C10G75/02

Basic ionic liquids as hydrochloric acid scavengers in refinery crude processing
10822547 · 2020-11-03 · ·

Treatment of crude oil with basic ionic liquids (ILs), results in scavenging of any hydrochloric acid (HCl) that is present to remove the HCl. The IL is a quaternary ammonium compound having the formula R.sub.4N.sup.+X.sup. or R.sub.3N.sup.+RN.sup.+R.sub.3, where R is independently an alkyl group, an alkylbenzyl group, a hydroxyalkyl group, or a hydroxyalkylbenzyl group, and R is straight or branched and has 1-22 carbon atoms, R is a straight or branched alkylene or oxyalkylene having 1 to 10 carbon atoms, and where X.sup. is selected from the group consisting of hydroxide, carbonate, alkylcarbonate, bicarbonate or alkoxide, where the alkyl group of the alkyl-carbonate or alkoxide, if present, is straight or branched and has 1 to 8 carbon atoms. The ILs are introduced into the crude oil after the refinery desalters and before the crude distillation tower to prevent or inhibit HCl from distilling to the crude tower overhead.

Zinc ammonium carbonate sulfide scavengers

Methods for the use of zinc ammonium carbonate as a scavenger of sulfur-containing species encountered in oilfield operations are provided. In one embodiment, the methods include introducing a sulfide scavenging additive including zinc ammonium carbonate into at least a portion of a conduit through which a potential sulfur-containing fluid is flowing.

Zinc ammonium carbonate sulfide scavengers

Methods for the use of zinc ammonium carbonate as a scavenger of sulfur-containing species encountered in oilfield operations are provided. In one embodiment, the methods include introducing a sulfide scavenging additive including zinc ammonium carbonate into at least a portion of a conduit through which a potential sulfur-containing fluid is flowing.

Effective novel polymeric additive for inhibiting napthenic acid corrosion and method of using the same

The present invention relates to the field of inhibition of metal corrosion in hot acidic hydrocarbons, wherein acidity is derived from presence of naphthenic acid. More particularly, it relates to a polymeric additive for inhibiting high temperature napthenic acid corrosion, wherein said polymeric additive is polymeric phosphate ester of polyisobutylene succinate ester or oxide derivative of polymeric phosphate ester of polyisobutylene succinate ester. A polymeric phosphate ester of polyisobutylene succinate ester which is capable of acting as naphthenic acid corrosion inhibitor by inhibiting naphthenic acid corrosion in crude oil/feedstock/hydrocarbon streams containing naphthenic acid, and demonstrating higher thermal stability at elevated temperature varying from about 200 C. to about 400 C. [about 400 F. to about 750 F.] is disclosed.

Effective novel polymeric additive for inhibiting napthenic acid corrosion and method of using the same

The present invention relates to the field of inhibition of metal corrosion in hot acidic hydrocarbons, wherein acidity is derived from presence of naphthenic acid. More particularly, it relates to a polymeric additive for inhibiting high temperature napthenic acid corrosion, wherein said polymeric additive is polymeric phosphate ester of polyisobutylene succinate ester or oxide derivative of polymeric phosphate ester of polyisobutylene succinate ester. A polymeric phosphate ester of polyisobutylene succinate ester which is capable of acting as naphthenic acid corrosion inhibitor by inhibiting naphthenic acid corrosion in crude oil/feedstock/hydrocarbon streams containing naphthenic acid, and demonstrating higher thermal stability at elevated temperature varying from about 200 C. to about 400 C. [about 400 F. to about 750 F.] is disclosed.

NOVEL ORGANIC ACID SYSTEMS
20200291287 · 2020-09-17 ·

An organic acid composition for use in oil industry activities, said composition comprising an arylsulfonic acid in water as well as the use of said composition to perform various operations in the oil industry. There is also disclosed a solid acid composition comprising a corrosion inhibitor ready for dissolution and use.

NOVEL ORGANIC ACID SYSTEMS
20200291287 · 2020-09-17 ·

An organic acid composition for use in oil industry activities, said composition comprising an arylsulfonic acid in water as well as the use of said composition to perform various operations in the oil industry. There is also disclosed a solid acid composition comprising a corrosion inhibitor ready for dissolution and use.

Method and composition for neutralizing acidic components in petroleum refining units

A method of inhibiting corrosion and fouling in petroleum refining units which comprises adding choline hydroxide either alone or in combination with a hydrogen-bond donor such as a carboxylic acid, an amine, an amide, or an alcohol.

Method and composition for neutralizing acidic components in petroleum refining units

A method of inhibiting corrosion and fouling in petroleum refining units which comprises adding choline hydroxide either alone or in combination with a hydrogen-bond donor such as a carboxylic acid, an amine, an amide, or an alcohol.

SODIUM NITROPRUSSIDE AND NITRATE METABOLIC INHIBITION OF SULFATE-REDUCING MICROBES TO CONTROL SULFIDE PRODUCTION

Combinations of a nitroprusside, such as sodium nitroprusside (SNP; Na.sub.2[Fe(CN).sub.5NO].2H.sub.2O) and a nitrate, are provided, together with methods for the combined use of the nitroprusside and the nitrate as metabolic inhibitors of microbial cultures. The microbial cultures may include sulfate reducing bacteria (SRB) in aqueous culture. This metabolic inhibition may for example be implemented in the presence of a hydrocarbon, for example in an oil reservoir or in oil field systems and facilities. When applied to an SRB culture in the presence of a hydrocarbon, the combination of the nitroprusside and the nitrate may accordingly be used to ameliorate the biological formation of sulfides, particularly hydrogen sulfide.