C10G59/06

Optimized reactor configuration for optimal performance of the aromax catalyst for aromatics synthesis

A naphtha reforming reactor system comprising a first reactor comprising a first inlet and a first outlet, wherein the first reactor is configured to operate as an adiabatic reactor, and wherein the first reactor comprises a first naphtha reforming catalyst; and a second reactor comprising a second inlet and a second outlet, wherein the second inlet is in fluid communication with the first outlet of the first reactor, wherein the second reactor is configured to operate as an isothermal reactor, and wherein the second reactor comprises a plurality of tubes disposed within a reactor furnace, a heat source configured to heat the interior of the reactor furnace; and a second naphtha reforming catalyst disposed within the plurality of tubes, wherein the first naphtha reforming catalyst and the second naphtha reforming catalyst are the same or different.

Reforming process
11939537 · 2024-03-26 · ·

An improved reforming process for producing aromatic hydrocarbons is disclosed. The process includes two reformers arranged in parallel flow configuration, with the first reformer being a conventional reformer comprising a catalyst selective for reforming C.sub.8+ hydrocarbons to a reformate and the second reformer comprising a catalyst selective for reforming C.sub.7? hydrocarbons to a reformate. In certain embodiments, the first reformer catalyst comprises a conventional alumina catalyst and the second reformer catalyst comprises a ZSM-5 catalyst.

Reforming process
11939537 · 2024-03-26 · ·

An improved reforming process for producing aromatic hydrocarbons is disclosed. The process includes two reformers arranged in parallel flow configuration, with the first reformer being a conventional reformer comprising a catalyst selective for reforming C.sub.8+ hydrocarbons to a reformate and the second reformer comprising a catalyst selective for reforming C.sub.7? hydrocarbons to a reformate. In certain embodiments, the first reformer catalyst comprises a conventional alumina catalyst and the second reformer catalyst comprises a ZSM-5 catalyst.

Cyclization and fluid catalytic cracking systems and methods for upgrading naphtha
11965136 · 2024-04-23 · ·

A process for upgrading a naphtha feed includes separating the naphtha feed into at least a light naphtha fraction, contacting the light naphtha fraction with hydrogen in the presence of at least one cyclization catalyst, and contacting the cyclization effluent with at least one cracking catalyst. Contacting the light naphtha fraction with hydrogen in the presence of at least one cyclization catalyst may produce a cyclization effluent comprising a greater concentration of naphthenes compared to the light naphtha fraction. Contacting the cyclization effluent with at least one cracking catalyst under conditions sufficient to crack at least a portion of the cyclization effluent may produce a fluid catalytic cracking effluent comprising light olefins, gasoline blending components, or both. A system for upgrading a naphtha feed includes a naphtha separation unit, a cyclization unit disposed downstream of the naphtha separation unit, and a fluid catalytic cracking unit disposed downstream of the cyclization unit.

Processes for selective naphtha reforming

Process for reforming a hydrocarbon feedstock comprising paraffins and naphthenes. A hydrocarbon feedstock is separated to produce a first fraction enriched in naphthenes and a second fraction that is enriched in paraffins. The first fraction is contacted with a first reforming catalyst in a first reactor that is maintained at a temperature and pressure that facilitates conversion of naphthenes to aromatics. The second fraction is contacted with a second reforming catalyst in a second reactor at a temperature and pressure that converts at least 50 wt. % of paraffins in the second fraction to olefins. The process produces a liquid hydrocarbon reformate product suitable for use as a blend component of a liquid transportation fuel.

Processes for selective naphtha reforming

Process for reforming a hydrocarbon feedstock comprising paraffins and naphthenes. A hydrocarbon feedstock is separated to produce a first fraction enriched in naphthenes and a second fraction that is enriched in paraffins. The first fraction is contacted with a first reforming catalyst in a first reactor that is maintained at a temperature and pressure that facilitates conversion of naphthenes to aromatics. The second fraction is contacted with a second reforming catalyst in a second reactor at a temperature and pressure that converts at least 50 wt. % of paraffins in the second fraction to olefins. The process produces a liquid hydrocarbon reformate product suitable for use as a blend component of a liquid transportation fuel.

CATALYTIC ACTIVATION OF ISOPENTANE-ENRICHED MIXTURES

The present disclosure relates generally to processes and systems for producing liquid transportation fuels by converting a feed stream that comprises both isopentane and n-pentane, and optionally, some C6+ hydrocarbons. Isopentane and smaller hydrocarbons are separated to form a first fraction while n-pentane and larger components of the feed stock form a second fraction. Each fraction is then catalytically-activated in a separate reaction zone with a separate catalyst, where the conditions maintained in each zone maximize the conversion of each fraction to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. In certain embodiments, the first fraction is activated at a lower temperature than the second fraction. The process provides increased yields of upgraded hydrocarbon products that possess the characteristics of a liquid transportation fuel or a blend component thereof.

CATALYTIC ACTIVATION OF ISOPENTANE-ENRICHED MIXTURES

The present disclosure relates generally to processes and systems for producing liquid transportation fuels by converting a feed stream that comprises both isopentane and n-pentane, and optionally, some C6+ hydrocarbons. Isopentane and smaller hydrocarbons are separated to form a first fraction while n-pentane and larger components of the feed stock form a second fraction. Each fraction is then catalytically-activated in a separate reaction zone with a separate catalyst, where the conditions maintained in each zone maximize the conversion of each fraction to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. In certain embodiments, the first fraction is activated at a lower temperature than the second fraction. The process provides increased yields of upgraded hydrocarbon products that possess the characteristics of a liquid transportation fuel or a blend component thereof.

CATALYTIC ACTIVATION AND OLIGOMERIZATION OF ISOPENTANE-ENRICHED MIXTURES

The present disclosure relates generally to processes and systems for producing liquid transportation fuels by converting a feed stream that comprises both isopentane and n-pentane, and optionally, some C6+ hydrocarbons. Isopentane and smaller hydrocarbons are separated to form a first fraction while n-pentane and larger components of the feed stock form a second fraction. Each fraction is then catalytically-activated in a separate reaction zone with a separate catalyst, where the conditions maintained in each zone maximize the conversion of each fraction to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. In certain embodiments, the first fraction is activated at a lower temperature than the second fraction. Certain embodiments additionally comprise mixing at least a portion of the two effluents and contacting with an oligomerization catalyst to provide enhanced yields of aliphatic hydrocarbons that possess the characteristics of a blend component of a liquid transportation fuel or other value-added chemical products.

CATALYTIC ACTIVATION AND OLIGOMERIZATION OF ISOPENTANE-ENRICHED MIXTURES

The present disclosure relates generally to processes and systems for producing liquid transportation fuels by converting a feed stream that comprises both isopentane and n-pentane, and optionally, some C6+ hydrocarbons. Isopentane and smaller hydrocarbons are separated to form a first fraction while n-pentane and larger components of the feed stock form a second fraction. Each fraction is then catalytically-activated in a separate reaction zone with a separate catalyst, where the conditions maintained in each zone maximize the conversion of each fraction to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. In certain embodiments, the first fraction is activated at a lower temperature than the second fraction. Certain embodiments additionally comprise mixing at least a portion of the two effluents and contacting with an oligomerization catalyst to provide enhanced yields of aliphatic hydrocarbons that possess the characteristics of a blend component of a liquid transportation fuel or other value-added chemical products.