A process and apparatus for oxidizing thiol compounds from an alkaline stream. The process includes passing a thiol rich alkaline stream and an oxygen containing gas to a low pressure oxidizing zone to oxidize at least a portion of the thiol compounds to disulfide compounds. A liquid stream comprising the alkali containing the disulfide compounds is passed through a pump to increase the pressure and form a pressurized alkaline stream. The pressurized alkaline stream and a sulfur lean liquid light hydrocarbon stream are introduced to a high pressure disulfide separation vessel to form a sulfur lean alkaline stream and a sulfur rich liquid light hydrocarbon stream.

A process and apparatus for oxidizing thiol compounds from an alkaline stream. The process includes passing a thiol rich alkaline stream and an oxygen containing gas to a low pressure oxidizing zone to oxidize at least a portion of the thiol compounds to disulfide compounds. A liquid stream comprising the alkali containing the disulfide compounds is passed through a pump to increase the pressure and form a pressurized alkaline stream. The pressurized alkaline stream and a sulfur lean liquid light hydrocarbon stream are introduced to a high pressure disulfide separation vessel to form a sulfur lean alkaline stream and a sulfur rich liquid light hydrocarbon stream.

The present disclosure relates to processes for the removal of paraffins. The processes generally include providing a C.sub.4 containing stream including isobutylene, 1-butene, 2-butene, n-butane and isobutane, introducing the C.sub.4 containing stream into a paraffin removal process to form an olefin rich stream, wherein the paraffin removal process is selected from extractive distillation utilizing a solvent including an organonitrile, passing the C.sub.4 containing stream over a semi-permeable membrane and combinations thereof; and recovering the olefin rich stream from the paraffin removal process, wherein the olefin rich stream includes less than 5 wt. % paraffins.

The present invention provides a process for recovery of propylene and LPG from the fuel gas produced in FCC unit by contacting a heavier hydrocarbon feed with FCC catalyst. The process provides an energy efficient configuration for revamping an existing unit constrained on wet gas compressor capacity or for designing a new gas concentration unit to recover propylene and LPG recovery beyond 97 mole %. The process of the present invention provides an increase propylene and LPG recovery without loading wet gas compressor with marginal increase in liquid loads.

The present invention relates to an apparatus that is part of a reusable fuel processing unit that allows the absorption of char contained within vapor that is leaving the reactor including a gear box, gearbox housing, support flange and seal, exhaust housing, exhaust port, connecting flange, screw top split housing, vertical steal housing, three augers with drive shafts on each auger contained within the steel housing, discharge flange, support ring, expansion cart, and cam followers.

A vacuum separator is used to separate a pitch stream from a slurry hydrocracking reactor upstream of the product fractionation column. The process and apparatus removes pitch from the product streams to enable easier separation of light VGO from heavy VGO in a fractionation column.

A process for extracting a condensable vapor from a supplied gas, comprising the steps of: i) condensing the condensable vapor by cooling the supplied gas at a condensing surface, such that the supplied gas is divided into at least one condensed fraction and a product gas; while ii) removing the at least one condensed fraction from the condensing surface by mechanical scraping means.

A transfer line between the outlet of a steam cracker and the inlet for the quench system has metallic or ceramic inserts having a pore size from about 0.001 to about 0.5 microns inside the line forming a gas tight barrier with the inner surface of the line and having a vent for the resulting gas tight pocket are used to separate H.sub.2, CH.sub.4, CO and CO.sub.2 from cracked gases reducing the load on the down-stream separation train of the steam cracker.

A transfer line between the outlet of a steam cracker and the inlet for the quench system has metallic or ceramic inserts having a pore size from about 0.001 to about 0.5 microns inside the line forming a gas tight barrier with the inner surface of the line and having a vent for the resulting gas tight pocket are used to separate H.sub.2, CH.sub.4, CO and CO.sub.2 from cracked gases reducing the load on the down-stream separation train of the steam cracker.

The power required to recover C.sub.3+ hydrocarbons from crude carbon dioxide comprising C.sub.1+ hydrocarbons and hydrogen sulfide may be reduced by distilling the crude carbon dioxide to produce carbon dioxide-enriched overhead vapor and C.sub.3+ hydrocarbon-enriched bottoms liquid such that the hydrogen sulfide is rejected with the overhead vapor. Power consumption reductions may be achieved by incorporating a heat pump cycle using carbon dioxide vapor as working fluid to provide at least a part of the refrigeration duty and using a side reboiler to reduce the bottom reboiler duty. Where the bottoms liquid is further processed to produce lighter and heavier hydrocarbon fractions, the process enables optimization of upgrading crude oil on the basis of API gravity, Reid Vapor pressure and/or viscosity.