A process for the hydroprocessing of heavy oils and/or oil residues, the process comprising the steps of contacting a non-metallised carbonaceous material with an oxygen-containing gas at a temperature of at least 120° C. to form a non-metallised carbonaceous additive, and contacting the heavy oils and/or oil residues with the non-metallised carbonaceous additive in the presence of a hydrogen-containing gas at a temperature of from 250° C. to 600° C.

The invention concerns a process for preparing a catalyst comprising at least one metal M from the platinum group, tin, a phosphorus promoter, a halogenated compound, a porous support and at least one promoter X1 selected from the group constituted by gallium, indium, thallium, arsenic, antimony and bismuth. The promoter or promoters X1 and the phosphorus are introduced during one or more sub-steps a1) or a2), the sub-step a1) corresponding to synthesis of the precursor of the main oxide and sub-step a2) corresponding to shaping the support. The tin is introduced during at least one of sub-steps a1) and a2). The product is dried and calcined before depositing at least one metal M from the platinum group. The ensemble is then dried in a stream of neutral gas or a stream of gas containing oxygen, and then is dried. The invention also concerns the use of a catalyst obtained by said process in catalytic reforming or aromatics production reactions.

Described herein is a base oil synthesis via ionic catalyst oligomerization further utilizing a hydrophobic process for removing an ionic catalyst from a reaction mixture with a silica gel composition, specifically a reaction mixture comprising an oligomerization reaction to produce PAO utilizing an ionic catalyst wherein the ionic catalyst is removed post reaction.

A new family of crystalline microporous silicometallophosphate designated SAPO-69 has been synthesized. These silicometallophosphate are represented by the empirical formula of:

R.sup.p+.sub.rM.sub.m.sup.+E.sub.xPSi.sub.yO.sub.z

where M is an alkali metal such as potassium, R is an organoammonium cation such as ethyltrimethylammonium and E is a trivalent framework element such as aluminum or gallium. The SAPO-69 family of materials represent the first phosphate-based molecular sieves to have the OFF topology and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.

Processes for preventing or minimizing the rate of upgrading catalyst deactivation in a petroleum refinery, preventing or minimizing the rate of silicone-containing deposits within refinery process equipment, or both utilizing high-field proton nuclear magnetic spectroscopy (NMR) to rapidly measure concentrations of polydimethylsiloxanes (PDMS) and its thermal degradation products in potential refinery feed stock and refinery intermediate streams with high sensitivity and precision.

The present invention describes an extractive oxidation process for removing contaminants from hydrocarbon streams using an ionic liquid combined with an organometallic ionic complex of iron(II), which comprises a complex of iron(II) cation with an ionophilic binder, catalyst of iron(II) with ionophilic binder in its molecular structure, oxidation of which is performed with an oxidizing agent and is catalysed by the organometallic iron(II) complex present in the phase of the ionic liquid. Besides maintaining its characteristics of selective solvent of oxidizing compounds, the ionic liquid combined with the organometallic complex of iron(II) with catalytic ionophilic binder of the oxidizing agent, stimulating the reactive phenomenon taking place in the ionic liquid phase, with the effect that the iron remains stable in the ionic liquid phase, without being leached into the oily phase. This measure results in a considerable improvement in removal of the heteroatoms from the hydrocarbon medium.

Provided is a selective transfer method including depositing a thin film on a substrate; patterning the thin film using a laser or a tool to acquire a thin film of a target pattern; masking the thin film of the target pattern; selectively controlling a surface wettability through surface treatment of the masked thin film; delaminating the thin film of the target pattern by dipping a surface of the thin film with a wettability changed in response to a completion of the selective surface treatment into a liquid material and by applying a crack opening force capable of delaminating an interface between the thin film and the substrate; and immersing a target substrate into the liquid material when the thin film of the target pattern is floating in the liquid material and then scoop-up transferring the floating thin film of the target pattern.

A process for preparing a peptized alumina having increased solids and acid contents and a decreased water content. The process comprising mixing a boehmite or pseudoboehmite alumina and acid with a high intensity, high energy mixer at a ratio of 0.16 to 0.65 moles acid/moles alumina for a time period sufficient to form a substantially free-flowing solid particulate having a solids content of 45 to 65 wt %. When used in catalyst manufacture, peptized alumina produced by the process provides an increased rate in catalyst production and decreased costs due to high solids concentration and the presence of less water to be evaporated.

A method of catalytically cracking liquid hydrocarbons is disclosed. The method includes the use of one or more radial flow moving bed reactors. The method may include mixing a liquid hydrocarbon stream comprising primarily C5 and C6 hydrocarbons with water or a dry gas to form a feed mixture and flowing the feed mixture into the one or more radial flow moving bed reactors in a manner so that the feed mixture flows radially inward or radially outward through the moving catalyst bed and thereby contacts the catalyst particles under reaction conditions to produce a hydrocarbon stream comprising light olefins (C2 to C4 olefins).

A liquid-solid axial moving bed reaction and regeneration apparatus and a solid acid alkylation process by using the liquid-solid axial moving bed reaction and regeneration apparatus. the liquid-solid axial moving bed reaction and regeneration apparatus comprise:

An axial moving bed reactor (1), a spent catalyst receiver (5), a catalyst regenerator (4) and a regenerated catalyst receiver (6) that are successively connected, wherein, a catalyst outlet of the regenerated catalyst receiver (6) is communicated with a catalyst inlet of the axial moving bed reactor (1);

Wherein, the axial moving bed reactor (1) is provided with at least two catalyst beds (3) arranged up and down, the axial moving bed reactor (1) is provided with a feed inlet (2) above each catalyst bed (3);

A catalyst delivery pipe (16) is arranged between two adjacent catalyst beds (3) so that the catalyst can move from top to bottom in the axial moving bed reactor (1);

A separation component (10) is provided between two adjacent catalyst beds (3), the inside space of the separation component (10) is communicated with the catalyst delivery pipe (16), the separation component (10) is for separating the stream after the reaction in the upstream catalyst bed from the catalyst, the catalyst obtained by the separation with the separation component (10) moves down through the catalyst delivery pipe (16).