C10G67/16

Process and plant for converting oxygenates to gasoline with improved gasoline yield and octane number as well as reduced durene levels

Process for converting an oxygenate feed stream, the process comprising the steps of: conducting the oxygenate feed stream to an oxygenate-to-gasoline reactor, suitably a methanol-to-gasoline reactor (MTG reactor) under the presence of a catalyst active for converting oxygenates in the oxygenate feed stream into a raw gasoline stream comprising C3-C4 paraffins and C5+ hydrocarbons; and adding an aromatic stream to the MTG reactor.

CATALYTIC GASOLINE DESULFURIZATION METHOD HAVING ALSO AN OLEFIN SELECTIVE REMOVAL FUNCTION
20190241821 · 2019-08-08 ·

The present invention provides a catalytic gasoline desulfurization method having also an olefin selective removal function, which comprises: when a catalytic gasoline is pre-hydrotreated, cutting into a light fraction, a middle fraction and a heavy fraction; performing liquid-liquid extraction desulfurization treatment on the middle fraction to produce a sulfur-poor oil and a rich solvent containing sulfur-rich oil; the light fraction back-extracting the rich solvent, using C5 olefin therein to replace a macromolecular acyclic olefin in the sulfur-rich oil, so as to gather together C5 iso-olefins, cycloolefins, aromatic hydrocarbons and sulfides in the sulfur-rich oil; performing hydrogenation, olefin-reduction and desulfurization treatment on the heavy fraction together with the sulfur-rich oil removed from the back-extracted rich solvent to saturate the olefin therein; and finally, preparing together with the sulfur-poor oil to produce a full range gasoline. The sulfur-content of the catalytic gasoline produced by the method of the present invention can be reduced to 10 ppm or less, the olefin content of the catalytic gasoline can be reduced to 22%, the olefin is saturated by up to 8 percentage, and the RON loss of the full range gasoline is 1.5 or less, so that while reducing the olefin content of the catalytic gasoline, it ensures the less octane number loss, thereby satisfying the olefin-reduction requirements upgraded in the gasoline National VI Standard for ethanol-gasoline supply area enterprises.

CATALYTIC GASOLINE DESULFURIZATION METHOD HAVING ALSO AN OLEFIN SELECTIVE REMOVAL FUNCTION
20190241821 · 2019-08-08 ·

The present invention provides a catalytic gasoline desulfurization method having also an olefin selective removal function, which comprises: when a catalytic gasoline is pre-hydrotreated, cutting into a light fraction, a middle fraction and a heavy fraction; performing liquid-liquid extraction desulfurization treatment on the middle fraction to produce a sulfur-poor oil and a rich solvent containing sulfur-rich oil; the light fraction back-extracting the rich solvent, using C5 olefin therein to replace a macromolecular acyclic olefin in the sulfur-rich oil, so as to gather together C5 iso-olefins, cycloolefins, aromatic hydrocarbons and sulfides in the sulfur-rich oil; performing hydrogenation, olefin-reduction and desulfurization treatment on the heavy fraction together with the sulfur-rich oil removed from the back-extracted rich solvent to saturate the olefin therein; and finally, preparing together with the sulfur-poor oil to produce a full range gasoline. The sulfur-content of the catalytic gasoline produced by the method of the present invention can be reduced to 10 ppm or less, the olefin content of the catalytic gasoline can be reduced to 22%, the olefin is saturated by up to 8 percentage, and the RON loss of the full range gasoline is 1.5 or less, so that while reducing the olefin content of the catalytic gasoline, it ensures the less octane number loss, thereby satisfying the olefin-reduction requirements upgraded in the gasoline National VI Standard for ethanol-gasoline supply area enterprises.

Integrated isomerization and hydrotreating apparatus
10351785 · 2019-07-16 · ·

Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by with an apparatus arranged for flashing the feed at a target cut point temperature to obtain two fractions. A low boiling temperature fraction contains refractory, sterically hindered sulfur-containing compounds, which have a boiling point at or above the target cut point temperature. A high boiling temperature fraction, having a boiling point below the target cut point temperature, is substantially free of refractory sulfur-containing compounds. The high boiling temperature fraction is contacted with isomerization catalyst, and the isomerized effluent and the low boiling temperature fraction are combined and contacted with a hydrotreating catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level.

Integrated isomerization and hydrotreating apparatus
10351785 · 2019-07-16 · ·

Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by with an apparatus arranged for flashing the feed at a target cut point temperature to obtain two fractions. A low boiling temperature fraction contains refractory, sterically hindered sulfur-containing compounds, which have a boiling point at or above the target cut point temperature. A high boiling temperature fraction, having a boiling point below the target cut point temperature, is substantially free of refractory sulfur-containing compounds. The high boiling temperature fraction is contacted with isomerization catalyst, and the isomerized effluent and the low boiling temperature fraction are combined and contacted with a hydrotreating catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level.

Systems for producing anode grade coke from high sulfur crude oils
10351778 · 2019-07-16 · ·

Methods and systems for producing anode grade coke are disclosed, which allow anode grade coke to be produced from crude oil having a high sulfur content. A fraction of the resid is hydrotreated while another fraction of the resid is treated in a solvent deasphalting unit. A synthetic stream is provided by blending hydrotreated resid with one or more streams from the deasphalting unit. The synthetic stream is fed to an anodic coker unit.

METHOD FOR PROCESSING VISCOUS OIL OR OIL PRODUCTS AND A PLANT FOR THEIR REFINING.
20190177625 · 2019-06-13 ·

The invention describes and claims a processing plant and a method for processing viscous oil and oil products. The processing is effectuated with a plant, which comprises a plurality of reaction modules, a plurality of rectifying chambers and pipelines. Each reaction module and each rectifying chamber comprises a tank, a pump, a hydrocavitation generator. Each reaction module comprises a plurality of intermediate reaction stages. Each rectifying chamber comprises a plurality of intermediate rectifying stages. The reaction module and the rectifying chamber are interconnected. Intermediate reaction stages are connected by pipelines, with the last one connected to a rectifying chamber.

METHOD FOR PROCESSING VISCOUS OIL OR OIL PRODUCTS AND A PLANT FOR THEIR REFINING.
20190177625 · 2019-06-13 ·

The invention describes and claims a processing plant and a method for processing viscous oil and oil products. The processing is effectuated with a plant, which comprises a plurality of reaction modules, a plurality of rectifying chambers and pipelines. Each reaction module and each rectifying chamber comprises a tank, a pump, a hydrocavitation generator. Each reaction module comprises a plurality of intermediate reaction stages. Each rectifying chamber comprises a plurality of intermediate rectifying stages. The reaction module and the rectifying chamber are interconnected. Intermediate reaction stages are connected by pipelines, with the last one connected to a rectifying chamber.

Process for the refining of crude oil
10316258 · 2019-06-11 · ·

A process for the refining of crude oil, comprising a separation unit of the crude oil, consisting of at least one atmospheric distillation unit for separating the various fractions, a unit for the conversion of the heavy fractions obtained, a unit for improving the quality of some of the fractions obtained by actions on the chemical composition of their constituents, and units for the removal of undesired components, characterized in that the heaviest fraction, the atmospheric distillation residue, is sent to the conversion unit comprising a hydroconversion reactor in slurry phase or of the ebullated bed type, into which hydrogen or a mixture of hydrogen and S is introduced in the presence of a suitable nanodispersed hydrogenation catalyst.

Process for the refining of crude oil
10316258 · 2019-06-11 · ·

A process for the refining of crude oil, comprising a separation unit of the crude oil, consisting of at least one atmospheric distillation unit for separating the various fractions, a unit for the conversion of the heavy fractions obtained, a unit for improving the quality of some of the fractions obtained by actions on the chemical composition of their constituents, and units for the removal of undesired components, characterized in that the heaviest fraction, the atmospheric distillation residue, is sent to the conversion unit comprising a hydroconversion reactor in slurry phase or of the ebullated bed type, into which hydrogen or a mixture of hydrogen and S is introduced in the presence of a suitable nanodispersed hydrogenation catalyst.