The present application relates to method for oligomerizing olefin or for producing polyalphaolefin utilizing catalyst mixtures comprising aluminum halides and an organic liquid carrier. A process comprising contacting 1) a catalyst mixture comprising i) an aluminum trihalide and ii) an organic liquid carrier comprising first olefins, wherein the organic liquid carrier first olefins comprise at least 60 mole % 1,2-disubstituted olefins, trisubstituted olefins, or any combination thereof; and 2) a monomer comprising second olefins to form an oligomer product. An oligomer product produced by the process comprising contacting 1) a catalyst mixture comprising i) an aluminum trihalide and ii) an organic liquid carrier comprising first olefins, wherein the organic liquid carrier olefins comprise at least 75 mole % 1,2-disubstituted olefins, trisubstituted olefins, or any combination thereof; and 2) a monomer comprising second olefins to form an oligomer product.

The present application relates to method for oligomerizing olefin or for producing polyalphaolefin utilizing catalyst mixtures comprising aluminum halides and an organic liquid carrier. A process comprising contacting 1) a catalyst mixture comprising i) an aluminum trihalide and ii) an organic liquid carrier comprising first olefins, wherein the organic liquid carrier first olefins comprise at least 60 mole % 1,2-disubstituted olefins, trisubstituted olefins, or any combination thereof; and 2) a monomer comprising second olefins to form an oligomer product. An oligomer product produced by the process comprising contacting 1) a catalyst mixture comprising i) an aluminum trihalide and ii) an organic liquid carrier comprising first olefins, wherein the organic liquid carrier olefins comprise at least 75 mole % 1,2-disubstituted olefins, trisubstituted olefins, or any combination thereof; and 2) a monomer comprising second olefins to form an oligomer product.

This disclosure relates to a liquid syndiotactic polyalphaolefin, sPAO, comprising one or more C.sub.4 to C.sub.24 monomers, said sPAO having: a) an rr triad content of 5 to 50% as measured by .sup.13C NMR; b) an mr triad content of 25 to 60% as measured by .sup.13C NMR, where the mr to mm triad ratio is at least 1.0; c) a pour point of Z C. or less, where Z=0.0648X51.2, where X=kinematic viscosity at 100 C. as reported in centistokes (cSt); d) a kinematic viscosity at 100 C. of 100 cSt or more (alternatively 200 cSt or more); e) a ratio of mr triads to rr triad (as determined by .sup.13C NMR) of less than 9; f) a ratio of vinylidene to 1,2-disubstituted olefins (as determined by .sup.1H NMR) of less than 8; g) a viscosity index of 120 or more; and h) an Mn of 40,000 or less. This disclosure further relates to processes to make and use sPAOs, including those having any combination of characterics a) to h).

This disclosure relates to a liquid syndiotactic polyalphaolefin, sPAO, comprising one or more C.sub.4 to C.sub.24 monomers, said sPAO having: a) an rr triad content of 5 to 50% as measured by .sup.13C NMR; b) an mr triad content of 25 to 60% as measured by .sup.13C NMR, where the mr to mm triad ratio is at least 1.0; c) a pour point of Z C. or less, where Z=0.0648X51.2, where X=kinematic viscosity at 100 C. as reported in centistokes (cSt); d) a kinematic viscosity at 100 C. of 100 cSt or more (alternatively 200 cSt or more); e) a ratio of mr triads to rr triad (as determined by .sup.13C NMR) of less than 9; f) a ratio of vinylidene to 1,2-disubstituted olefins (as determined by .sup.1H NMR) of less than 8; g) a viscosity index of 120 or more; and h) an Mn of 40,000 or less. This disclosure further relates to processes to make and use sPAOs, including those having any combination of characterics a) to h).

Disclosed are processes for forming an oligomer product by contacting a feedstock olefin containing trisubstituted olefins with a solid acid catalyst. The oligomer product can be formed at an oligomerization temperature in a range from 20 C. to 40 C. Polyalphaolefins produced from the oligomer product can have reduced viscosities at low temperatures.

Disclosed are processes for forming an oligomer product by contacting a feedstock olefin containing trisubstituted olefins with a solid acid catalyst. The oligomer product can be formed at an oligomerization temperature in a range from 20 C. to 40 C. Polyalphaolefins produced from the oligomer product can have reduced viscosities at low temperatures.

A process for converting light paraffins (especially C.sub.3-C.sub.5) to middle distillate and higher boiling range liquid hydrocarbons by (1) oxygen or air oxidation of iso-paraffins to alkyl hydroperoxides; (2) conversion of alkyl hydroperoxides to dialkyl peroxides; (3) radical coupling of paraffins using the dialkyl peroxides as radical initiators forming heavier hydrocarbon products; and (4) fractionation of the heavy hydrocarbon products. The net reaction is catalytically converting light paraffins to heavier hydrocarbons using oxygen or air to effect the conversion.

A process for converting light paraffins (especially C.sub.3-C.sub.5) to middle distillate and higher boiling range liquid hydrocarbons by (1) oxygen or air oxidation of iso-paraffins to alkyl hydroperoxides; (2) conversion of alkyl hydroperoxides to dialkyl peroxides; (3) radical coupling of paraffins using the dialkyl peroxides as radical initiators forming heavier hydrocarbon products; and (4) fractionation of the heavy hydrocarbon products. The net reaction is catalytically converting light paraffins to heavier hydrocarbons using oxygen or air to effect the conversion.

This invention discloses an improved process which employs mixed alpha-olefins as feed over activated metallocene catalyst systems to provide essentially random liquid polymers particularly useful in lubricant components or as functional fluids

Methods are provided for producing Group III base stocks having high viscosity and also having one or more properties indicative of a high quality base stock. The resulting Group III base stocks can have a viscosity at 100 C. and/or a viscosity at 40 C. that is greater than the corresponding viscosity for a conventional Group III base stock. Additionally, the resulting Group III base stocks can have one or more properties that are indicative of a high quality base stock.