Patent classifications
C10G2400/02
UPGRADING BIO-WASTE IN FCC
A method may include: providing bio waste stream wherein the bio waste stream comprises at least one bio waste selected from the group consisting of palm oil mill effluent, soapstock, and combinations thereof; introducing the bio waste effluent stream into a fluidized catalytic cracking unit; contacting the bio waste with a catalyst in the fluidized catalytic cacking unit; and cracking at least a portion of the bio waste stream to form cracked products that comprise a cracked product stream.
Providing carbon dioxide by means of oxygen-based combustion
A method for preparing a carbonaceous product includes providing oxygen, in particular from electrolysis, and providing a fuel. The method also includes combusting the fuel with the oxygen by an oxy-fuel combustion process in order to provide energy, purifying a flue gas produced by the oxy-fuel combustion process, and separating carbon dioxide from the flue gas produced by the oxy-fuel combustion process, wherein energy provided by the oxy-fuel combustion process includes, in particular exclusively, heat which is used as process heat for purifying and/or for synthesising or providing the carbonaceous product. A corresponding system is designed to carry out the described method.
Circular economy for plastic waste to polyethylene via refinery FCC and alkylation units
Provided in one embodiment is a continuous process for converting waste plastic into recycle for polyethylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene, and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a pyrolysis oil and optionally wax comprising a naphtha/diesel and heavy fraction, and char. The pyrolysis oil and wax is passed to a refinery FCC unit from which a liquid petroleum gas C.sub.3-C.sub.5 olefin/paraffin mixture fraction is recovered. The liquid petroleum gas C.sub.3-C.sub.5 olefin/paraffin mixture fraction is passed to a refinery alkylation unit, with a propane and butane fraction recovered from the alkylation unit. The propane and butane fraction is then passed to a steam cracker for ethylene production. In another embodiment, a naphtha fraction (C.sub.5-C.sub.8) is recovered from the alkylation unit and passed to the steam cracker. In another embodiment, a propane/propylene fraction (C.sub.3-C.sub.3.sup.=) is recovered from the FCC and passed to the steam cracker.
Circular economy for plastic waste to polyethylene and chemicals via refinery crude unit
Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization or for normal alpha olefins. The process comprises selecting waste plastics containing polyethylene and/or polypropylene and then passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit in a refinery from which is recovered a straight run naphtha fraction (C.sub.5-C.sub.8) or a propane/butane (C.sub.3-C.sub.4) fraction. The straight run naphtha fraction, or propane and butane (C.sub.3-C.sub.4) fraction, is passed to a steam cracker for ethylene production. The ethylene is converted to normal alpha olefin and/or polyethylene. Also, a heavy fraction from the pyrolysis reactor can be combined with a heavy fraction of normal alpha olefin stream recovered from the steam cracker. The combined heavy fraction and heavy fraction of normal alpha olefin stream can be passed to a wax hydrogenation zone to produce wax.
Circular economy for plastic waste to polypropylene and lubricating oil via refinery FCC and isomerization dewaxing units
A continuous process for converting waste plastic into recycle for polypropylene polymerization is provided. The process integrates refinery operations to provide an effective and efficient recycle process. The process comprises selecting waste plastics containing polyethylene and polypropylene and then passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a refinery FCC unit, from which is recovered a liquid petroleum gas C.sub.3 olefin/paraffin mixture. The C.sub.3 paraffins and C.sub.3 olefins are separated into different fractions with a propane/propylene splitter. The C.sub.3 olefin fraction is passed to a propylene polymerization reactor. The C.sub.3 paraffin fraction is optionally passed to a dehydrogenation unit to produce additional propylene and then the resulting C.sub.3 olefin is passed to a propylene polymerization reactor. The heavy fraction of pyrolyzed oil is passed to an isomerization dewaxing unit to produce a lubricating base oil.
ALUMINA GRAIN, PREPARATION METHOD THEREFOR AND USE THEREOF
An alumina grain has a single-crystal structure and has an approximate regular octahedral stereoscopic morphology. Eight sides of the alumina grain belong to the {111} family of crystal planes of γ-state alumina, and the grain size is 5-100 μm. The alumina grain is unique in crystal plane exposure and distribution, simple and feasible in preparation, and low in cost, and has higher operability, and thus has good application prospect in the field of catalysis and adsorption.
METHOD AND APPARATUS FOR DESULFURIZATION AND SEPARATION OF CATALYTICALLY CRACKED LIGHT PRODUCT
A method for the desulfurization and separation of a catalytic cracking light product includes the steps of: 1) contacting a catalytic cracking light product with a desulfurization adsorbent in an adsorption desulfurization reaction unit in the presence of hydrogen for desulfurization, and optionally, carrying out gas-liquid separation on the resulting desulfurization product, to obtain a desulfurized rich gas and a desulfurized crude gasoline, wherein the catalytic cracking light product is an overhead oil-gas fraction from a catalytic cracking fractionator, or a rich gas and a crude gasoline from a catalytic cracking fractionator; and 2) separately sending the desulfurized rich gas and the desulfurized crude gasoline obtained in the step 1) to a catalytic cracking absorption stabilization system for separation, to obtain a desulfurized dry gas, a desulfurized liquefied gas and a desulfurized stabilized gasoline.
PROCESSES AND SYSTEMS FOR FORMATION OF RECYCLE-CONTENT HYDROCARBON COMPOSITIONS
Processes and systems for making recycle content hydrocarbons, including olefins, from recycled waste material. Recycle waste material may be pyrolyzed to form recycle content pyrolysis oil composition (r-pyoil), at least a portion of which may then be cracked to form a recycle content olefin composition (r-olefin). In some cases, a heavy fraction from the cracker effluent may be used to form a recycle content pyrolysis gasoline composition (r-pyrolysis gasoline).
PROCESSES AND SYSTEMS FOR FORMATION OF RECYCLE-CONTENT HYDROCARBON COMPOSITIONS
Processes and systems for making recycle content hydrocarbons, including olefins, are provided that integrate a cracker unit with one or more other processing units. For example, in some cases, a pyrolysis unit and cracking unit may share a common energy exchange zone so that energy from one unit may be transferred to the other. The energy exchange may be direct or indirect and may be present at one or more locations between the units.
Flexible production of gasoline and jet fuel in alkylation reactor
Systems and processes for the flexible production of gasoline and jet fuel via alkylation of C4 and C5 olefins.