit to increase the solubility of the asphaltene compounds and reduce sedimentation. Systems for conducting the process are also disclosed.

A process for preparing hydrocarbons from an oxygenated hydrocarbon feedstock, such as animal fat, having a high nitrogen impurity is described. The process involves hydrotreatment of the oxygenated feedstock in a first hydrotreating reactor and a further hydrotreatment in a second hydrotreating reactor, where between the two reactors, the gaseous phase is removed. The specific process setup effectively removes nitrogen impurities from the resultant hydrocarbon product causing an improved cloud point after isomerisation.

For the shipping industry, these fuels provide solutions to long outstanding technical problems that heretofore hindered supply of low sulfur marine fuels in quantities needed to meet worldwide sulfur reduction goals. When ships on the open seas burn cheap low grade heavy bunker oils high in sulfur, nitrogen and metals, the SOx, NOx, and metal oxides go to the environment. This invention converts essentially all of each barrel of crude feed to a single ultraclean fuel versus conventional refining where crude feed is cut into many pieces, and each piece is sent down a separate market path meeting various different product specifications. When in port, ships can generate and sell electricity to land based electrical grids to offset fuel cost in an environment-friendly manner.