A system that includes a feedstock of a non-petroleum or renewable feedstock containing oxygen and contaminants of one or more of metals, gums, and resins that is introduced into the reactor at a flow velocity of from 20 ft/sec to 100 ft/sec. The feedstock is heated within the reactor to a temperature of from 700° F. to 1100° F. to remove and/or reduce the content of one or more of gums and resins in the fats and/or oils of the feedstock. The system further includes a reactor product that is formed in the reactor from the feedstock that has the one or more of gums and resins in the fats and/or oils of the feedstock removed and/or reduced and a heat exchanger to cool the reactor product. A separator unit separates and removes non-condensable gases, metals and water from the cooled reactor product. A final product of the system is separated from the non-condensable gases, metals and water from the cooled reactor product. The final product has an oxygen content that is 60% or less of that of the feedstock, and wherein the final product comprises 25 wt % or less of any triglycerides, monoglycerides, diglycerides, free fatty acids, phosphatides, sterols, tocopherols, tocotrienols, and fatty alcohols, from 5 wt % to 30 wt % naphtha, and 50 wt % or more diesel.

The present disclosure relates to methods for preparing aviation fuel component from a feedstock containing fossil hydrotreating feed and a second feed containing esters of fatty acids and rosins, free fatty acids and resin acids. The method includes subjecting the feedstock to hydrotreatment reaction conditions to produce a hydrotreated stream, separating the hydrotreated stream to three fractions from which at least part the highest boiling fraction is subjected to hydrocracking reaction to produce a hydrocracked stream. At least part of the hydrocracked stream is admixed with at least part of the hydrotreated stream, and their admixture is processed further until desired conversion of the feedstock to the aviation fuel component is obtained.

A hydrofinishing catalyst according to the present invention includes an amorphous silica-alumina support; and a hydrogenated active metal supported on the support, and has an Al composition having a total mass (wt %) of Al and Si as a denominator and a mass (wt %) of Al as a numerator with respect to a reference line, which is a straight line passing through the center of a cross-section of the support, locations evenly spaced apart along the reference line are sequentially numbered, where composition uniformity, which is defined as UN by the Al composition at the i-th location and an average Al composition at the cross-section of the support passing through the center of the support, is 3.0 or less.

A hydrofinishing catalyst according to the present invention includes an amorphous silica-alumina support; and a hydrogenated active metal supported on the support, and has an Al composition having a total mass (wt %) of Al and Si as a denominator and a mass (wt %) of Al as a numerator with respect to a reference line, which is a straight line passing through the center of a cross-section of the support, locations evenly spaced apart along the reference line are sequentially numbered, where composition uniformity, which is defined as UN by the Al composition at the i-th location and an average Al composition at the cross-section of the support passing through the center of the support, is 3.0 or less.

A base stock having at least 90 wt. % saturates, an amount and distribution of aromatics, as determined by ultra violet (UV) spectroscopy, including an absorptivity between 280 and 320 nm of less than 0.015 l/gm-cm, a viscosity index (VI) from 80 to 120, and having a cycloparaffin performance ratio greater than 1.05 and a kinematic viscosity at 100° C. between 4 and 6 cSt. A base stock having at least 90 wt. % saturates, an amount and distribution of aromatics, as determined by UV spectroscopy, including an absorptivity between 280 and 320 nm of less than 0.020 l/gm-cm, a viscosity index (VI) from 80 to 120, and having a cycloparaffin performance ratio greater than 1.05 and a kinematic viscosity at 100° C. between 10 and 14 cSt. A lubricating oil having the base stock as a major component, and one or more additives as a minor component. Methods for improving oxidation performance and low temperature performance of formulated lubricant compositions through the compositionally advantaged base stock.

A base stock having at least 90 wt. % saturates, an amount and distribution of aromatics, as determined by ultra violet (UV) spectroscopy, including an absorptivity between 280 and 320 nm of less than 0.015 l/gm-cm, a viscosity index (VI) from 80 to 120, and having a cycloparaffin performance ratio greater than 1.05 and a kinematic viscosity at 100° C. between 4 and 6 cSt. A base stock having at least 90 wt. % saturates, an amount and distribution of aromatics, as determined by UV spectroscopy, including an absorptivity between 280 and 320 nm of less than 0.020 l/gm-cm, a viscosity index (VI) from 80 to 120, and having a cycloparaffin performance ratio greater than 1.05 and a kinematic viscosity at 100° C. between 10 and 14 cSt. A lubricating oil having the base stock as a major component, and one or more additives as a minor component. Methods for improving oxidation performance and low temperature performance of formulated lubricant compositions through the compositionally advantaged base stock.

Methods are provided for refining natural oil feedstocks. The methods comprise reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters. In certain embodiments, the methods further comprise separating the olefins from the esters in the metathesized product. In certain embodiments, the methods further comprise hydrogenating the olefins under conditions sufficient to form a fuel composition. In certain embodiments, the methods further comprise transesterifying the esters in the presence of an alcohol to form a transesterified product.

Methods are provided for refining natural oil feedstocks. The methods comprise reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters. In certain embodiments, the methods further comprise separating the olefins from the esters in the metathesized product. In certain embodiments, the methods further comprise hydrogenating the olefins under conditions sufficient to form a fuel composition. In certain embodiments, the methods further comprise transesterifying the esters in the presence of an alcohol to form a transesterified product.

Device and process for converting a feedstock of aromatic compounds, in which the feedstock is notably treated using a fractionation train (4-7), a xylenes separating unit (10) and an isomerization unit (11), and in which a pyrolysis unit (13) treats a second hydrocarbon-based feedstock, produces a pyrolysis effluent feeding the feedstock, and produces a pyrolysis gas comprising CO, CO2 and H2; an RWGS reverse water gas shift reaction section (51) treats the pyrolysis gas and produces an RWGS gas enriched in CO and in water; a fermentation reaction section (52) treats the RWGS gas enriched in CO and in water and produces ethanol; and an aromatization reaction section (14) converts the ethanol into a mixture of aromatic and paraffinic compounds feeding the feedstock.

Device and process for converting a feedstock of aromatic compounds, in which the feedstock is notably treated using a fractionation train (4-7), a xylenes separating unit (10) and an isomerization unit (11), and in which a pyrolysis unit (13) treats a second hydrocarbon-based feedstock, produces a pyrolysis effluent feeding the feedstock, and produces a pyrolysis gas comprising CO, CO2 and H2; an RWGS reverse water gas shift reaction section (51) treats the pyrolysis gas and produces an RWGS gas enriched in CO and in water; a fermentation reaction section (52) treats the RWGS gas enriched in CO and in water and produces ethanol; and an aromatization reaction section (14) converts the ethanol into a mixture of aromatic and paraffinic compounds feeding the feedstock.