A hydrocarbon feed stream, particularly one comprising heavier hydrocarbons, may be converted to valuable products such as motor gasoline and/or lubricating oil by employing one or more MOF catalysts, which may be prepared from a precursor metal-organic framework (MOF). A MOF catalyst may be prepared by exchanging one or more organic linking ligands of the precursor MOF for an organic linking ligand having a different acidity and/or electron-withdrawing properties, which, in turn, may affect catalytic activity.

Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. In one embodiment, the process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit distillation column in a refinery where a straight run naphtha (C.sub.5-C.sub.8) fraction or a propane/butane (C.sub.3-C.sub.4) fraction is recovered. The straight run naphtha fraction (C.sub.5-C.sub.8) or the propane/butane (C.sub.3-C.sub.4) fraction is passed to a steam cracker for ethylene production. The heavy fraction from the pyrolysis unit can also be passed to an isomerization dewaxing unit to produce a base oil.

A hydrotreating catalyst comprising an active phase containing at least one group VIB metal and at least one group VIII metal, and a porous support containing alumina and at least one spinel MAl.sub.2O.sub.4 where M is chosen from nickel and cobalt, characterized in that: the molar ratio (r1) between said group VIII metal and said group VIB metal of the active phase is between 1.0 and 3.0 mol/mol; the molar ratio (r2) between said metal M of the porous support and said group VIII metal of the active phase is between 0.3 and 0.7 mol/mol; the molar ratio (r3) between the sum of the contents of the metal M and of the group VIII metal relative to the content of group VIB metal is between 2.2 and 3.0 mol/mol.

Methods for processing paraffinic naphtha include contacting a paraffinic naphtha feedstock with a catalyst system in a dehydrogenation reactor. The catalyst system includes a framework-substituted ultra-stable Y (USY)-type zeolite to produce a dehydrogenated product stream. The catalyst system includes a framework-substituted ultra-stable Y (USY)-type zeolite. The framework-substituted USY-type zeolite has a modified USY framework. The modified USY framework includes a USY aluminosilicate framework modified by substituting a portion of framework aluminum atoms of the USY aluminosilicate framework with substitution atoms independently selected from the group consisting of titanium atoms, zirconium atoms, hafnium atoms, and combinations thereof. A dehydrogenation catalyst for dehydrogenating a paraffinic naphtha includes the framework-substituted ultra-stable Y (USY)-type zeolite.

A solvent comprised of (1) a caustic and an alcohol, (2) a caustic and a quaternary ammonium hydroxide, or (3) a caustic, an alcohol, and a quaternary ammonium hydroxide may contact an adsorbent bed that has been used to remove sulfur compounds from a hydrocarbon stream to extract adsorbed sulfur compounds from the adsorbent material in the bed to regenerate it. The regenerated adsorbent bed may be reused, either alone or in combination with a liquid-liquid extraction column, to remove sulfur compounds from a hydrocarbon stream.

Improved alkylation catalysts, alkylation methods, and methods of making alkylation catalysts are described. The alkylation method comprises reaction over a solid acid, zeolite-based catalyst and can be conducted for relatively long periods at steady state conditions. The alkylation catalyst comprises a crystalline zeolite structure, a Si/Al molar ratio of 20 or less, less than 0.5 weight percent alkali metals, and further having a characteristic catalyst life property. Some catalysts may contain rare earth elements in the range of 10 to 35 wt %. One method of making a catalyst includes a calcination step following exchange of the rare earth element(s) conducted at a temperature of at least 575° C. to stabilize the resulting structure followed by an deammoniation treatment. An improved method of deammoniation uses low temperature oxidation.

Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization or for normal alpha olefins. The process comprises selecting waste plastics containing polyethylene and/or polypropylene and then passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit in a refinery from which is recovered a straight run naphtha fraction (C.sub.5-C.sub.8) or a propane/butane (C.sub.3-C.sub.4) fraction. The straight run naphtha fraction, or propane and butane (C.sub.3-C.sub.4) fraction, is passed to a steam cracker for ethylene production. The ethylene is converted to normal alpha olefin and/or polyethylene. Also, a heavy fraction from the pyrolysis reactor can be combined with a heavy fraction of normal alpha olefin stream recovered from the steam cracker. The combined heavy fraction and heavy fraction of normal alpha olefin stream can be passed to a wax hydrogenation zone to produce wax.

A fluid catalytic cracking catalyst for hydrocarbon oil that is a blend of two types of fluid catalytic cracking catalysts each of which has a different hydrogen transfer reaction activity or has a pore distribution within a specific range after being pseudo-equilibrated. One catalyst is a catalyst containing a zeolite and matrix components, and the other catalyst is a catalyst containing a zeolite and matrix components. This catalyst is composed of the one catalyst and the other catalyst blended at a mass ratio within a range of 10:90 to 90:10.

The present invention relates to an integrated process for increasing the research octane number (RON) of FCC gasoline with simultaneous reduction in benzene content. In this process, benzene rich gasoline fraction is reacted with light olefin rich gaseous streams like FCC off gas/dry gas, coker off gas to produce alkyl aromatics using FCC catalyst system containing ZSM-5 zeolite. The catalyst is continuously drawn from the FCC regenerator by suitably placing the alkylation reactor in communication with the FCC regenerator. The product stream of the alkylation reactor is routed to main fractionator for separation of off gas and benzene lean gasoline. This integrated process not only improves the octane number of gasoline but also lowers the gasoline benzene content. Further the integrated alkylation reactor system acts as a heat sink lowering the FCC regenerator temperature and enables the FCC unit to process high CCR feeds.

The present invention provides a multistage single reactor system for hydroprocessing and a process of carrying out multistage hydroprocessing in the said reactor assembly consisting of, a fixed bed solid catalyst system, a feed injection system enabling axial flow of hydrogen saturated hydrocarbon feed, a hydrogen dispensing system inside the reactor enabling minimum required hydrogen flow in cross-flow pattern, also using multitudes of integrated separation and withdrawal limbs for continuous staging. The innovative reactor disclosed in the present invention enables continuous separation and withdrawal of gaseous products along the reactor length by means of combined horizontal reactor orientation and vertical separation limbs provided at the top of the horizontally oriented reactor. The advantage of the reactor assembly includes effective heat sink of exothermic reactions and lower severity of operation due to removal of inhibitory gaseous products.