C10G65/14

PROCESSES FOR SELECTIVE NAPHTHA REFORMING

Processes for reforming a hydrocarbon feedstock by selectively reforming different sub-components or fractions of the feedstock using at least two compositionally-distinct reforming catalysts. Advantages may include a decreased rate of reforming catalyst deactivation and an increased yield of a liquid hydrocarbon reformate product that is characterized by at least one of an increased octane rating and a decreased vapor pressure (relative to conventional one-step reforming processes and systems).

Production of oilfield hydrocarbons

A process (20) to produce olefinic products suitable for use as or conversion to oilfield hydrocarbons includes separating (42) an olefins-containing Fischer-Tropsch condensate (64) into a light fraction (68), an intermediate fraction (82) and a heavy fraction (94), oligomerizing (44) at least a portion of the light fraction (68) to produce a first olefinic product (72) which includes branched internal olefins, and carrying out either one or both of the steps of (i) dehydrogenating (50) at least a portion of the intermediate fraction (82) to produce an intermediate product (84) which includes internal olefins and alpha-olefins, and synthesizing (52) higher olefins from the intermediate product which includes internal olefins and alpha-olefins to produce a second olefinic product (86), and (ii) dimerizing (52) at least a portion of the intermediate fraction to produce a second olefinic product (86). At least a portion of the heavy fraction (94) is dehydrogenated (58) to produce a third olefinic product (96) which includes internal olefins. Also provided is a process (30) to produce paraffinic products suitable for use as or conversion to oilfield hydrocarbons which includes separating (110) a Fischer-Tropsch wax (124) into at least a lighter fraction (126, 128) and a heavier fraction (130), hydrocracking (120) the heavier fraction (130) to provide a cracked intermediate (144), and separating (122) the cracked intermediate (144) into at least a naphtha fraction (148), a heavier than naphtha paraffinic distillate fraction (150) suitable for use as or conversion to oilfield hydrocarbons, and a bottoms fraction (152) which is heavier than the paraffinic distillate fraction (150).

Production of oilfield hydrocarbons

A process (20) to produce olefinic products suitable for use as or conversion to oilfield hydrocarbons includes separating (42) an olefins-containing Fischer-Tropsch condensate (64) into a light fraction (68), an intermediate fraction (82) and a heavy fraction (94), oligomerizing (44) at least a portion of the light fraction (68) to produce a first olefinic product (72) which includes branched internal olefins, and carrying out either one or both of the steps of (i) dehydrogenating (50) at least a portion of the intermediate fraction (82) to produce an intermediate product (84) which includes internal olefins and alpha-olefins, and synthesizing (52) higher olefins from the intermediate product which includes internal olefins and alpha-olefins to produce a second olefinic product (86), and (ii) dimerizing (52) at least a portion of the intermediate fraction to produce a second olefinic product (86). At least a portion of the heavy fraction (94) is dehydrogenated (58) to produce a third olefinic product (96) which includes internal olefins. Also provided is a process (30) to produce paraffinic products suitable for use as or conversion to oilfield hydrocarbons which includes separating (110) a Fischer-Tropsch wax (124) into at least a lighter fraction (126, 128) and a heavier fraction (130), hydrocracking (120) the heavier fraction (130) to provide a cracked intermediate (144), and separating (122) the cracked intermediate (144) into at least a naphtha fraction (148), a heavier than naphtha paraffinic distillate fraction (150) suitable for use as or conversion to oilfield hydrocarbons, and a bottoms fraction (152) which is heavier than the paraffinic distillate fraction (150).

Production of Sustainable Aviation Fuel from CO2 and Low-Carbon Hydrogen

A process for the production of sustainable aviation fuel (SAF) with low carbon intensity. The jet fuel is produced from the reaction of hydrogen from the electrolysis of water with captured carbon dioxide. The hydrogen and carbon dioxide are reacted to product a stream comprising carbon monoxide. Hydrogen and carbon monoxide are reacted to produce n-alkanes. Alkanes are hydroisomerized to produce sustainable aviation fuel with low carbon intensity.

INSTALLATION AND INTEGRATED HYDROTREATMENT AND HYDROCONVERSION PROCESS WITH COMMON FRACTIONATION SECTION

An installation for the hydrotreatment and hydroconversion of hydrocarbon-containing feedstocks, with a common fractionation section, for the production of at least one of the following products: naphtha (light and/or heavy), diesel, kerosene, distillate and residue: comprising at least: at least one hydroconversion reactor, a hot high-pressure separator drum B-1, a cold high-pressure separator drum B-2, at least one hydrotreatment reactor, a cold high-pressure separator drum B-20, a common fractionation section separating a top fraction, an intermediate fraction and a heavy fraction,

An integrated hydroconversion and hydrotreatment process implementing said installation.

PROCESS FOR IMPROVING GASOLINE QUALITY FROM CRACKED NAPHTHA
20180171244 · 2018-06-21 ·

A method is provided for producing gasoline that includes separating a cracked naphtha feed into a light catalytic naphtha fraction and a heavy naphtha fraction; and exposing the light catalytic naphtha fraction to a catalyst under effective conversion conditions to reduce sulfur content of the light catalytic naphtha fraction while also reducing a Reid vapor pressure and an olefin content of the light catalytic naphtha fraction, wherein the effective conversion conditions comprise a pressure of less than about 500 psig and a temperature of at least about 550 F. (288 C.).

PROCESS FOR IMPROVING GASOLINE QUALITY FROM CRACKED NAPHTHA
20180171244 · 2018-06-21 ·

A method is provided for producing gasoline that includes separating a cracked naphtha feed into a light catalytic naphtha fraction and a heavy naphtha fraction; and exposing the light catalytic naphtha fraction to a catalyst under effective conversion conditions to reduce sulfur content of the light catalytic naphtha fraction while also reducing a Reid vapor pressure and an olefin content of the light catalytic naphtha fraction, wherein the effective conversion conditions comprise a pressure of less than about 500 psig and a temperature of at least about 550 F. (288 C.).

Hydroconversion process to upgrade the transport properties of heavy and extra-heavy crude oils at low severity conditions using dispersed-phase catalyst

The present invention relates to a catalytic hydroconversion process in dispersed phase of extra-heavy and heavy crude oils for upgrading their transport properties, that operates at low severity conditions, in such a way that the obtained product can be transported by conventional pumping to the distribution and refining centers. The main technical contributions of the hydroconversion process in dispersed phase of this invention to upgrade the transport properties of heavy and extra-heavy crudes are: Compact size and can be localized next to the production facilities on ground or offshore Use of operating conditions at low severity Reduction of the viscosity and increase of the API gravity at values that allow the transportation by pipeline of heavy or extra-heavy crude Upgrading of the crude oil properties in a permanent way Hydrocarbon and gases from production centers are used as supplies Operation in dispersed phase avoiding plugging problems Use of low-cost disposable catalysts at low concentrations.

Hydroconversion process to upgrade the transport properties of heavy and extra-heavy crude oils at low severity conditions using dispersed-phase catalyst

The present invention relates to a catalytic hydroconversion process in dispersed phase of extra-heavy and heavy crude oils for upgrading their transport properties, that operates at low severity conditions, in such a way that the obtained product can be transported by conventional pumping to the distribution and refining centers. The main technical contributions of the hydroconversion process in dispersed phase of this invention to upgrade the transport properties of heavy and extra-heavy crudes are: Compact size and can be localized next to the production facilities on ground or offshore Use of operating conditions at low severity Reduction of the viscosity and increase of the API gravity at values that allow the transportation by pipeline of heavy or extra-heavy crude Upgrading of the crude oil properties in a permanent way Hydrocarbon and gases from production centers are used as supplies Operation in dispersed phase avoiding plugging problems Use of low-cost disposable catalysts at low concentrations.

Processes for prolonging catalyst activity in a hydroprocessing unit
12139675 · 2024-11-12 · ·

A process for prolonging catalyst activity may comprise contacting heavy hydrocarbon feedstock, wherein the heavy hydrocarbon feedstock is essentially free of residue, and hydrogen with catalyst in a hydroprocessing unit operating at a pressure of greater than or equal to 100 bars. The process may further comprise performing hydrocracking, hydrodesulfurization, and hydrodenitrogenation in a single stage of the hydroprocessing unit to create a hydroprocessed effluent. The process may further comprise regenerating spent catalyst in a catalyst regeneration unit. Additionally, the process may further comprise passing regenerated catalyst back to the hydroprocessing unit without rejuvenating the spent catalyst.