C10G45/58

Circular economy for plastic waste to polyethylene and lubricating oil via crude and isomerization dewaxing units
11473016 · 2022-10-18 · ·

Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. In one embodiment, the process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit distillation column in a refinery where a straight run naphtha (C.sub.5-C.sub.8) fraction or a propane/butane (C.sub.3-C.sub.4) fraction is recovered. The straight run naphtha fraction (C.sub.5-C.sub.8) or the propane/butane (C.sub.3-C.sub.4) fraction is passed to a steam cracker for ethylene production. The heavy fraction from the pyrolysis unit can also be passed to an isomerization dewaxing unit to produce a base oil.

Circular economy for plastic waste to polyethylene and lubricating oil via crude and isomerization dewaxing units
11473016 · 2022-10-18 · ·

Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. In one embodiment, the process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit distillation column in a refinery where a straight run naphtha (C.sub.5-C.sub.8) fraction or a propane/butane (C.sub.3-C.sub.4) fraction is recovered. The straight run naphtha fraction (C.sub.5-C.sub.8) or the propane/butane (C.sub.3-C.sub.4) fraction is passed to a steam cracker for ethylene production. The heavy fraction from the pyrolysis unit can also be passed to an isomerization dewaxing unit to produce a base oil.

PROCESS FOR IMPROVING BASE OIL YIELDS

An improved process for making a base oil and for improving base oil yields by combining an atmospheric resid feedstock with a base oil feedstock and forming a base oil product via hydroprocessing. The process generally involves subjecting a base oil feedstream comprising the atmospheric resid to hydrocracking and dewaxing steps, and optionally to hydrofinishing, to produce a light and heavy grade base oil product. A process is also disclosed for making a base oil having a viscosity index of 120 or greater from a base oil feedstock having a viscosity index of about 100 or greater that includes a narrow cut-point range vacuum gas oil. The invention is useful to make Group II and/or Group III/III+ base oils, and, in particular, to increase the yield of a heavy base oil product relative to a light base oil product produced in the process.

BIOFUEL BLENDS WITH IMPROVED OXIDATION STABILITY AND LUBRICITY

A biofuel includes a mixture having a gasoil generated from hydropyrolysis and hydroconversion of a solid biomass containing lignocellulose and an isomerized hydroprocessed ester and fatty acid (HEFA) generated from hydrotreating a renewable resource having fats and oils. The gasoil has a cetane index less than 46 and at least 10 parts per million weight (ppmw) of a heteroatom and a cetane index of the biofuel is greater than 46.

BIOFUEL BLENDS

A biofuel includes a mixture of a gasoil generated from hydropyrolysis and hydroconversion of a solid biomass containing lignocellulose. The gasoil has a cetane index less than 46. The biofuel also includes a hydroprocessed ester fatty acid (HEFA) generated from hydrotreating a renewable resource having fats and oils. A cetane index of the biofuel is greater than 46.

BIOFUEL BLENDS

A biofuel includes a mixture of a gasoil generated from hydropyrolysis and hydroconversion of a solid biomass containing lignocellulose. The gasoil has a cetane index less than 46. The biofuel also includes a hydroprocessed ester fatty acid (HEFA) generated from hydrotreating a renewable resource having fats and oils. A cetane index of the biofuel is greater than 46.

Apparatus and process for heating hydroisomerization feed

The process and apparatus of the disclosure utilize a heater between a hydroprocessing reactor and a hydroisomerization reactor. A hydroprocessing feed exchanger cools hydroprocessed effluent to effect turndown of heated hydroprocessed effluent so as to not feed the hydroprocessed effluent to the hydroisomerization reactor at a higher temperature than necessary.

Integrated Process for the Manufacture of Renewable Diesel
20230159835 · 2023-05-25 ·

Methods and systems are provided for producing renewable diesel. Disclosed herein is an example method of method for integration of product separation in renewable diesel production, including: stripping a hydrotreated effluent stream comprising hydrotreated biofeedstock to remove isomerization contaminants and form at least an isomerization feed stream and a first gas stream; contacting an isomerization effluent with the first gas stream such that the isomerization effluent adsorbs at least C4+ hydrocarbons from the first gas stream; and stripping at least a portion of an isomerization effluent in an integrated stripper while separated from the stripping the hydrocarbon stream by a dividing wall to remove hydrocarbons having 10 carbons or less and form at least a product stream and a second gas stream, wherein the product stream comprises renewable diesel.

INTEGRATED PROCESS FOR THE CONVERSION OF CRUDE TO OLEFINS

A process for producing light olefins comprising thermal cracking. Hydrocracked streams are thermally cracked to produce light olefins. A pyrolysis gas stream is separated into a light pyrolysis gas stream and a heavy pyrolysis gas stream. A light pyrolysis gas stream is separated into a normal paraffins stream and a non-normal paraffins stream. A normal paraffins stream is thermally cracked. The integrated process may be employed to obtain olefin products of high value from a crude stream.

INTEGRATED PROCESS FOR THE CONVERSION OF CRUDE TO OLEFINS

A process for producing light olefins comprising thermal cracking. Hydrocracked streams are thermally cracked to produce light olefins. A pyrolysis gas stream is separated into a light pyrolysis gas stream and a heavy pyrolysis gas stream. A light pyrolysis gas stream is separated into a normal paraffins stream and a non-normal paraffins stream. A normal paraffins stream is thermally cracked. The integrated process may be employed to obtain olefin products of high value from a crude stream.