C10G51/06

METHOD TO PRODUCE LIGHT OLEFINS FROM CRUDE OIL

Embodiments of the disclosure provide a system and method for producing light olefins from a crude oil. A crude oil feed is introduced to a crude distillation unit to produce a distillate fraction and a residue fraction. The distillate fraction is introduced to a non-catalytic steam cracker to produce a light olefin fraction and a pyrolysis oil fraction. The residue fraction is introduced to a supercritical water reactor to produce an effluent stream. The effluent stream is introduced to a flash separator to produce a gas phase fraction and a liquid phase fraction. The gas phase fraction is introduced to a catalytic steam cracker to produce a light olefin fraction and a pyrolysis oil fraction. Optionally, the residue fraction is introduced to a vacuum distillation unit to produce a light vacuum gasoil fraction, a heavy vacuum gasoil fraction, and a vacuum residue fraction. The vacuum residue fraction is introduced to a solvent deasphalting unit to produce a deasphalted oil and a pitch fraction. The deasphalted oil fraction, optionally combined with the heavy vacuum gasoil fraction, can be introduced to the supercritical water reactor in lieu of the residue fraction.

Online coke removal in a heater pass

This disclosure provides methods for decoking tubular passes of crude oil heaters and processed hydrocarbon heaters. The method permits continued operation of an associated crude oil processing unit or a processed hydrocarbon processing unit receiving crude oil or processed hydrocarbons from the heater during the decoking operation. The decoking operation utilizes dry steam to remove coke from passes within the crude oil heater or processed hydrocarbon heater and dry steam to maintain balanced operation of the crude oil processing unit or processed hydrocarbon processing unit.

Online coke removal in a heater pass

This disclosure provides methods for decoking tubular passes of crude oil heaters and processed hydrocarbon heaters. The method permits continued operation of an associated crude oil processing unit or a processed hydrocarbon processing unit receiving crude oil or processed hydrocarbons from the heater during the decoking operation. The decoking operation utilizes dry steam to remove coke from passes within the crude oil heater or processed hydrocarbon heater and dry steam to maintain balanced operation of the crude oil processing unit or processed hydrocarbon processing unit.

Fluid catalytic cracking process

A fluid catalytic cracking unit (FCCU) for production of petrochemical feedstock fractions comprises a first reactor to receive a stream of desalinated crude oil and produce a first cracked product stream; a second reactor to receive a stream of light cracked naphtha (LCN) and produce a second cracked product stream; a third reactor to receive a bottom stream and produce a third cracked product stream; and a fractionating column and gas concentration section to separate components of the first cracked product stream, the second cracked product stream, and the third cracked product stream to produce, upon further fractionation, Ethylene, Propylene, Butylene, Benzene, Toluene and Xylene as the petrochemical feedstock fractions.

HIGH-SEVERITY FLUIDIZED CATALYTIC CRACKING SYSTEMS AND PROCESSES HAVING PARTIAL CATALYST RECYCLE

Methods for operating a system having two downflow high-severity FCC units for producing products from a hydrocarbon feed includes introducing the hydrocarbon feed to a feed separator and separating it into a lesser boiling point fraction and a greater boiling point fraction. The greater boiling point fraction is passed to the first FCC unit and cracked in the presence of a first catalyst at 500 C. to 700 C. to produce a first cracking reaction product and a spent first catalyst. The lesser boiling point fraction is passed to the second FCC unit and cracked in the presence of a second catalyst at 500 C. to 700 C. to produce a second cracking reaction product and a spent second catalyst. At least a portion of the spent first catalyst or the spent second catalyst is passed back to the first FCC unit, the second FCC unit or both.

HIGH-SEVERITY FLUIDIZED CATALYTIC CRACKING SYSTEMS AND PROCESSES HAVING PARTIAL CATALYST RECYCLE

Methods for operating a system having two downflow high-severity FCC units for producing products from a hydrocarbon feed includes introducing the hydrocarbon feed to a feed separator and separating it into a lesser boiling point fraction and a greater boiling point fraction. The greater boiling point fraction is passed to the first FCC unit and cracked in the presence of a first catalyst at 500 C. to 700 C. to produce a first cracking reaction product and a spent first catalyst. The lesser boiling point fraction is passed to the second FCC unit and cracked in the presence of a second catalyst at 500 C. to 700 C. to produce a second cracking reaction product and a spent second catalyst. At least a portion of the spent first catalyst or the spent second catalyst is passed back to the first FCC unit, the second FCC unit or both.

HIGH SEVERITY FLUIDIZED CATALYTIC CRACKING SYSTEMS AND PROCESSES FOR PRODUCING OLEFINS FROM PETROLEUM FEEDS

Systems and processes are disclosed for producing petrochemical products, such as ethylene, propene and other olefins from crude oil in high severity fluid catalytic cracking (HSFCC) units. Processes include separating a crude oil into a light fraction and a heavy fraction, cracking the light fraction and heavy fraction in separation cracking reaction zones, and regenerating the cracking catalysts in a two-zone regenerator having a first regeneration zone for the first catalyst (heavy fraction) and a second regeneration zone for the second catalyst (light fraction) separate from the first regeneration zone. Flue gas from the first catalyst regeneration zone is passed to the second regeneration zone to provide additional heat to raise the temperature of the second catalyst of the light fraction side. The disclosed systems and processes enable different catalysts and operating conditions to be utilized for the light fraction and the heavy fraction of a crude oil feed.

HIGH SEVERITY FLUIDIZED CATALYTIC CRACKING SYSTEMS AND PROCESSES FOR PRODUCING OLEFINS FROM PETROLEUM FEEDS

Systems and processes are disclosed for producing petrochemical products, such as ethylene, propene and other olefins from crude oil in high severity fluid catalytic cracking (HSFCC) units. Processes include separating a crude oil into a light fraction and a heavy fraction, cracking the light fraction and heavy fraction in separation cracking reaction zones, and regenerating the cracking catalysts in a two-zone regenerator having a first regeneration zone for the first catalyst (heavy fraction) and a second regeneration zone for the second catalyst (light fraction) separate from the first regeneration zone. Flue gas from the first catalyst regeneration zone is passed to the second regeneration zone to provide additional heat to raise the temperature of the second catalyst of the light fraction side. The disclosed systems and processes enable different catalysts and operating conditions to be utilized for the light fraction and the heavy fraction of a crude oil feed.

Maximizing high-value chemicals from mixed plastic using different steam-cracker configurations

A process for producing olefins and aromatics comprising converting plastics to a hydrocarbon product comprising a gas phase and a liquid phase in a pyrolysis unit; separating the hydrocarbon product into a hydrocarbon gas stream comprising the gas phase and a hydrocarbon liquid stream comprising the liquid phase; feeding the hydrocarbon gas stream to a gas steam cracker to produce a gas steam cracker product comprising olefins, wherein an olefins amount in the gas steam cracker product is greater than in the hydrocarbon gas stream; separating the hydrocarbon liquid stream into a first fraction (b.p.<300 C.) and a second fraction (b.p>300 C.); feeding the first fraction to a liquid steam cracker to produce a liquid steam cracker product comprising olefins and aromatics, wherein an olefins amount in the liquid steam cracker product is greater than in the first fraction; and recycling the second fraction to the pyrolysis unit.

Maximizing high-value chemicals from mixed plastic using different steam-cracker configurations

A process for producing olefins and aromatics comprising converting plastics to a hydrocarbon product comprising a gas phase and a liquid phase in a pyrolysis unit; separating the hydrocarbon product into a hydrocarbon gas stream comprising the gas phase and a hydrocarbon liquid stream comprising the liquid phase; feeding the hydrocarbon gas stream to a gas steam cracker to produce a gas steam cracker product comprising olefins, wherein an olefins amount in the gas steam cracker product is greater than in the hydrocarbon gas stream; separating the hydrocarbon liquid stream into a first fraction (b.p.<300 C.) and a second fraction (b.p>300 C.); feeding the first fraction to a liquid steam cracker to produce a liquid steam cracker product comprising olefins and aromatics, wherein an olefins amount in the liquid steam cracker product is greater than in the first fraction; and recycling the second fraction to the pyrolysis unit.