Patent classifications
C10G2300/70
PROCESS FOR UPGRADING RENEWABLE LIQUID HYDROCARBONS
The invention relates to a catalytic process for upgrading a renewable crude oil produced from biomass and/or waste comprising providing a renewable crude oil and pressurizing it to a pressure in the range in the range 60 to 150 bar, contacting the pressurized renewable crude oil with hydrogen and at least one heterogeneous catalyst contained in a first reaction zone at a weight based hourly space velocity (WHSV) in the range 0.1 to 2.0 h.sub.−1 and at a temperature in the range of 150° C. to 360° C., hereby providing a partially upgraded renewable crude oil, separating the partially upgraded renewable crude oil from the first reaction zone to a partially upgraded heavy renewable oil fraction, a partially upgraded light renewable oil fraction, a water stream and a process gas stream, introducing the separated and partially upgraded heavy renewable oil fraction and separated process gas to a second reaction zone comprising at least two reactors arranged in parallel and being adapted to operate in a first and a second mode of operation, the reactors comprising dual functioning heterogeneous catalyst(-s) capable of performing a catalytic steam cracking reaction in a first mode of operation or a steam reforming reaction in a second mode of operation, where the partially upgraded heavy renewable oil fraction from the first reaction zone is contacted with the dual functioning heterogeneous catalyst and steam at a pressure of 10 to 150 bar and a temperature of 350° C. to 430° C. whereby a catalytic steam cracking of the partially upgraded heavy renewable oil is performed in the reactors in the first mode of operation, hereby providing a further upgraded heavy renewable oil fraction, while separated process gas from the first and/or second reaction zone is contacted with the dual functioning catalyst and steam at a pressure of 0.1 to 10 bar and a temperature of 350 to 600° C. in the reactors in the second mode of operation and contacted with the dual functioning catalyst, thereby producing a hydrogen enriched gas, separating the further upgraded heavy renewable oil fraction from the catalytically steam cracking reactor to at least one light renewable oil fraction, a heavy renewable oil fraction, a hydrogen rich process gas and a water phase, separating hydrogen from the hydrogen enriched gas from the catalytic steam cracking zone and/or from the catalytic steam reforming and recycling it to the first reaction zone, alternating the reactors between the first mode of operation and the second mode of operation at predetermined time intervals thereby allowing for regeneration of the heterogeneous catalyst for the catalytic steam cracking in the first mode of op
Catalyst recovery system, hydrocarbon synthesis reaction apparatus, hydrocarbon synthesis reaction system, and catalyst recovery process
A catalyst recovery system that includes a concentrated slurry production unit that concentrates a slurry extracted from a reactor main unit and continuously produces a concentrated slurry, a first discharge unit that discharges the concentrated slurry from the concentrated slurry production unit, a solidified slurry production unit that cools the concentrated slurry discharged from the concentrated slurry production unit, thereby solidifying the liquid medium within the concentrated slurry and producing a solidified slurry, and a recovery mechanism that recovers the solidified slurry from the solidified slurry production unit.
CATALYST, PYROLYSIS DEVICE AND PYROLYSIS METHOD
A catalyst is illustrated, which has 70-90 parts by weight of mica, 1-10 parts by weight of zeolite, 5-15 parts by weight of titanium dioxide, 1-10 parts by weight of aluminum oxide, 1-5 parts by weight of sodium oxide and 1-5 parts by weight of potassium oxide. The present disclosure also illustrates a pyrolysis device using the catalyst, and further illustrates a pyrolysis method using the catalyst and/or the pyrolysis device for thermally cracking an organic polymer.
PROCESS FOR ADSORBER REGENERATION
Disclosed is a process for the regeneration of an adsorber. For the regeneration a liquid stream (S2) is applied which is obtained by hydrogenation of a stream (S1) comprising at least one alkane and least one olefin. The stream (S2) comprises one alkane and a reduced amount of at least one olefin compared to the amount in the stream (S1). Then the stream (S2) is converted from the liquid into the gaseous phase and the adsorber is regenerated by contact with the gaseous stream (S2).
NAPHTHA COMPLEX WITH THERMAL OXIDATION SYSTEM
A process for treating effluent streams in a naphtha complex is described. One or more of the sour water stripping unit for the NHT sour water from the NHT, the amine treatment unit and the caustic treatment unit for the NHT stripper off-gas, the caustic scrubber unit or other chloride treatment unit for the off-gas from the C.sub.5-C.sub.6 isomerization zone and the C.sub.4 isomerization zone, and the caustic scrubber unit or other chloride treatment unit for the regenerator off-gas are replaced with a thermal oxidation system.
Nano-crystallite binder based CO combustion promoter
The present invention relates to catalyst product, a method of making a catalyst and its use in fluid catalytic conversion process. In particular, this invention relates to a process for the preparation of CO-combustion promoter microspheres, comprising a large crystallite low surface area alumina; a composite binder comprising nano-crystallite alumina and dispersant; and platinum or palladium or both. The large crystallite low surface area alumina is bound together by the composite binder in the said particulate composition.
Fischer-Tropsch synthesis catalyst containing nitride support, preparation method therefor and use thereof
Disclosed are a Fischer-Tropsch synthesis catalyst, a preparation method therefor and use thereof in a Fischer-Tropsch synthesis reaction. Wherein the catalyst comprises: an active component, being at least one selected from VIIIB transition metals; an optional auxiliary metal; and a nitride carrier having a high specific surface area. The catalyst is characterized in that the active metal is supported on the nitride carrier having the high specific surface, such that the active component in the catalyst is highly dispersed. The catalyst has a high hydrothermal stability, an excellent mechanical wear resistance, a high Fischer-Tropsch synthesis activity and an excellent high-temperature stability.
Pyrolysis tube for manufacturing olefin and method for manufacturing dehydrogenating catalyst
The present invention provides a pyrolysis tube for manufacturing olefin which tube can improve a yield of olefin in a pyrolysis reaction of a hydrocarbon raw material. The pyrolysis tube (1A) for manufacturing olefin includes a tubular base material (2) made of a heat resistant metal material and a dehydrogenating catalyst (4A) which is supported on an inner surface of the tubular base material (2).
Method for Improving Oil Quality and Increasing Yield of Low-carbon Olefins by Utilizing Bio-Oil Catalytic Cracking
The Invention discloses a method for improving the quality of oil products and increasing the yield of low-carbon olefins by catalytic cracking of bio-oil, which takes bio-oil or mixed oil of bio-oil and hydrocarbon oil as raw oil for catalytic cracking reaction. With this method, the octane number of the gasoline in product is obviously increased, simultaneously, the content of propylene and other low-carbon olefins in product is also improved.
NAPHTHA CATALYTIC CRACKING CATALYST, CATALYTIC CRACKING METHOD AND REACTION DEVICE
A method for catalytic cracking of naphtha is provided. Naphtha is catalytically cracked under the action of a catalyst. The catalyst includes aluminosilicate, alkali metal oxide, alkaline earth metal oxide, TiO.sub.2, iron oxide, vanadium oxide and nickel oxide. On the other hand, a rapid separation component is arranged in a disengager of a catalytic cracking reaction device, so that a transport disengaging height is greatly reduced without changing a gas flow and a diameter of the disengager. In addition, the separation efficiency of oil gas and the catalyst is improved.